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Volume 31
Main Index

Issue 1


Reactions of carbonylchlorohydridobis(triisopropylphosphine)ruthenium with molecular hydrogen in solution. New molecular hydrogen complexes of ruthenium: RuH(H2)Cl(CO)[P(iso-Pr)3]2 and Ru(H)2(H2)(CO)[P(iso-Pr)3]2
D. G. Gusev, A. B. Vymenits, and V. I. Bakhmutov
pp 1 - 2; DOI:
10.1021/ic00027a001
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Di-tert-butylphosphido versus diphenylphosphido as a bridging ligand in binuclear iron carbonyl complexes: synthesis and structural characterization of Fe2(CO)5(.mu.-P(tert-Bu)2)2 and Fe2(CO)6(.mu.-PPh2)(.mu.-P(tert-Bu)2)
Michael R. Adams, Judith Gallucci, Andrew Wojcicki, and Gary J. Long
pp 2 - 4; DOI:
10.1021/ic00027a002
PDF
Ligand-bridged rhenium(I) complexes: an electrochemical and photophysical study
B. J. Yoblinski, Michael Stathis, and Thomas F. Guarr
pp 5 - 10; DOI:
10.1021/ic00027a003
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Stabilities of metal complexes of the meso and SS isomers of oxydisuccinic acid
Ramunas J. Motekaitis and Arthur E. Martell
pp 11 - 15; DOI:
10.1021/ic00027a004
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Transesterification of a phosphate diester by divalent and trivalent metal ions
Janet R. Morrow, Lisa A. Buttrey, and Kristin A. Berback
pp 16 - 20; DOI:
10.1021/ic00027a005
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Coordination of 4,7-bis(2-hydroxybenzyl)-1-oxa-4,7-diazacyclononane (LH2) with manganese(II) and -(III) and zinc(II). Crystal structure of [(LH)2Zn2(.mu.-OH)](PF6).cntdot.0.5CH3OH
Claus Flassbeck, Karl Wieghardt, Eckhard Bill, Christian Butzlaff, Alfred X. Trautwein, Bernhard Nuber, and Johannes Weiss
pp 21 - 26; DOI:
10.1021/ic00027a006
PDF
Syntheses, structures, and reactivities of the sulfur-bridged trinuclear complexes [(L)Ru(CO)(PPh3)]2(.mu.-MS4) (L = PhNCHS, CH2CH2(C5H4N), CH2CH2C(O)OMe; M = Mo, W). Photochemical and chemical reactions and isolation of a trinuclear complex having a coordinatively unsaturated ruthenium atom
Masao Kato, Masaki Kawano, Hirokazu Taniguchi, Mikimasa Funaki, Hiroshi Moriyama, Toshio Sato, and Kazuko Matsumoto
pp 26 - 35; DOI:
10.1021/ic00027a007
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Charge distribution in bis(quinone) complexes of ruthenium and osmium. Structural, spectral, and electrochemical properties of the Os(bpy)(Cat)2 (Cat = catecholate, 3,5-di-tert-butylcatecholate, tetrachlorocatecholate) series
Samaresh Bhattacharya and Cortlandt G. Pierpont
pp 35 - 39; DOI:
10.1021/ic00027a008
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Chemistry of the ruthenium [Ru(RQ)(tap)2]z family: authentic catecholates, reduction potentials, and spectra (RQ = quinone/semiquinone/catecholate; tap = 2-(m-tolylazo)pyridine; z = 0, .+-., .+-.2)
Nilkamal Bag, Amitava Pramanik, Goutam Kumar Lahiri, and Animesh Chakravorty
pp 40 - 45; DOI:
10.1021/ic00027a009
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cis-Bis(phosphine)platinum(II) complexes with pyrimidyl nucleobases. Synthesis, characterization, and crystal structures of cis-(1-methylthyminato-N3)(N,N-dimethylformamide-O)(1,1'-bis(diphenylphosphino)ferrocene)platinum(II) tetrafluoroborate-dichloromethane, [(dppf)Pt(1-MeTy(-H))(DMF)]BF4.cntdot.CH2Cl2, and cis-(1-methylthyminato-N3)(1-methylcytosine-N3)(1,1'-bis(diphenylphosphino)ferrocene)platinum(II) tetrafluoroborate, [(dppf)Pt(1-MeTy(-H))(1-MeCy)]BF4
Giuliano Bandoli, Guendalina Trovo, Alessandro Dolmella, and Bruno Longato
pp 45 - 51; DOI:
10.1021/ic00027a010
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Electron-transfer reactions of bis(dipeptide)nickel(III) complexes
Steven E. Schadler, Christopher Sharp, and A. Graham Lappin
pp 51 - 57; DOI:
10.1021/ic00027a011
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Copper(II)-catalyzed oxidation of catechol by molecular oxygen in aqueous solution
Jozsef Balla, Tamas Kiss, and Reginald F. Jameson
pp 58 - 62; DOI:
10.1021/ic00027a012
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Mechanism of isocyanide insertion into the methyl-iron bond of [Fe(CO)2L2(CNR)CH3]BPh4
Gianfranco Bellachioma, Giuseppe Cardaci, Alceo Macchioni, and Gustavo Reichenbach
pp 63 - 66; DOI:
10.1021/ic00027a013
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Ketyl titanium complexes of (silox)3Ti (silox = tert-Bu3SiO-)
Katharine J. Covert, Peter T. Wolczanski, Steven A. Hill, and Paul J. Krusic
pp 66 - 78; DOI:
10.1021/ic00027a014
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A 10-electron rhenium hydride cluster
D. M. Hoffman, D. Lappas, and E. Putilina
pp 79 - 81; DOI:
10.1021/ic00027a015
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Oxo-hydrido and imido-hydrido derivatives of permethyltantalocene. Structures of (.eta.5-C5Me5)2Ta(:O)H and (.eta.5-C5Me5)2Ta(:NC6H5)H: doubly or triply bonded tantalum oxo and imido ligands?
Gerard Parkin, Allan Van Asselt, David J. Leahy, LeRoy Whinnery, Nhi G. Hua, Roger W. Quan, Lawrence M. Henling, William P. Schaefer, Bernard D. Santarsiero, and John E. Bercaw
pp 82 - 85; DOI:
10.1021/ic00027a016
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Bis(cyclooctatetraene)vanadium: x-ray structure and study of molecular motions by EPR and ENDOR spectroscopy in frozen solution
Didier Gourier, Edmond Samuel, Bernd Bachmann, Friedemann Hahn, and Juergen Heck
pp 86 - 95; DOI:
10.1021/ic00027a017
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Organometallic chemistry of vanadium(III) based on the vanadium-dibenzotetramethyltetraaza[14]annulene moiety: synthesis, structural studies by x-ray and proton NMR spectroscopy, and reactivity of vanadium-carbon functionalities
Euro Solari, Stefania De Angelis, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 96 - 101; DOI:
10.1021/ic00027a018
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Reduction of biscarborane: molecular structures of [(15-crown-5)3Na2](C2B10H11)2 and [P(C6H5)3CH3]2[.mu.-9,10-CH-(.mu.-9',10'-CH-nido-7'-CB10H11)-nido-7-CB10H11]
Thomas D. Getman, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 101 - 105; DOI:
10.1021/ic00027a019
PDF
Homonuclear copper complexes with multidentate amino alcohol ligands. Synthesis and characterization of a dicopper zwitterion, bis(1,3-bis(dimethylamino)-2-propanol)tetrachlorodicopper and a tricopper compound, bis(1,3-bis(dimethylamino)-2-propanolato)tetrachlorotricopper
Jian Chuan Zheng, Roger J. Rousseau, and Suning Wang
pp 106 - 110; DOI:
10.1021/ic00027a020
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Ferromagnetically coupled gadolinium(III)copper(II) molecular material
Olivier Guillou, Pierre Bergerat, Olivier Kahn, Evangelos Bakalbassis, Kamal Boubekeur, Patrick Batail, and Maurice Guillot
pp 110 - 114; DOI:
10.1021/ic00027a021
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Bonding properties of calcium gallium arsenide, Ca14GaAs11: a compound containing discrete GaAs4 tetrahedra and a hypervalent As3 polyatomic unit
R. F. Gallup, C. Y. Fong, and Susan M. Kauzlarich
pp 115 - 118; DOI:
10.1021/ic00027a022
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Electronic structure, bonding, and properties of copper phosphide, CuP2
Pere Alemany, Santiago Alvarez, Myung Hwan Whangbo, and Michel Evain
pp 119 - 124; DOI:
10.1021/ic00027a023
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Electrochemical and spectral probes of metal/ligand orbital mixing in tetraammine(bipyridine)ruthenium(2+) and tetrammine(phenanthroline)ruthenium(2+)
Gary A. Mines, Jody A. Roberts, and Joseph T. Hupp
pp 125 - 128; DOI:
10.1021/ic00027a024
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A theoretical study of the adsorbate-induced reconstruction of the (110) surface of nickel and a molecular analog
Jeremy K. Burdett, Paul T. Czech, and Thomas F. Fassler
pp 129 - 136; DOI:
10.1021/ic00027a025
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X-ray crystallographic investigation of the bonding changes accompanying a new, reversible cobalt-to-carbon alkyl migration reaction
Brian E. Daikh, Timothy J. R. Weakley, and Richard G. Finke
pp 137 - 139; DOI:
10.1021/ic00027a026
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Triply bridged diruthenium complexes with [RuIII2(.mu.-O)(.mu.-O2CCH3)2]2+ and [RuIVRuIII(.mu.-O)(.mu.-O2CCH3)2]3+ cores: synthesis, spectra, and electrochemistry
Nishi Gupta, Subhasish Mukerjee, Samiran Mahapatra, Manabendra Ray, and Rabindranath Mukherjee
pp 139 - 141; DOI:
10.1021/ic00027a027
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(2,4-Pentanedionato)vanadium(III) and -vanadium(II) complexes: synthesis from the oxovanadium reductive chlorination and their structural characterization
Euro Solari, Stefania De Angelis, Carlo Floriani, Angiola Chiesi-Villa, and Carlo Guastini
pp 141 - 144; DOI:
10.1021/ic00027a028
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Metathetical and reductive deintercalation of .alpha.-zirconium phosphate derivatives
Guy L. Rosenthal and James Caruso
pp 144 - 145; DOI:
10.1021/ic00027a029
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Homonuclear phosphorus-31 J-resolved 2D spectra of rhodium(I) phosphine complexes in the solid state
Gang Wu and Roderick E. Wasylishen
pp 145 - 148; DOI:
10.1021/ic00027a030
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Reactions of hydrogen or deuterium molecule with a rhodium(II) metalloradical: kinetic evidence for a four-centered transition state
Bradford B. Wayland, Sujuan Ba, and Alan E. Sherry
pp 148 - 150; DOI:
10.1021/ic00027a031
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Infrared spectroscopic study on the hydration of mercury(II), cadmium(II), and zinc(II) in aqueous solution and in the hexahydrated perchlorate salts
Pehr Aake Bergstroem, Jan Lindgren, Magnus Sandstroem, and Yixin Zhou
pp 150 - 152; DOI:
10.1021/ic00027a032
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Issue 2


N-methylimidazole-promoted reactions of iron and nickel carbonyls with chalcogens: interconversions of iron polysulfide complexes and the structure of [FeSe8(CO)2]2-
Thomas B. Rauchfuss, Somanath Dev, and Scott R. Wilson
pp 153 - 154; DOI:
10.1021/ic00028a001
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Stability and structure of C12B24N24: a hybrid analog of buckminsterfullerene
James R. Bowser, Daniel A. Jelski, and Thomas F. George
pp 154 - 156; DOI:
10.1021/ic00028a002
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Push effect on the heterolytic oxygen-oxygen bond cleavage of peroxoiron(III) porphyrin adducts
Kazuya Yamaguchi, Yoshihito Watanabe, and Isao Morishima
pp 156 - 157; DOI:
10.1021/ic00028a003
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Environmentally induced multiple intervalence transitions in a symmetrically substituted analog of the Creutz-Taube ion
Jody A. Roberts and Joseph T. Hupp
pp 157 - 160; DOI:
10.1021/ic00028a004
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Synthesis and structural characterization of a novel sulfur-bridged cobalt(III)nickel(II)cobalt(III) complex [Ni{Co(aet)2(en)}2]4+ (aet = 2-aminoethanethiolate; en = ethylenediamine): ligand transfer from the nickel(II) to the cobalt(III) coordination sphere
Takumi Konno, Kenichi Okamoto, and Jinsai Hidaka
pp 160 - 161; DOI:
10.1021/ic00028a005
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An unusual species containing the mixed-valence [VIII(.mu.-N)VIV]4+ core obtained by reductive decomposition of Me3SiN3: [VBr2(N3)(dmpe)(.mu.-N)VBr(dmpe)2]
David B. Sable and William H. Armstrong
pp 161 - 163; DOI:
10.1021/ic00028a006
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Photocatalytic oxidation of organic compounds by polyoxometalates of molybdenum and tungsten. Catalyst regeneration by dioxygen
A. Hiskia and E. Papaconstantinou
pp 163 - 167; DOI:
10.1021/ic00028a007
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Mechanistic studies of the oxidative cleavage of the molybdenum-mercury bonds in [CpMo(CO)2(PPh3)]2Hg
Chen C. Lin and Stephen L. Gipson
pp 167 - 172; DOI:
10.1021/ic00028a008
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Intramolecular energy transfer in ruthenium(II)-chromium(III) chromophore-luminophore complexes. Ru(bpy)2[Cr(cyclam)(CN)2]24+
Carlo Alberto Bignozzi, Olga Bortolini, Claudio Chiorboli, Maria Teresa Indelli, Maria Anita Rampi, and Franco Scandola
pp 172 - 177; DOI:
10.1021/ic00028a009
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Carbon-13 CP-MAS, carbon-13 and proton NMR spectroscopic study of mixed-valence 1,1''-biruthenocenium salts
Masanobu Watanabe, Toschitake Iwamoto, Satoshi Kawata, Atsushi Kubo, Hirotoshi Sano, and Izumi Motoyama
pp 177 - 182; DOI:
10.1021/ic00028a010
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Ethene-exchange kinetics of palladium(II) and platinum(II) chloro ethene complexes
Anders Olsson and Pauli Kofod
pp 183 - 186; DOI:
10.1021/ic00028a011
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Kinetics and mechanisms of ligand-substitution reactions at tetrahedral bis(diimine)copper(I) complexes in acetone and methanol
Urs M. Frei and Gerhard Geier
pp 187 - 190; DOI:
10.1021/ic00028a012
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Comparison of the influence of saturated nitrogen and sulfur donor atoms on the properties of copper(II/I)-macrocyclic polyamino polythiaether ligand complexes: redox potentials and protonation and stability constants of CuIL species and new structural data
M. Margarida Bernardo, Mary Jane Heeg, Ronald R. Schroeder, L. A. Ochrymowycz, and D. B. Rorabacher
pp 191 - 198; DOI:
10.1021/ic00028a013
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Synthesis and properties of isostructural transition-metal (copper, nickel, cobalt, and iron) compounds with 7,7',8,8'-tetracyanoquinodimethanide(1-) in an unusual monodentate coordination mode: crystal structure of bis(3,5-bis(pyridin-2-yl)-4-amino-1,2,4-triazole)bis(7,7',8,8'-tetracyanoquinodimethanido)copper(II)
Joost P. Cornelissen, John H. Van Diemen, Lucas R. Groeneveld, Jaap G. Haasnoot, Anthony L. Spek, and Jan Reedijk
pp 198 - 202; DOI:
10.1021/ic00028a014
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Exodentate versus endodentate coordination of a crown thioether ligand in silver(I) complexes of 2,5,8-trithia[9]-o-benzenophane (TT[9]OB). Structures of [Ag(TT[9]OB)2][X] (X = ClO4, BPh4, CF3SO3)
Broer De Groot, Hilary A. Jenkins, and Stephen J. Loeb
pp 203 - 208; DOI:
10.1021/ic00028a015
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Halogenated derivatives of the dimolybdenum tetraphosphoxane cage
Mark M. Turnbull, Carmen Valdez, Edward H. Wong, Eric J. Gabe, and Florence L. Lee
pp 208 - 214; DOI:
10.1021/ic00028a016
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Intermediates in the diastereoselective formation of bis(phosphino)amines
Timothy R. Prout, Tomasz W. Imiolczyk, R. Curtis Haltiwanger, Tara G. Hill, and Arlan D. Norman
pp 215 - 221; DOI:
10.1021/ic00028a017
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EPR and absorption spectra of singly reduced mono- and dinuclear diorganoplatinum complexes of heterocyclic .alpha.-diimines
Paul S. Braterman, Jae Inh Song, Conny Vogler, and Wolfgang Kaim
pp 222 - 224; DOI:
10.1021/ic00028a018
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Chemistry of sulfur halides. 50. Preparation of the fluorosulfonium hexafluorometalates CH3S(H)F+MF6- and CF3S(H)F+MF6- and the chlorofluoromethylsulfonium salts CH3S(Cl)F+MF6- (M = As, Sb)
Rolf Minkwitz and Gabriele Nowicki
pp 225 - 227; DOI:
10.1021/ic00028a019
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Preparation and characterization polyborazines
J. Bai, K. Niedenzu, J. Serwatowska, and J. Serwatowski
pp 228 - 233; DOI:
10.1021/ic00028a020
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Aqueous proton NMR relaxation enhancement by manganese(II) macrocyclic complexes: structure-relaxivity relationships
Susan C. Jackels, Melinda M. Durham, James E. Newton, and Todd C. Henninger
pp 234 - 239; DOI:
10.1021/ic00028a021
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Oxdiation reactions of [Fe4S4(S-2,4,6-(iso-Pr)3C6H2)4]2- and an oxidative conversion of the Fe4S4 core into an Fe3S4 center
E. K. H. Roth and J. Jordanov
pp 240 - 243; DOI:
10.1021/ic00028a022
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Carbon-13 nuclear magnetic resonance spectroscopic study of dodecacarbonyltriiron and -triruthenium supported on metal oxide surfaces
Linda Reven and Eric Oldfield
pp 243 - 252; DOI:
10.1021/ic00028a023
PDF
A reversible molecular oxygen binding system: pentacyanocobaltate(3-) inside zeolite Y
Robert J. Taylor, Russell S. Drago, and John P. Hage
pp 253 - 258; DOI:
10.1021/ic00028a024
PDF
Two-electron reduction of carbon disulfide at a triply bonded dirhenium(II) center with preservation of the dimetal unit
Ju Sheng Qi, Paul W. Schrier, Phillip E. Fanwick, and Richard A. Walton
pp 258 - 262; DOI:
10.1021/ic00028a025
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Redox-responsive molybdenum mononitrosyl complexes incorporating cyclic polyether cation binding sites and x-ray crystal structure of [Mo(NO){HB(3,5-Me2C3N2H)3}{OCH2(CH2OCH2)3CH2O}]
Najat J. AlObaidi, Sithy S. Salam, Paul D. Beer, Christopher D. Bush, Thomas A. Hamor, Ferida S. McQuillan, Christopher J. Jones, and Jon A. McCleverty
pp 263 - 267; DOI:
10.1021/ic00028a026
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Synthesis, structure, and characterization of lanthanacarboranes. Molecular structures of [closo-1,1,1-(MeCN)3-1,2,4-EuC2B10H12].infin. and [1,1-(THF)2-commo-1,1'-Eu(1,2,4-EuC2B10H12)2]2-
Rajesh Khattar, Mark J. Manning, Carolyn B. Knobler, Stephen E. Johnson, and M. Frederick Hawthorne
pp 268 - 273; DOI:
10.1021/ic00028a027
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Preparation, characterization, and x-ray crystal structures of S2I4(MF6)2 (M = As, Sb) and the electronic structure of the highly .pi.-bonded eclipsed disulfur tetraiodine(2+) cation: thermodynamic considerations and the nonexistence of SI3AsF6(s)
Michael P. Murchie, James P. Johnson, Jack Passmore, George W. Sutherland, Mahmoud Tajik, Thomas K. Whidden, Peter S. White, and Friedrich Grein
pp 273 - 283; DOI:
10.1021/ic00028a028
PDF
Intermolecular versus intramolecular exchange interactions. Magnetic properties of (tetraacetylethanato(2-))bis((N,N,N',N'-tetramethylethylenediamine)copper(II)) diperchlorate hydrate (I) and of (tetraacetylethanato(2-))bis((N,N,N',N'-tetramethylethylenediamine)copper(II)) bis(tetraphenylborate) hydrate (II). Crystal and molecular structure of (I)
Jean Pierre Costes, Francoise Dahan, and Jean Pierre Laurent
pp 284 - 289; DOI:
10.1021/ic00028a029
PDF
A molecular mechanics model of ligand effects. 2. Binding of phosphines to pentacarbonylchromium
Kevin J. Lee and Theodore L. Brown
pp 289 - 294; DOI:
10.1021/ic00028a030
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Anisotropic exchange and dimerization in the ordered bimetallic chains Co2(EDTA).6H2O and CoCu(EDTA).6H2O. Single-crystal EPR investigation
Juan J. Borras-Almenar, Eugenio Coronado, Dante Gatteschi, and Claudia Zanchini
pp 294 - 298; DOI:
10.1021/ic00028a031
PDF
Temperature- and axial-ligand-dependent EPR spectra of cobalt porphyrin cation radicals: effects of mixing of the A1u and A2u states and a locally excited triplet state
Satoh Minoru, Yasunori Ohba, Seigo Yamauchi, and Masamoto Iwaizumi
pp 298 - 303; DOI:
10.1021/ic00028a032
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High-pressure infrared and micro-Raman spectra of crystalline pentacarbonyl(thiocarbonyl)chromium(0) and (.eta.-benzene)dicarbonyl(thiocarbonyl)chromium(0)
Yining Huang, Ian S. Butler, and Denis F. R. Gilson
pp 303 - 305; DOI:
10.1021/ic00028a033
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Studies on gold(II) complexes with hard and soft donor ligands. 2. Complexes with o-(methylthio)aniline and 1,2-bis((o-aminophenyl)thio)ethane
Aditya P. Koley, Sanchita Purohit, Lakkaraju S. Prasad, Saktiprosad Ghosh, and Periakaruppan T. Manoharan
pp 305 - 311; DOI:
10.1021/ic00028a034
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Determination of the magnitude and sign of the 2JPt-P coupling constants in dinuclear platinum(I) phosphine complexes by two-dimensional phosphorus-31 NMR spectroscopy
Jane V. Zeile Krevor, Ursula Simonis, Annette Karson, Claire Castro, and Mohammed Aliakbar
pp 312 - 317; DOI:
10.1021/ic00028a035
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Theoretical studies of inorganic and organometallic reaction mechanisms. 4. Oxidative addition of dihydrogen to d8 square-planar iridium complexes with trans phosphines
Andrew L. Sargent and Michael B. Hall
pp 317 - 321; DOI:
10.1021/ic00028a036
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Carbon-13 chemical shift anisotropies of the carbonyl and thiocarbonyl ligands in (.eta.-benzene)tricarbonylchromium(0) and (.eta.-benzene)dicarbonyl(thiocarbonyl)chromium(0)
Yining Huang, Denis F. R. Gilson, Ian S. Butler, and Frederick G. Morin
pp 322 - 323; DOI:
10.1021/ic00028a037
PDF
Carbonylchlorobis(tri-tert-butylphosphine)rhodium: a simple rhodium(I) complex which is not square-planar?
Richard L. Harlow, Stephen A. Westcott, David L. Thorn, and R. Thomas Baker
pp 323 - 326; DOI:
10.1021/ic00028a038
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Role of phosphine ligands in gold cluster chemistry. Relativistic SCF calculations on Au2 and Au2(PH3)2
Peter Schwerdtfeger and Peter D. W. Boyd
pp 327 - 329; DOI:
10.1021/ic00028a039
PDF
Difluorodinitrosomethane, ONCF2NO, and hexafluorodinitrosopropane, ONCF2CF2CF2NO
Earnest O. John, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 329 - 331; DOI:
10.1021/ic00028a040
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Synthesis and structural characterization of the nitrido-carbonyl cluster anion [Co7N(CO)15]2-, possessing a carbonyl stereochemistry different from that of its rhodium analog
G. Ciani, N. Masciocchi, A. Sironi, A. Fumagalli, and S. Martinengo
pp 331 - 333; DOI:
10.1021/ic00028a041
PDF
Synthesis and coordination properties with copper(I) triflate of 1,1'-dimethyl-P-phenyl-2,2'-bis(ferrocenylmethylene)phosphonothioic dihydrazide
Beatrice Delavaux-Nicot, Noel Lugan, Rene Mathieu, and Jean Pierre Majoral
pp 334 - 336; DOI:
10.1021/ic00028a042
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Mixed platinum-rhodium carbonyl clusters. The isolation of [Pt4Rh18(CO)35]4-, an example of a cherry-like cluster with a semiexposed tetraplatinum core
Alessandro Fumagalli, Secondo Martinengo, Gianfranco Ciani, Norberto Masciocchi, and Angelo Sironi
pp 336 - 340; DOI:
10.1021/ic00028a043
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Reactivity of molecules containing element-element bonds. 2. Transition elements [Erratum to document cited in CA114(15):143614m]
Fausto Calderazzo, Alberto Juris, Rinaldo Poli, and Fausto Ungari
pp 340 - 340; DOI:
10.1021/ic00028a044
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Deoxygenation of carbon dioxide to diethylformamide in the zinc/diethylamine/carbon dioxide system. Crystal and molecular structure of hexakis (diethylcarbamato)oxotetrazinc [Erratum to document cited in CA115(14):148929y]
Antonio Belforte, Fausto Calderazzo, Ulli Englert, and Joachim Straehle
pp 340 - 340; DOI:
10.1021/ic00028a045
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Issue 3


A linear triiron core structure consisting of fused (.mu.-hydroxo)bis(.mu.-carboxylato)diiron(III) "kernels"
Vivian A. Vankai, M. Gary Newton, and Donald M. Kurtz
pp 341 - 343; DOI:
10.1021/ic00029a001
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Synthesis and crystal structure of a vanadium(V) complex with a 2-hydroxy acid ligand, (NH4)2[V(OC(CH2CH3)2COO)(O)2]2: a structural model of both vanadium(V) transferrin and ribonuclease complexes with inhibitors
Trevor W. Hambley, Robert J. Judd, and Peter A. Lay
pp 343 - 345; DOI:
10.1021/ic00029a002
PDF
Kinetics and mechanism of the complex formation reactions of diaqua(ethylenediamine)- and diaqua(tetraethylethylenediamine)palladium(II) with the purine nucleosides adenosine and inosine
Heribert Hohmann, Bjoern Hellquist, and Rudi Van Eldik
pp 345 - 351; DOI:
10.1021/ic00029a003
PDF
Polarized specular reflectance spectra of the partially oxidized phthalocyanines Cu(pc)I and H2(pc)I compared with those of Co(pc)I and Ni(pc)I: metal-based charge-transfer transitions in one-dimensional conductors
Dean E. Rende, Michael D. Heagy, William B. Heuer, Kwangkyoung Liou, Julia A. Thompson, Brian M. Hoffman, and Ronald L. Musselman
pp 352 - 358; DOI:
10.1021/ic00029a004
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2D NMR studies of paramagnetic diiron complexes
Li June Ming, Ho G. Jang, and Lawrence Que
pp 359 - 364; DOI:
10.1021/ic00029a005
PDF
Crystal structure of the ternary complex between carboxypeptidase A, L-phenylalanine, and the azide ion
Stefano Mangani and Pierluigi Orioli
pp 365 - 368; DOI:
10.1021/ic00029a006
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Synthesis, structure, and properties of [Mn(salpn)(EtOH)2](ClO4) and its aerobic oxidation product [Mn(salpn)O]2
Joel W. Gohdes and William H. Armstrong
pp 368 - 373; DOI:
10.1021/ic00029a007
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Manganese-manganese separations in oxide- and alkoxide-bridged complexes: correlation of structure with ligand type and number
Erlund Larson, Myoung Soo Lah, Xinhua Li, Joseph A. Bonadies, and Vincent L. Pecoraro
pp 373 - 378; DOI:
10.1021/ic00029a008
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Late-transition-metal .mu.-oxo and .mu.-imido complexes. 8. Rhodium imido/amido coupling reactions with carbon monoxide
Yuan Wen Ge and Paul R. Sharp
pp 379 - 384; DOI:
10.1021/ic00029a009
PDF
Ortho-metalation reactions in binuclear dirhodium compounds. Molecular structure and reactivity of a monometalated compound with the phosphine P(o-ClC6H4)(C6H5)2
Pascual Lahuerta, Jorge Paya, Xavier Solans, and M. Angeles Ubeda
pp 385 - 391; DOI:
10.1021/ic00029a010
PDF
Mono- and dinuclear complexes of platinum(II) with chiral diphosphines: Pt(P-P')Cl2 and [Pt(P-P')(.mu.-OH)]2[BF4]2(P-P' = prolophos, N-(diphenylphosphino)-2-((diphenylphoshpinoxy)methyl)pyrrolidine, and butaphos, 1-(diphenylphosphinoxy)-2-(N-ethyl-N-(diphenylphosphino)amino)butane). Crystal and molecular structure of P{S-prolophos-P,P'}Cl2
Anna Laura Bandini, Guido Banditelli, Edoardo Cesarotti, Giovanni Minghetti, and Bruna Bovio
pp 391 - 398; DOI:
10.1021/ic00029a011
PDF
Phosphido-bridged, heterodi-, heterotri-, and heterotetranuclear complexes of palladium and platinum with transition metals. Crystal structure of [{(OC)4Mn(.mu.-PPh2)}2Pt(PPh3)] (Mn-Mn, 2 Mn-Pt)
Pierre Braunstein, Ernesto De Jesus, Alain Dedieu, Maurizio Lanfranchi, and Antonio Tiripicchio
pp 399 - 410; DOI:
10.1021/ic00029a012
PDF
Electrophilic additions to phosphido-bridged palladium- and platinum-transition-metal bonds. Synthesis and crystal structure of the heterotetranuclear cluster [cyclic] [{Cp(OC)2W(.mu.-CO)(.mu.-PPh2)}{Cp(OC)2W(.mu.-AuPPh3)(.mu.-PPh2)}Pt][PF6].cntdot.2THF (Au-Pt, Au-W, 2W-Pt)
Pierre Braunstein, Ernesto De Jesus, Antonio Tiripicchio, and Franco Ugozzoli
pp 411 - 418; DOI:
10.1021/ic00029a013
PDF
Synthesis and reactivity of chiral metal fluoride and water complexes derived from the rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+
Sename K. Agbossou, Christophe Roger, Alain Igau, and J. A. Gladysz
pp 419 - 424; DOI:
10.1021/ic00029a014
PDF
Chemistry of copper(I) .beta.-diketonate complexes. 2. Synthesis, characterization, and physical properties of (.beta.-diketonato)copper(I) trimethylphosphine and bis(trimethylphosphine) complexes
H. K. Shin, K. M. Chi, J. Farkas, M. J. Hampden-Smith, T. T. Kodas, and E. N. Duesler
pp 424 - 431; DOI:
10.1021/ic00029a015
PDF
Hydrothermal polychalcogenide chemistry. Stabilization of selenidomolybdate, [Mo9Se40]8-, a cluster of clusters, and [Mo3Se18]n2n- a polymeric polyselenide. Novel phases based on trinuclear [Mo3Se7]4+ building blocks
Ju Hsiou Liao and Mercouri G. Kanatzidis
pp 431 - 439; DOI:
10.1021/ic00029a016
PDF
Hydrothermal synthesis and structural characterization of two calcium vanadium(III) phosphates: Ca2V(PO4)(HPO4)2.cntdot.H2O and Ca2V(PO4)(P2O7)
K. H. Lii, N. S. Wen, C. C. Su, and B. R. Chueh
pp 439 - 442; DOI:
10.1021/ic00029a017
PDF
1,4-Phenylene-bridged 1,3,2,4,6-thia- and 1,3,2,4,6-selenaphosphatriazinyl diradicals: preparation, spin distributions, and solid-state structures
Ketut Bestari, George Ferguson, John F. Gallagher, and Richard T. Oakley
pp 442 - 447; DOI:
10.1021/ic00029a018
PDF
Synthesis and characterization of chiral 18-membered-macrocycle-lanthanide complexes: circular dichroism and circularly polarized luminescence
Taro Tsubomura, Koichi Yasaku, Takayuki Sato, and Makoto Morita
pp 447 - 450; DOI:
10.1021/ic00029a019
PDF
Electronic structure of monodentate-coordinated diphosphine complexes. Photoelectron spectra of pentacarbonylmethylene bis(dimethyl phosphine)molybdenum and pentacarbonylethylene bis(dimethyl phosphine)molybdenum
Dennis L. Lichtenberger and Mark E. Jatcko
pp 451 - 455; DOI:
10.1021/ic00029a020
PDF
Electronic, infrared, Raman, and resonance Raman spectroscopy of the dirhodium tetrakis(thiocarboxylate) complexes Rh2(OSCCH3)4L2 (L = PPh3, AsPh3, SbPh3, CH3COSH)
Robin J. H. Clark, David J. West, and Robert Withnall
pp 456 - 459; DOI:
10.1021/ic00029a021
PDF
XANES spectra of copper(II) complexes: correlation of the intensity of the 1s .fwdarw. 3d transition and the shape of the complex
Mitsuru Sano, Seiko Komorita, and Hideo Yamatera
pp 459 - 463; DOI:
10.1021/ic00029a022
PDF
Characterization of matrix-isolated carbonylchlorocopper. IR spectroscopic investigation and ab initio calculation
Harald S. Plitt, Michael R. Baer, Reinhart Ahlrichs, and Hansgeorg Schnoeckel
pp 463 - 465; DOI:
10.1021/ic00029a023
PDF
Boron in new environments. Structure and reaction properties of discrete, mixed-metal, hexanuclear borides
A. K. Bandyopadhyay, Rajesh Khattar, J. Puga, T. P. Fehlner, and A. L. Rheingold
pp 465 - 472; DOI:
10.1021/ic00029a024
PDF
Synthesis, structure, and reactivity of homoleptic cerium(IV) and cerium(III) alkoxides
Ayusman Sen, Hilmar A. Stecher, and Arnold L. Rheingold
pp 473 - 479; DOI:
10.1021/ic00029a025
PDF
Syntheses, structure, and reactivity of cobalt and nickel complexes of 1,4,7-trithiacyclodecane: self-exchange rates for Co(S6)2+/3+ couples from cobalt-59 NMR spectroscopy
S. Chandrasekhar and A. McAuley
pp 480 - 487; DOI:
10.1021/ic00029a026
PDF
Synthesis and reactions of fluoroalkyl polynitrogen compounds
Yuan Yang Zheng, Nimesh R. Patel, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 488 - 491; DOI:
10.1021/ic00029a027
PDF
Perhaloalkanesulfinyl chlorides, RfS(O)Cl, and perhaloalkanesulfinate esters, RfS(O)ORf'
Yuan Fa Zhang, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 492 - 494; DOI:
10.1021/ic00029a028
PDF
Synthesis and characterization of redox polymers of [M(4-vinyl-4'-methyl-2,2'-bipyridine)3](PF6)2 (M = Ru, Os)
S. L. Bommarito, S. P. Lowery-Bretz, and H. D. Abruna
pp 495 - 502; DOI:
10.1021/ic00029a029
PDF
Synthesis and characterization of redox copolymers of tris(4-vinyl-4'-methyl-2,2'-bipyridine)ruthenium(2+) and tris(4-vinyl-4'-methyl-2,2'-bipyridine)osmium(2+): unusual energy-transfer dynamics
S. L. Bommarito, S. P. Lowery-Bretz, and H. D. Abruna
pp 502 - 507; DOI:
10.1021/ic00029a030
PDF
Kinetics of the aqueous cobalt(II)/cobalt(III)/EDTA system at variable pressure
William H. Jolley, Donald R. Stranks, and Thomas W. Swaddle
pp 507 - 511; DOI:
10.1021/ic00029a031
PDF
Solution IR spectroscopic studies of cis-dioxomolybdenum(VI) complexes
Joseph Topich and John O. Bachert
pp 511 - 515; DOI:
10.1021/ic00029a032
PDF
Photochemical behavior of trans-[Ru(NH3)4P(OEt)3L]2+ complex ions (L = P(OEt)3, CO, H2O)
Selma Elaine Mazzetto, Lidia Maria de Almeida Plicas, Elia Tfouni, and Douglas Wagner Franco
pp 516 - 519; DOI:
10.1021/ic00029a033
PDF
Convenient synthesis, structure and properties of trichloro(hydrotripyrazolylborato)ferrate(1-)
Sung Hee Cho, Dongmok Whang, Kyu Nam Han, and Kimoon Kim
pp 519 - 522; DOI:
10.1021/ic00029a034
PDF
The germanium-tin bond. Structures of the isomeric complexes Me3E-E'Ph3 (E = Ge, E' = Sn; E = Sn, E' = Ge)
Keith H. Pannell, Laszlo Parkanyi, Hemant Sharma, and Francisco Cervantes-Lee
pp 522 - 524; DOI:
10.1021/ic00029a035
PDF
Metal complexes with tetrapyrrole ligands. 62. Carbon-13 NMR spectra of dicerium(III) and dipraseodymium(III) tris(octaethylporphyrinate)
Johann W. Buchler, Juergen Loeffler, and Mark Wicholas
pp 524 - 526; DOI:
10.1021/ic00029a036
PDF
A linear relationship between the sulfur-nitrogen bond enthalpy term and bond length and an assessment of the reliability of empirical length-strength relationships in the estimation of thermochemical properties of sulfur-nitrogen compounds
Simon Parsons and Jack Passmore
pp 526 - 528; DOI:
10.1021/ic00029a037
PDF

Issue 4


Synthesis and x-ray characterization of a uranyl(VI) Schiff base complex derived from a 2:2 condensation product of 3,4-diethylpyrrole-2,5-dicarbaldehyde and 1,2-diamino-4,5-dimethoxybenzene
Jonathan L. Sessler, Tarak D. Mody, and Vincent Lynch
pp 529 - 531; DOI:
10.1021/ic00030a001
PDF
Luminescent supramolecular architectures: a cyclodextrin modified with a europium(III) crown swing
Zoe Pikramenou and Daniel G. Nocera
pp 532 - 536; DOI:
10.1021/ic00030a002
PDF
Variable-temperature and -pressure multinuclear magnetic resonance study of solvent exchange at the tris(ethylenediamine)nickel(II) ion in ethylenediamine
Sayo Soyama, Masao Ishii, Shigenobu Funahashi, and Motoharu Tanaka
pp 536 - 538; DOI:
10.1021/ic00030a003
PDF
Photochemistry of chromium(III) ammine compounds: an ab initio study
L. G. Vanquickenborne, B. Coussens, D. Postelmans, A. Ceulemans, and K. Pierloot
pp 539 - 547; DOI:
10.1021/ic00030a004
PDF
Photoexcited states of biruthenium(II) compounds bridged by 2,2'-bis(2-pyridyl)bibenzimidazole or 1,2-bis(2-(2-pyridyl)benzimidazolyl)ethane
Takeshi Ohno, Koichi Nozaki, and Masaaki Haga
pp 548 - 555; DOI:
10.1021/ic00030a005
PDF
Electronic absorption spectra of the iron(II) complexes of 2,2'-bipyridine, 2,2'-bipyrimidine, 1,10-phenanthroline, and 2,2':6',2''-terpyridine and their reduction products
Paul S. Braterman, Jae Inh Song, and Robert D. Peacock
pp 555 - 559; DOI:
10.1021/ic00030a006
PDF
Influence of coligands on the .eta.1-coordination mode of sulfur dioxide in L3NiSO2 complexes. A pseudopotential ab initio study
Joachim Reinhold, Matthias Schueler, Thomas Hoffmann, and Eberhard Wenschuh
pp 559 - 562; DOI:
10.1021/ic00030a007
PDF
Theoretical investigation of the electronic and structural properties of pentagonal-bipyramidal complexes. 1. Diaqua(2,6-diacetylpyridine)bis(semicarbazone))iron(II)
Shaun O. Sommerer, John David Baker, M. C. Zerner, and G. J. Palenik
pp 563 - 567; DOI:
10.1021/ic00030a008
PDF
Chemical bonding in rutile-type compounds
Peter I. Sorantin and Karlheinz Schwarz
pp 567 - 576; DOI:
10.1021/ic00030a009
PDF
A molecular orbital study of bonding and ionization energies in pentavalent uranium imide/amide complexes
G. A. Bowmaker, A. Goerling, O. Haeberlen, N. Roesch, G. L. Goodman, and D. E. Ellis
pp 577 - 581; DOI:
10.1021/ic00030a010
PDF
Rearrangements in square-planar and square-pyramidal complexes of palladium(II) and platinum(II) containing the enantiomers of (.+-.)-methylphenyl(8-quinolyl)arsine and its phosphorus analog
Geoffrey Salem and S. Bruce Wild
pp 581 - 586; DOI:
10.1021/ic00030a011
PDF
Products of partial oxidative decarbonylation of tricarbonyl{hydrotris(3,5-dimethyl-1-pyrazolyl)borato}tungstate(0) by tetraalkylthiuram disulfides: {HB(Me2C3N2H)3}W(CO)2(S2CNEt2), mixed-valence {HB(Me2C3N2H)3}WII(CO)2(.mu.-S)WIV(S2CNEt2)2(SCNEt2), and related complexes
Charles G. Young, Michael A. Bruck, Pamela A. Wexler, Michael D. Carducci, and John H. Enemark
pp 587 - 593; DOI:
10.1021/ic00030a012
PDF
Products of complete oxidative decarbonylation of tricarbonyl{hydrotris(3,5-dimethyl-1-pyrazolyl)borato}tungstate(0) by tetraalkylthiuram disulfides: {HB(Me2C3N2H)3}WS(S2CNEt2), W2(.mu.-S)2(S2CNEt2)4, and [W(S2CNEt2)4]+
Charles G. Young, Michael A. Bruck, and John H. Enemark
pp 593 - 598; DOI:
10.1021/ic00030a013
PDF
Studies of fluorinated 1,3-diketones and related compounds. 17. Benzoic acid hydrazide derivatives of 1,3-diketones and their nickel complexes. Molecular structures of [cyclic]C6H5C(:O)NN:C(p-FC6H4)CH2C(OH)(p-FC6H4) and [cyclic][C6H5C(O):NN:C(p-FC6H4)CH:C(O)(p-FC6H4)-O,N]Ni(NH3)
Krishna C. Joshi, Rakesh Bohra, and Bidya S. Joshi
pp 598 - 603; DOI:
10.1021/ic00030a014
PDF
Metal ion complexes of water-soluble calix[4]arenes
Jerry L. Atwood, G. William Orr, N. Carlene Means, Fumio Hamada, Hongming Zhang, Simon G. Bott, and Kerry D. Robinson
pp 603 - 606; DOI:
10.1021/ic00030a015
PDF
Cooperative effects in .pi.-ligand-bridged dinuclear complexes. 11. Three different positional isomers of paramagnetic (.mu.-[.eta.7:7-bi(cyclooctatrienyl)])bis[(.eta.5-cyclopentadienyl)vanadium]: strong influence on magnetic properties caused by the different kinds of linkages
Bernd Bachmann, Juergen Heck, Gerd Meyer, Juergen Pebler, and Thomas Schleid
pp 607 - 614; DOI:
10.1021/ic00030a016
PDF
Two novel phases containing centered, isolated zirconium clusters, Rb4Zr6Cl18C and Li6Zr6Cl18H
Jie Zhang, Robin P. Ziebarth, and John D. Corbett
pp 614 - 619; DOI:
10.1021/ic00030a017
PDF
Molecular structure and chemical and electrochemical reactivity of tetrakis(N,N'-diphenylbenzamidinato)dicobalt and -dirhodium
L. P. He, C. L. Yao, M. Naris, J. C. Lee, J. D. Korp, and J. L. Bear
pp 620 - 625; DOI:
10.1021/ic00030a018
PDF
Weak ferromagnetism in the molecular compound Cu(ta)(3-pic).cntdot.H2O(ta=terephthalato,3-pic=3-picoline). Crystal structure of Cu(ta)(3-pic)2.cntdot.0.5(3-pic).cntdot.0.5CH3OH
Evangelos Bakalbassis, Pierre Bergerat, Olivier Kahn, Suzanne Jeannin, Yves Jeannin, Yves Dromzee, and Maurice Guillot
pp 625 - 631; DOI:
10.1021/ic00030a019
PDF
Platinum(IV) complexes of a tetraaza macrocycle with pendent dichloroamine or ammonium groups
Paul V. Bernhardt, Geoffrey A. Lawrance, and Trevor W. Hambley
pp 631 - 634; DOI:
10.1021/ic00030a020
PDF
Activation of the trans geometry in platinum antitumor complexes. Synthesis, characterization, and biological activity of complexes with the planar ligands pyridine, N-methylimidazole, thiazole, and quinoline. Crystal and molecular structure of trans-dichlorobis(thiazole)platinum(II)
Marijo Van Beusichem and Nicholas Farrell
pp 634 - 639; DOI:
10.1021/ic00030a021
PDF
Syntheses and electrochemistry of incomplete cubane-type clusters with M3S4 cores (M = molybdenum, tungsten). X-ray structures of [W3S4(H2O)9](CH3C6H4SO3)4.cntdot.9H2O, Na2[W3S4(Hnta)3].cntdot.5H2O, and (bpyH)5[W3S4(NCS)9].cntdot.3H2O
Takashi Shibahara, Mikio Yamasaki, Genta Sakane, Kenichi Minami, Toru Yabuki, and Akio Ichimura
pp 640 - 647; DOI:
10.1021/ic00030a022
PDF
Tungsten-183 NMR studies of tungstate complexes of carbohydrates. 1. Characterization of two structural types in the alditol series. Evidence that the tungstate and molybdate threo complexes are not homologous
Stella Chapelle and Jean Francois Verchere
pp 648 - 652; DOI:
10.1021/ic00030a023
PDF
Mercury(II) reactions with water-soluble porphyrins
Louis R. Robinson and Peter Hambright
pp 652 - 656; DOI:
10.1021/ic00030a024
PDF
Thermo- and photoaquation of trans dicyanobis(1,3-diaminopropane)chromium(1+) perchlorate. Quenching of photochemistry by photoproducts
Alexander David Kirk and S. Rupasiri L. Fernando
pp 656 - 661; DOI:
10.1021/ic00030a025
PDF
Kinetic investigation of halide substitution in the 17-electron MoCpX2(PMe3)2 system
Rinaldo Poli, Beth E. Owens, and Robert G. Linck
pp 662 - 667; DOI:
10.1021/ic00030a026
PDF
Ligand effects on the photoaquation of tetrakis(amine)rhodium(III) complexes [Rh(L)4XY]+
Mariel M. Muir and Sergio Sanchez
pp 667 - 669; DOI:
10.1021/ic00030a027
PDF
Syntheses and structures of [M(CO)5{B2H4.cntdot.2P(CH3)3}] and [M(CO)4{B2H4.cntdot.2P(CH3)3}] (M = chromium, molybdenum, tungsten)
Kinji Katoh, Mamoru Shimoi, and Hiroshi Ogino
pp 670 - 675; DOI:
10.1021/ic00030a028
PDF
Synthesis and molecular structures of nickel(II) alkyl-substituted cyclam complexes
Kazuya Kobiro, Atsuyoshi Nakayama, Toshitaka Hiro, Mitsuhito Suwa, and Yoshito Tobe
pp 676 - 685; DOI:
10.1021/ic00030a029
PDF
Coordination chemistry of ammonia on zinc oxide(0001) and cuprous chloride(111) surfaces: .sigma.-bonding interactions with d10 metal ion sites
Jianyi Lin, Paul M. Jones, Michael D. Lowery, Robert R. Gay, Susan L. Cohen, and Edward I. Solomon
pp 686 - 695; DOI:
10.1021/ic00030a030
PDF
Silver and gold dimers. Crystal and molecular structure of Ag2(dmpm)2Br2 and [Au2(dmpm)2](PF6)2 and relation between metal-metal force constants and metal-metal separations
Daniel Perreault, Marc Drouin, Andre Michel, Vincent M. Miskowski, William P. Schaefer, and Pierre D. Harvey
pp 695 - 702; DOI:
10.1021/ic00030a031
PDF
Electron transfer. 111. Disproportionation of carboxylato-bound chromium(IV). Catalysis by manganese(II)
M. C. Ghosh, E. Gelerinter, and E. S. Gould
pp 702 - 705; DOI:
10.1021/ic00030a032
PDF
Reactivity of the diboron tetrahalides. Diboration of ethylene with diboron tetrabromide and thermal decomposition and ligand exchanges of diboron tetrabromide and diboron tetrachloride in carbon tetrabromide and carbon tetrachloride
L. Ahmed, J. Castillo, D. A. Saulys, and J. A. Morrison
pp 706 - 710; DOI:
10.1021/ic00030a033
PDF
Magnetochemistry of the tetrahaloferrate(III) ions. 4. Heat capacity and magnetic ordering in bis[4-chloropyridinium tetrachloroferrate(III)]-4-chloropyridinium chloride
Roey Shaviv and Richard L. Carlin
pp 710 - 712; DOI:
10.1021/ic00030a034
PDF
A convenient synthesis of tricyclo[3.3.1.13,7]tetrasilathianes and tricyclo[3.3.1.13,7]tetrasilaselenanes
Steven R. Bahr and Philip Boudjouk
pp 712 - 713; DOI:
10.1021/ic00030a035
PDF
Synthesis, structure, and properties of a [manganese] complex that consists of an {Mn2O2(O2CCH3)}2+ core and a spanning hexadentate ligand
Samudranil Pal, Joel W. Gohdes, Wolf Christian A. Wilisch, and William H. Armstrong
pp 713 - 716; DOI:
10.1021/ic00030a036
PDF
Crystal and molecular structure of dimeric bis[N,N-di-n-propyldithiocarbamato]zinc(II) and the study of exchange-coupled copper(II)-copper(II) pairs in its lattice. [Erratum to document cited in CA113(18):162998k]
N. Sreehari, Babu Varghese, and P. T. Manoharan
pp 716 - 716; DOI:
10.1021/ic00030a037
PDF
Synthesis and structure of transition-metal bis(porphyrinato) complexes. Characterization of Zr(TPP)2 and Zr(OEP)2. [Erratum to document cited in CA114(26):258485n]
Kimoon Kim, Won S. Lee, Hee Joon Kim, Sung Hee Cho, Gregory S. Girolami, Philip A. Gorlin, and Kenneth S. Suslick
pp 716 - 716; DOI:
10.1021/ic00030a038
PDF

Issue 5


Structure and properties of a bimetallic complex with a conjugated bridge between iron atoms in two macrocycles
H. Scott Mountford, Larry O. Spreer, John W. Otvos, Melvin Calvin, Karen J. Brewer, Mark Richter, and Brian Scott
pp 717 - 718; DOI:
10.1021/ic00031a001
PDF
Is intramolecular hydrogen-bonding important for bleomycin reactivity? A molecular mechanics study
Yun Dong Wu, K. N. Houk, J. S. Valentine, and Wonwoo Nam
pp 718 - 720; DOI:
10.1021/ic00031a002
PDF
Kinetics of formation and reactions of thiyl radicals in aqueous solution
Patrick Huston, James H. Espenson, and Andreja Bakac
pp 720 - 722; DOI:
10.1021/ic00031a003
PDF
Synthesis and structure of mixed-ligand iron-sulfur cubane-like clusters [(.eta.-C5Me5)3(Ph2C2S2)Fe4S5]n (n = O and 1+)
Shinji Inomata, Hiromi Tobita, and Hiroshi Ogino
pp 722 - 723; DOI:
10.1021/ic00031a004
PDF
The coordination chemistry of the C:S function. 9. Synthesis of cationic ruthenium thiobenzaldehyde complexes through .beta.-hydride abstraction
Wolfdieter A. Schenk, Thomas Stur, and Eberhard Dombrowski
pp 723 - 724; DOI:
10.1021/ic00031a005
PDF
Pentacoordinated molecules. 90. A new structural form for a pentaoxyphosphorane. Diequatorial ring formation in a trigonal bipyramid
T. K. Prakasha, Roberta O. Day, and Robert R. Holmes
pp 725 - 726; DOI:
10.1021/ic00031a006
PDF
Synthesis and characterization of aluminum-gallium pillared clays with high thermal and hydrothermal stability
F. Gonzalez, C. Pesquera, C. Blanco, I. Benito, and S. Mendioroz
pp 727 - 731; DOI:
10.1021/ic00031a007
PDF
Rectangular and hexagonal columnar mesophases in dinuclear rhodium(II) (alkyloxy)benzoate complexes
Joaquin Barbera, Miguel A. Esteruelas, Anne Marie Levelut, Luis A. Oro, Jose L. Serrano, and Eduardo Sola
pp 732 - 737; DOI:
10.1021/ic00031a008
PDF
A new preparation method of lanthanum cobalt oxide, LaCoO3, perovskite using electrochemical oxidation
Yasumichi Matsumoto, Takeshi Sasaki, and Jukichi Hombo
pp 738 - 741; DOI:
10.1021/ic00031a009
PDF
Gadolinium(III) complexes with pyridine-substituted nitronyl nitroxide radicals
Cristiano Benelli, Andrea Caneschi, Dante Gatteschi, and Luca Pardi
pp 741 - 746; DOI:
10.1021/ic00031a010
PDF
Preparation of group 15 (phosphorus, antimony, and bismuth) complexes of meso-tetra-p-tolylporphyrin (TTP) and x-ray crystal structure of [Sb(TTP)(OCH(CH3)2)2]Cl
Tanya Barbour, Warwick J. Belcher, Penelope J. Brothers, Clifton E. F. Rickard, and David C. Ware
pp 746 - 754; DOI:
10.1021/ic00031a011
PDF
Niobium telluride iodide, Nb2Te6I, a pseudo-two-dimensional compound with a new mode of transition-metal bonding for a dichalcogen group
Wolfgang Tremel
pp 755 - 760; DOI:
10.1021/ic00031a012
PDF
Two manganese(IV) complexes with isomeric MnN4O2 spheres incorporating hexadentate amide-amine-phenolate coordination
Swapan Kumar Chandra and Animesh Chakravorty
pp 760 - 765; DOI:
10.1021/ic00031a013
PDF
Using platinum(II) as a building block to two-electron redox systems. Crystal structure and redox behavior of cis-[PtII(3-ferrocenylpyridine)2Cl2]
Oliviero Carugo, Giancarlo De Santis, Luigi Fabbrizzi, Maurizio Licchelli, Alberto Monichino, and Piersandro Pallavicini
pp 765 - 769; DOI:
10.1021/ic00031a014
PDF
A new linear chain compound: crystal and magnetic structures of thallium manganese fluoride hydrate, Tl2MnF5.H2O
P. Nunez, A. Tressaud, J. Darriet, P. Hagenmuller, G. Hahn, G. Frenzen, W. Massa, D. Babel, A. Boireau, and J. L. Soubeyroux
pp 770 - 774; DOI:
10.1021/ic00031a015
PDF
Structural and magnetic studies of a syn-anti carboxylate-bridged helix-like chain copper(II) complex
Enrique Colacio, Jose Manuel Dominguez-Vera, Jean Pierre Costes, Raikko Kivekas, Jean Pierre Laurent, Jose Ruiz, and Markku Sundberg
pp 774 - 778; DOI:
10.1021/ic00031a016
PDF
Oxamidato complexes. 2. Copper(II) and nickel(II) complexes with oxamide-N,N'-diacetic acid: solution study, synthesis, crystal structures, and magnetic properties
Francesc Lloret, Jorunn Sletten, Rafael Ruiz, Miguel Julve, Juan Faus, and Michel Verdaguer
pp 778 - 784; DOI:
10.1021/ic00031a017
PDF
Oxamidato complexes. 3. A study of the formation of homo- and heteropolymetallic Cu(II)H2apoxM(II) complexes (H2apox = N,N'-bis(3-aminopropyl)oxamide; M(II) = Mn, Co, Ni, Cu, Zn, Cd). Synthesis and crystal structure of [Cu2(apox)(NCO)2]
Francesc Lloret, Miguel Julve, Juan Faus, Rafael Ruiz, Isabel Castro, Miquel Mollar, and Michele Philoche-Levisalles
pp 784 - 791; DOI:
10.1021/ic00031a018
PDF
High-pressure NMR kinetics. 52. Variable-temperature and -pressure studies of solvent exchange, complex formation, and dissociation of vanadium(III) in DMSO
Ivo Dellavia, Pierre Yves Sauvageat, Lothar Helm, Yves Ducommun, and Andre E. Merbach
pp 792 - 797; DOI:
10.1021/ic00031a019
PDF
Deamination of 2-methyl-2-propanamine induced by hydroxyl radicals and metal ions: a comparison between the rates of .beta.-elimination of ammonia and water
Sara Goldstein, Gidon Czapski, Haim Cohen, Dan Meyerstein, Jeoung Ki Cho, and Sason S. Shaik
pp 798 - 803; DOI:
10.1021/ic00031a020
PDF
Thermodynamics for the hydrogenation of dimanganese decacarbonyl
R. J. Klingler and J. W. Rathke
pp 804 - 808; DOI:
10.1021/ic00031a021
PDF
Electron-transfer reactions of cobalt(III) complexes possessing oxysulfur ligands
Michael D. Johnson and Robert J. Balahura
pp 808 - 809; DOI:
10.1021/ic00031a022
PDF
Cyanide exchange of the methyltricyanoplatinate(II) dianion: temporal resolution of cis and trans cyanide exchange
Albert Y. C. Hung, John C. Woolcock, Michael F. Rettig, and Richard M. Wing
pp 810 - 812; DOI:
10.1021/ic00031a023
PDF
Measurement and analysis of circular dichroism in the 4f-4f transitions of holmium(3+) in sodium tris(oxydiacetato)holmate(3-) bis(sodium perchlorate) hexahydrate
Diane M. Moran and F. S. Richardson
pp 813 - 818; DOI:
10.1021/ic00031a024
PDF
Chiroptical luminescence spectra of uranyl ion in cubic sodium tris(acetato)dioxouranate(1-) crystals
Diane M. Moran, David H. Metcalf, and F. S. Richardson
pp 819 - 825; DOI:
10.1021/ic00031a025
PDF
Hypercoordination in Group IV MH5 and MH5- systems
Marshall T. Carroll, Mark S. Gordon, and Theresa L. Windus
pp 825 - 829; DOI:
10.1021/ic00031a026
PDF
Excited-state properties and energy migration in [rhodium complex] [RhL2(2,2'-bipyridine)]PF6 (L = 2-phenylpyridinate(1-) or 2-thienylpyridinate(1-))
Arne Zilian and Hans U. Guedel
pp 830 - 835; DOI:
10.1021/ic00031a027
PDF
Electrochemical and spectroscopic properties of dimeric cofacial porphyrins with nonelectroactive metal centers. Delocalization processes in the porphyrin .pi.-cation-radical systems
Yves Le Mest, Maurice L'Her, Neil H. Hendricks, Kimoon Kim, and James P. Collman
pp 835 - 847; DOI:
10.1021/ic00031a028
PDF
Scalar and dipolar contributions of rhenium to the relaxation properties of coordinated ligands
T. Beringhelli, G. D'Alfonso, M. Freni, and A. P. Minoja
pp 848 - 852; DOI:
10.1021/ic00031a029
PDF
Kinetic and thermodynamic study of complex formation between iron(II) and pyridoxal isonicotinoylhydrazone and other synthetic chelating agents
Jacques Emile Dubois, Hussein Fakhrayan, Jean Pierre Doucet, and Jean Michel El Hage Chahine
pp 853 - 859; DOI:
10.1021/ic00031a030
PDF
Characterization of protonated trans bis(dioxime) ruthenium complexes: crystal structures of trans-Ru(DPGH)2(NO)Cl, trans-[Ru(DMGH)(DMGH2)(NO)Cl]Cl, and trans-Ru(DMGH)2(NO)Cl
Lisa F. Szczepura, James G. Muller, Carol A. Bessel, Ronald F. See, Thomas S. Janik, Melvyn Rowen Churchill, and Kenneth J. Takeuchi
pp 859 - 869; DOI:
10.1021/ic00031a031
PDF
Studies on bis(catecholato)iron(III) complexes. Structure and bonding in members of the Fe(bpy)(Cl4SQ)(Cl4Cat)/Fe(bpy)(Cl4Cat)2- redox couple
Zirong Ding, Samaresh Bhattacharya, James K. McCusker, Paula M. Hagen, David N. Hendrickson, and Cortlandt G. Pierpont
pp 870 - 877; DOI:
10.1021/ic00031a032
PDF
Studies of platinum(II) methionine complexes: metabolites of cisplatin
Richard E. Norman, John D. Ranford, and Peter J. Sadler
pp 877 - 888; DOI:
10.1021/ic00031a033
PDF
Oxidative decarbonylation of transition metal carbonyls by arsenic selenide anions: preparation and structures of [M(CO)2(As3Se3)2]2- and [M(AsSe5)2]2- (M = molybdenum, tungsten)
Samuel C. O'Neal, William T. Pennington, and Joseph W. Kolis
pp 888 - 894; DOI:
10.1021/ic00031a034
PDF
Multiple bonds between main group elements and transition metals. 95. Synthesis and reactivity of TcCl(CO)3[P(C6H5)3]2: novel technetium complexes of 1,4,7-triazacyclononane and hydridotris(pyrazolyl)borate
Roger Alberto, Wolfgang A. Herrmann, Paul Kiprof, and Franz Baumgaertner
pp 895 - 899; DOI:
10.1021/ic00031a035
PDF
Synthesis and characterization of ruthenium acetate complexes containing triphosphines
Guochen Jia, Arnold L. Rheingold, Brian S. Haggerty, and Devon W. Meek
pp 900 - 904; DOI:
10.1021/ic00031a036
PDF
A fluxional binuclear nickel(I) complex and evidence for reversible A-frame formation
Ljubica Manojlovic-Muir, Kenneth W. Muir, William M. Davis, Hameed A. Mirza, and Richard J. Puddephatt
pp 904 - 909; DOI:
10.1021/ic00031a037
PDF
Characterization of bis(isopropoxo)nitrosyl(.eta.-pentamethylcyclopentadienyl)chromium: coordination saturation from alkoxide .pi.-donation
John L. Hubbard and William K. McVicar
pp 910 - 913; DOI:
10.1021/ic00031a038
PDF
Mono- and dinuclear complexes of a new binucleating porphyrin, .alpha.,.alpha.-5,15-bis(o-(nicotinoylamino)phenyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethylporphyrin. Crystal structures of a mononuclear nickel(II) complex and a binuclear copper-platinum complex
L. Keith Woo, Mannar R. Maurya, Robert A. Jacobson, Shumei Yang, and Sharon L. Ringrose
pp 913 - 919; DOI:
10.1021/ic00031a039
PDF
Mo2F4(PR3)4 compounds and a comparison of their properties with those of other Mo2X4(PR3)4 compounds. A new synthetic route to metal fluorides by the reaction of alkyl species with Olah's reagent
F. Albert Cotton and Kenneth J. Wiesinger
pp 920 - 925; DOI:
10.1021/ic00031a040
PDF
Spectroelectrochemistry of copper-zinc superoxide dismutase
Cynthia Strong St. Clair, Harry B. Gray, and Joan Selverstone Valentine
pp 925 - 927; DOI:
10.1021/ic00031a041
PDF
Surface organometallic chemistry: synthesis and characterization of a tris(neopentyl)zirconium(IV) complex grafted to the surface of a partially dehydroxylated silica
Francoise Quignard, Christine Lecuyer, Catherine Bougault, Frederic Lefebvre, Agnes Choplin, Daniele Olivier, and Jean Marie Basset
pp 928 - 930; DOI:
10.1021/ic00031a042
PDF
The product of the reaction of trans-diamminedichloroplatinum(II) with diamines is dependent on chain length. Example of a bridging ethylenediamine and formation of a novel trans-chelated structure with 1,5-pentanediamine
Yun Qu and Nicholas Farrell
pp 930 - 932; DOI:
10.1021/ic00031a043
PDF
Photochemical formation of oxochromium(IV) tetraphenylporphyrin from nitritochromium(III) tetraphenylporphyrin in benzene
Minoru Yamaji, Yoshimasa Hama, Yoshio Miyazaki, and Mikio Hoshino
pp 932 - 934; DOI:
10.1021/ic00031a044
PDF

Issue 6


Metal ion catalysis of amide hydrolysis. Very large rate enhancements by copper(II) in the hydrolysis of simple ligand-functionalized tertiary amides
Lawrence M. Sayre, K. Veera Reddy, Alan R. Jacobson, and Wei Tang
pp 935 - 937; DOI:
10.1021/ic00032a001
PDF
EPR studies of a dinickel complex in its (II,II) and (II,III) oxidation states
Theodore R. Holman, Michael P. Hendrich, and Lawrence Que
pp 937 - 939; DOI:
10.1021/ic00032a002
PDF
Characterization of iron octaethylporphyrin .pi.-cation radicals
W. Robert Scheidt, Hungsun Song, Kenneth J. Haller, Martin K. Safo, Robert D. Orosz, Christopher A. Reed, Peter G. Debrunner, and Charles E. Schulz
pp 939 - 941; DOI:
10.1021/ic00032a003
PDF
Sulfur compounds. 148. Generation and characterization of dihydroxy disulfide, HOSSOH: the chainlike isomer of thiosulfurous acid
Heinar Schmidt, Ralf Steudel, Detlev Suelzle, and Helmut Schwarz
pp 941 - 944; DOI:
10.1021/ic00032a004
PDF
Single-crystal polarized absorption spectroscopic study of the electronic structure of .mu.-1,2-peroxo binuclear cobalt complexes
Felix Tuczek and Edward I. Solomon
pp 944 - 953; DOI:
10.1021/ic00032a005
PDF
(o-Phenylenediimido)- and (p-phenylenediimido)ditungsten complexes
Mong Liang and Eric A. Maatta
pp 953 - 956; DOI:
10.1021/ic00032a006
PDF
Synthesis of the iron-sulfur cluster compounds [Fe4S4(MeCp)4](PF6)y (y = 0-2). X-ray structure determinations of Fe4(.mu.3-S)4(MeCp)4 and [Fe4(.mu.3-S)4(MeCp)4](PF6)
H. L. Blonk, J. G. M. Van der Linden, J. J. Steggerda, R. P. Geleyn, J. M. M. Smits, G. Beurskens, Paul T. Beurskens, and J. Jordanov
pp 957 - 962; DOI:
10.1021/ic00032a007
PDF
Synthesis and characterization of the iron-sulfur cluster compounds [Fe4S5(MeCp)4](PF6)y (y = 0-2). X-ray structure determination of [Fe4S5(MeCp)4](PF6)
H. L. Blonk, J. Mesman, J. G. M. Van der Linden, J. J. Steggerda, J. M. M. Smits, G. Beurskens, Paul T. Beurskens, C. Tonon, and J. Jordanov
pp 962 - 968; DOI:
10.1021/ic00032a008
PDF
Synthesis and x-ray structural characterization of heterobimetallic rhodium-platinum and rhodium-palladium benzothiazole-2-thiolate compounds. The first binuclear complexes having two short-bite anionic bridging ligands in a trans disposition
Miguel A. Ciriano, Jesus J. Perez-Torrente, Fernando J. Lahoz, and Luis A. Oro
pp 969 - 974; DOI:
10.1021/ic00032a009
PDF
1,5-Cyclooctanediylbis(pyrazol-1-yl)borate: a ligand with enhanced agostic interaction
Swiatoslaw Trofimenko, Joseph C. Calabrese, and Jeffery S. Thompson
pp 974 - 979; DOI:
10.1021/ic00032a010
PDF
Synthesis and chemistry of B11H11Sn2- and its germanium and lead analogs. Crystal structure of [B11H11SnCH3]PPh3CH3.cntdot.CH2Cl2
Robert W. Chapman, John G. Kester, Kirsten Folting, William E. Streib, and Lee J. Todd
pp 979 - 983; DOI:
10.1021/ic00032a011
PDF
[Tris(3-tert-butylpyrazolyl)hydroborato]beryllium hydride: synthesis, structure, and reactivity of a terminal beryllium hydride complex
Runyu Han and Gerard Parkin
pp 983 - 988; DOI:
10.1021/ic00032a012
PDF
Synthesis and reactivity of zinc and aluminum alkyl derivatives stabilized by oxygen tripod ligands
Adrian G. Looney, Mark Cornebise, Dena Miller, and Gerard Parkin
pp 989 - 992; DOI:
10.1021/ic00032a013
PDF
Structural determinations of chlorobis(triisopropylphosphine)rhodium compounds in the +2 and +3 oxidation states
Richard L. Harlow, David L. Thorn, R. Thomas Baker, and Nancy L. Jones
pp 993 - 997; DOI:
10.1021/ic00032a014
PDF
Aggregation of CpRu(PPh3)2SR via loss of triphenylphosphine (R = propyl, isopropyl). Structure of [CpRuS-1-C3H7]3, a molecule with short C-H.cntdot..cntdot..cntdot.S distances
Alan Shaver, Pierre Yves Plouffe, David C. Liles, and Eric Singleton
pp 997 - 1001; DOI:
10.1021/ic00032a015
PDF
Neutral catecholate derivatives of manganese and iron: synthesis and characterization of the metal-oxygen cubane-like species M4(DBCat)4(py)6 (M = Mn, Fe), the trinuclear complex Mn3(DBCat)4(py)4, and the dimers M2(DBCat)2(py)n (M = Mn, n = 6; M = Fe, n = 4,6)
Steven C. Shoner and Philip P. Power
pp 1001 - 1010; DOI:
10.1021/ic00032a016
PDF
Pathways for water oxidation catalyzed by the (.mu.-oxo)bis[aquabis(bipyridine)ruthenium](4+) ion
James K. Hurst, Jinzhong Zhou, and Yabin Lei
pp 1010 - 1017; DOI:
10.1021/ic00032a017
PDF
Synthesis and characterization of (tetramethylethylenediamine)(9,10-phenanthrenequinone)(9,10-phenanthrenediolato)copper(II), a copper complex containing mixed-charge 9,10-phenanthrenequinone ligands
Gabor Speier, Sandor Tisza, Antal Rockenbauer, Steven R. Boone, and Cortlandt G. Pierpont
pp 1017 - 1020; DOI:
10.1021/ic00032a018
PDF
Bonding in halocuprates
Lalitha Subramanian and Roald Hoffmann
pp 1021 - 1029; DOI:
10.1021/ic00032a019
PDF
Electronic structure of niobium telluride ion, NbTe103-, a tellurium cluster with an encapsulated metal [niobium] atom
Wolfgang Tremel
pp 1030 - 1033; DOI:
10.1021/ic00032a020
PDF
Electrochemical and spectroscopic studies of tantalum species in NaCl-AlCl3 melts at 160-300.degree.C
J. H. Von Barner, L. E. McCurry, C. A. Joergensen, N. J. Bjerrum, and G. Mamantov
pp 1034 - 1039; DOI:
10.1021/ic00032a021
PDF
Preparation and characterization of KxMIIxMIII1-xF3 (x .apprxeq. 0.4-0.6; MII = manganese, nickel; MIII = vanadium, chromium)
Y. S. Hong, R. F. Williamson, K. N. Baker, T. Y. Du, S. M. Seyedahmadian, and W. O. J. Boo
pp 1040 - 1045; DOI:
10.1021/ic00032a022
PDF
Order and disorder of vanadyl chains: crystal structures of vanadyl dihydrogen arsenate (VO(H2AsO4)2) and the lithium derivative Li4VO(AsO4)2
Miguel A. G. Aranda, J. Paul Attfield, Sebastian Bruque, and Maria Martinez-Lara
pp 1045 - 1049; DOI:
10.1021/ic00032a023
PDF
New layered ternary niobium tellurides: synthesis, structure, and properties of niobium metal telluride, NbMTe2 (M = iron, cobalt)
Jing Li, Michael E. Badding, and F. J. DiSalvo
pp 1050 - 1054; DOI:
10.1021/ic00032a024
PDF
A tris(thioxanthate) of nickel(II) and its transformation to a dinuclear trithiocarbonate complex. Synthesis and structure of [Et4N]2[Ni2(SEt)2(CS3)2]
Suranjan Bhanja Choudhury and Animesh Chakravorty
pp 1055 - 1058; DOI:
10.1021/ic00032a025
PDF
Spontaneous fixation of carbon dioxide in air by a nickel diamine complex: synthesis and characterization of a trinuclear nickel(II) complex with a novel hydrogen bonding system around a carbonate ligand
Tomoaki Tanase, Sadao Nitta, Sadao Yoshikawa, Kimiko Kobayashi, Tosio Sakurai, and Shigenobu Yano
pp 1058 - 1062; DOI:
10.1021/ic00032a026
PDF
Crystal structure and spectroscopic properties of a novel mixed-valence compound containing tetrabromocuprate(II) and tribromocuprate(I) anions
M. R. Sundberg, R. Kivekas, J. Ruiz, J. M. Moreno, and E. Colacio
pp 1062 - 1066; DOI:
10.1021/ic00032a027
PDF
Synthesis, structure, and spectral and magnetic properties of (.mu.-carbonato)(.mu.-hydroxo)bis[N,N'-(bis(2-aminoethyl)ethane-1,2-diamine)chromium(III)] perchlorate
Leone Spiccia, Gary D. Fallon, Andrew Markiewicz, Keith S. Murray, and Hans Riesen
pp 1066 - 1072; DOI:
10.1021/ic00032a028
PDF
Substituent constant correlations as predictors of spectroscopic, electrochemical, and photophysical properties in ring-substituted 2,2'-bipyridine complexes of rhenium(I)
Janel K. Hino, Leopoldo Della Ciana, Walter J. Dressick, and B. Patrick Sullivan
pp 1072 - 1080; DOI:
10.1021/ic00032a029
PDF
Kinetic and structural studies on the oxotetracyanotechnetate(V) core: protonation and ligation of dioxotetracyanotechnetate(V) ions and crystal structure of 2,2'-bipyridinium trans-oxothiocyanatotetracyanotechnetate(V)
Andreas Roodt, Johann G. Leipoldt, Edward A. Deutsch, and James C. Sullivan
pp 1080 - 1085; DOI:
10.1021/ic00032a030
PDF
Electron-transfer reactions of encapsulated transition metal complexes. Oxidation of (4,4'-bipyridine)pentaammineruthenium(II) by (ethylenediaminetetraacetato)cobaltate(III)
Michael D. Johnson, Vincent C. Reinsborough, and Sean Ward
pp 1085 - 1087; DOI:
10.1021/ic00032a031
PDF
A novel photochemical, pH-controlled synthesis of organochromium complexes
Andreja Bakac, James A. Janni, and James H. Espenson
pp 1088 - 1090; DOI:
10.1021/ic00032a032
PDF
Kinetic study of the interaction of aquated palladium(II) complexes with purine 5'-nucleoside monophosphates and ribose 5'-monophosphate in aqueous solution. Effects of steric hindrance and phosphate-induced reactivity
Heribert Hohmann, Bjoern Hellquist, and Rudi Van Eldik
pp 1090 - 1095; DOI:
10.1021/ic00032a033
PDF
A kinetic investigation of the lanthanide DOTA chelates. Stability and rates of formation and of dissociation of a macrocyclic gadolinium(III) polyaza polycarboxylic MRI contrast agent
Xiangyun Wang, Tianzhu Jin, Vinciane Comblin, Antonio Lopez-Mut, Emile Merciny, and Jean F. Desreux
pp 1095 - 1099; DOI:
10.1021/ic00032a034
PDF
Synthesis and NMRD studies of gadolinium(3+) complexes of macrocyclic polyamino polycarboxylic ligands bearing .beta.-benzyloxy-.alpha.-propionic residues
Silvio Aime, Mauro Botta, Giuseppe Ermondi, Franco Fedeli, and Fulvio Uggeri
pp 1100 - 1103; DOI:
10.1021/ic00032a035
PDF
Synthesis and structure of infinite-chain copper(II) polymer systems
Larry W. Morgan, Kevin V. Goodwin, William T. Pennington, and John D. Petersen
pp 1103 - 1106; DOI:
10.1021/ic00032a036
PDF
Synthesis and characterization of the new mixed-metal cluster complexes [Fe2M(.mu.3-E)2(CO)10] (M = W, E = Se, Te; M = Mo, E = Se). Crystal structure of [Fe2W(.mu.3-Te)2(CO)10]
Pradeep Mathur, Debojit Chakrabarty, M. Munkir Hossain, Raad S. Rashid, V. Rugmini, and Arnold L. Rheingold
pp 1106 - 1108; DOI:
10.1021/ic00032a037
PDF
A high-yield one-step synthesis of dichloro(tetraazacyclotetradecane)chromium(1+) chloride (trans-[Cr([14]aneN4)Cl2]Cl) and its conversion to trans-[Cr([14]aneN4)(H2O)2](CF3SO3)3
Andreja Bakac and James H. Espenson
pp 1108 - 1110; DOI:
10.1021/ic00032a038
PDF
Preparation and characterization of an A1u (Oxo) iron(IV) porphyrin .pi.-cation-radical complex
Hiroshi Fujii and Kazuhiko Ichikawa
pp 1110 - 1112; DOI:
10.1021/ic00032a039
PDF
Preparation of complexes of the forms WCp*(OR)3Cl, WCp*(OR)4, and WCp*(X)(.eta.2-alkyne)2 (X = OR, Cl)
Marie B. O'Regan, Michael G. Vale, Joseph F. Payack, and Richard R. Schrock
pp 1112 - 1115; DOI:
10.1021/ic00032a040
PDF
Synthesis and complexation studies of mesocyclic and macrocyclic polythioethers. 9. Crystal and molecular structure of (1,4,7,10,13-pentathiacyclopentadecane)cadmium(II) perchlorate hydrate: a seven-coordinate cadmium
William N. Setzer, Yaping Tang, Gregory J. Grant, and Donald G. VanDerveer
pp 1116 - 1118; DOI:
10.1021/ic00032a041
PDF
.alpha.- and .beta.-ferric fluoride trihydrate revisited: crystal structure and iron-57 Moessbauer spectra
D. G. Karraker and P. K. Smith
pp 1118 - 1120; DOI:
10.1021/ic00032a042
PDF
Structural diversity in bis(pentamethylcyclopentadienyl)yttrium chloride complexes: cocrystallization of [(C5Me5)2Y(.mu.-Cl)2Li(THF)2] and [(C5Me5)2YCl(.mu.-Cl)Li(THF)3]
William J. Evans, Timothy J. Boyle, and Joseph W. Ziller
pp 1120 - 1122; DOI:
10.1021/ic00032a043
PDF
Quenching of the doublet excited state of tris(polypyridine)chromium(III) ions by oxalate ions: an example of irreversible electron transfer. [Erratum to document cited in CA111(8):67702j]
Carl R. Steffan, Andreja Bakac, and James H. Espenson
pp 1122 - 1122; DOI:
10.1021/ic00032a044
PDF

Issue 7


Attenuation of antiferromagnetic exchange interactions via water hydrogen bonding to oxo-bridged diiron(III) complexes
Kenneth J. Oberhausen, John F. Richardson, Robert J. O'Brien, Robert M. Buchanan, James K. McCusker, Robert J. Webb, and David N. Hendrickson
pp 1123 - 1125; DOI:
10.1021/ic00033a001
PDF
Photosubstitution of iron pentacarbonyl, with triethylphosphine in cyclohexane: Fe(CO)4PEt3 and Fe(CO)3(PEt3)2 are single-photon products
Suresh K. Nayak and Theodore J. Burkey
pp 1125 - 1127; DOI:
10.1021/ic00033a002
PDF
Unusual stabilization of trans-2,2'-bipyridine ligands in a rhenium(V) phenylimido complex
Mohammed Bakir, Scott Paulson, Patricia Goodson, and B. Patrick Sullivan
pp 1127 - 1129; DOI:
10.1021/ic00033a003
PDF
Electrochemical investigation of the association of distamycin A with the manganese(III) complex of meso-tetrakis(N-methyl-4-pyridiniumyl)porphine and the interaction of this complex with DNA
Marisol Rodriguez and Allen J. Bard
pp 1129 - 1135; DOI:
10.1021/ic00033a004
PDF
Physical basis for the resolution of intra- and extracellular cesium-133 NMR resonances in cesium(+) loaded human erythrocyte suspensions in the presence and absence of shift reagents
Lisa Wittenkeller, Duarte Mota de Freitas, Carlos F. G. C. Geraldes, and Angelo J. R. Tome
pp 1135 - 1144; DOI:
10.1021/ic00033a005
PDF
Determination of the molar extinction coefficients of the deuteroferriheme analogs of peroxidase enzyme compounds I and II
Fanny S. Woo, Ricardo E. Rodriguez, Dale A. Huckaby, Peter Jones, and Henry C. Kelly
pp 1144 - 1147; DOI:
10.1021/ic00033a006
PDF
Geometric and electronic structure of paramagnetic tetraarylporphyrin complexes of chromium
Alan L. Balch, Lechoslaw Latos-Grazynski, Bruce C. Noll, Marilyn M. Olmstead, and Edward P. Zovinka
pp 1148 - 1151; DOI:
10.1021/ic00033a007
PDF
Costa-type B12 models: synthesis, structural characterization, and electrochemistry of chloro derivatives
Alessandra Gerli and Luigi G. Marzilli
pp 1152 - 1160; DOI:
10.1021/ic00033a008
PDF
Synthesis and properties of cage-type sulfur-bridged cobalt(III)zinc(II) polynuclear complexes. Crystal structure of spontaneously resolved [{Co(aet)3}4Zn4O]Br6 (aet = 2-aminoethanethiolate)
Takumi Konno, Takayuki Nagashio, Kenichi Okamoto, and Jinsai Hidaka
pp 1160 - 1165; DOI:
10.1021/ic00033a009
PDF
Synthesis and characterization of pillared buserite
She Tin Wong and Soofin Cheng
pp 1165 - 1172; DOI:
10.1021/ic00033a010
PDF
Thiolato-technetium complexes. 5. Synthesis, characterization, and electrochemical properties of bis(o-phenylenebis(dimethylarsine))technetium(II) and -technetium(III) complexes with thiolato ligands. Single-crystal structural analyses of trans-[Tc(SCH3)2(DIARS)2]PF6 and trans-[Tc(SC6H5)2(DIARS)2]0
Takumi Konno, Mary Jane Heeg, Jeanne A. Stuckey, Jon R. Kirchhoff, William R. Heineman, and Edward Deutsch
pp 1173 - 1181; DOI:
10.1021/ic00033a011
PDF
Characterization of the galloaluminate GaO4Al12(OH)24(H2O)127+ polyoxocation by MAS NMR and infrared spectroscopies and powder x-ray diffraction
Susan M. Bradley, Ronald A. Kydd, and Colin A. Fyfe
pp 1181 - 1185; DOI:
10.1021/ic00033a012
PDF
Reactivity of the molybdenum-polysulfide functional groups in thio- and oxothiomolybdate complexes toward carbon disulfide. Synthesis and reactivity of trithio- and perthiocarbonate complexes of Mo(IV) and Mo(V) and structural characterization of trans-[Ph4P]2[Mo(S)(CS4)2].cntdot.DMF (I), cis-[Ph4P][Et4N][Mo(S)(CS4)2] (II), cis-syn-[Ph4P]2[Mo2(S)2(.mu.-S)2(CS4)2].cntdot.1/2DMF (III), syn-[Ph4P]2[Mo2(S)2(.mu.-S)2(CS3)2] (IV), and syn-[Et4N]2(Mo2(O)2(.mu.-S)2(CS4)(CS3)] (V)
D. Coucouvanis, M. E. Draganjac, S. M. Koo, A. Toupadakis, and A. I. Hadjikyriacou
pp 1186 - 1196; DOI:
10.1021/ic00033a013
PDF
Rapid versus intermediate electronic relaxation between S = 3/2 and S = 1/2 states in nitrosyl-iron complexes with Jaeger-type ligands
E. Koenig, G. Ritter, J. Dengler, and L. F. Larkworthy
pp 1196 - 1202; DOI:
10.1021/ic00033a014
PDF
Kinetic studies of nickel(II) and copper(II) complexes with N4 macrocycles of the cyclam type. 1. Kinetics and mechanism of complex formation with different N-methylated 1,4,8,11-tetraazacyclotetradecanes
Juergen R. Roeper and Horst Elias
pp 1202 - 1210; DOI:
10.1021/ic00033a015
PDF
Kinetic studies of nickel(II) and copper(II) complexes with N4 macrocycles of the cyclam type. 2. Kinetics and mechanism of complex formation with different C-alkylated 1,4,8,11-tetraazacyclotetradecanes
Juergen R. Roeper and Horst Elias
pp 1210 - 1214; DOI:
10.1021/ic00033a016
PDF
Photochemically produced cobalt(II) complexes with coordinated free radicals: intramolecular oxidation of the metal center by the coordinated alkyl radical
E. Natarajan and P. Natarajan
pp 1215 - 1220; DOI:
10.1021/ic00033a017
PDF
Predictions and methods of separation of racemic bidentate ligands via stereoselective ligand exchange reactions
Paul V. Bernhardt, Peter Comba, Thomas Gyr, and Katalin Varnagy
pp 1220 - 1223; DOI:
10.1021/ic00033a018
PDF
Fast ortho-metalation reactions in binuclear dirhodium compounds. Syntheses and molecular structures of a monometalated compound and two doubly metalated compounds with head-to-head configurations
Pascual Lahuerta, Jorge Paya, Maria Angela Pellinghelli, and Antonio Tiripicchio
pp 1224 - 1232; DOI:
10.1021/ic00033a019
PDF
Addition of mercury(II) electrophiles to [Ru2(C10H8N2)(CO)4(P-iso-Pr3)2] and selective insertion versus addition in the reactions of mercury(II) electrophiles with trinuclear diruthenium mercury clusters. X-ray structures of [Ru2Hg(O2CCF3)2(C10H8N2)(CO)4(P-iso-Pr3)2] and [Ru2Hg2Cl4(C10H8N2)(CO)4(P-iso-Pr3)2].cntdot.CH2Cl2 (C10H10N2 = 1,8-diaminonaphthalene)
Javier A. Cabeza, Jose M. Fernandez-Colinas, Santiago Garcia-Granda, Victor Riera, and Juan F. Van der Maelen
pp 1233 - 1238; DOI:
10.1021/ic00033a020
PDF
Stereoregular coordination polymers formed on binding of peptide-based polydentate ligands to silver(I) and copper(I). X-ray structure of ([Ag{N-[N-((5-methyl-2-thienyl)methylidene)-L-methionyl]histamine}]+[O3SCF3]-.MeOH).infin. and a solution structure study
Johan F. Modder, Kees Vrieze, Anthony L. Spek, Gerrit Challa, and Gerard Van Koten
pp 1238 - 1247; DOI:
10.1021/ic00033a021
PDF
Protonation of a metal-metal bond can lead to bond shortening
David J. Elliot, Jagadese J. Vittal, Richard J. Puddephatt, David G. Holah, and Alan N. Hughes
pp 1247 - 1250; DOI:
10.1021/ic00033a022
PDF
Electronic structure calculations on octanuclear silsesquioxanes and aluminosilsesquioxanes
Clarke W. Earley
pp 1250 - 1255; DOI:
10.1021/ic00033a023
PDF
Electrochemical and spectroscopic characterization of niobium {Nb6Cl12}z+ chloride clusters in the aluminum chloride-1-methyl-3-ethylimidazolium chloride molten salt
Robert Quigley, Paul A. Barnard, Charles L. Hussey, and Kenneth R. Seddon
pp 1255 - 1261; DOI:
10.1021/ic00033a024
PDF
Yttrium-89 and silicon-29 NMR spectra as probes of solution dynamics: ligand and metal polyhedral rearrangements in yttrium aggregates
Paul S. Coan, Liliane G. Hubert-Pfalzgraf, and Kenneth G. Caulton
pp 1262 - 1267; DOI:
10.1021/ic00033a025
PDF
New halogen-bridged dinuclear edge-sharing and face-sharing bioctahedral tungsten(III) complexes, W2X6(PR3)n, where X = Cl or Br, PR3 = PMe3, PMe2Ph, PBu3, and n = 4 or 3: crystal structures of W2Cl6(PMe2Ph)4, W2Cl6(PMe2Ph)3 and W2Br6(PMe2Ph)3
F. Albert Cotton and Sanjay K. Mandal
pp 1267 - 1274; DOI:
10.1021/ic00033a026
PDF
Reactions of diphenyl[bis(trimethylsilyl)amido](trimethylsilylimido)phosphorane with organochalcogen halides: preparation, x-ray structure, and reactions of Ph2PN2(SiMe3)2(SPh) with E2Cl2 (E = S, Se) and PhSeCl
Tristram Chivers, Santhanathan S. Kumaravel, Masood Parvez, and M. N. Sudheendra Rao
pp 1274 - 1278; DOI:
10.1021/ic00033a027
PDF
Pentacoordinated molecules. 91. Conformational comparison of a seven-membered ring in tri- and pentacoordinated geometries of oxygen-containing phosphorus compounds. Solution NMR behavior of seven- and eight-membered rings in oxyphosphoranes
Johannes Hans, Roberta O. Day, Lori Howe, and Robert R. Holmes
pp 1279 - 1285; DOI:
10.1021/ic00033a028
PDF
A molecular mechanics model of ligand effects. 3. A new measure of ligand steric effects
Theodore L. Brown
pp 1286 - 1294; DOI:
10.1021/ic00033a029
PDF
Cis and trans isomers of tetrakis(dimethylphenylphosphine)bis(dinitrogen)tungsten
T. Adrian George, Jeffrey R. D. DeBord, Bharat B. Kaul, Christopher J. Pickett, and David J. Rose
pp 1295 - 1297; DOI:
10.1021/ic00033a030
PDF
Coordination polymers of tetracyanoethylene with metal hexafluoroacetylacetonates: formation and x-ray crystal structures
Andrew G. Bunn, Patrick J. Carroll, and Bradford B. Wayland
pp 1297 - 1299; DOI:
10.1021/ic00033a031
PDF
A simple, efficient route to a .mu.6-oxo-centered hexanuclear iron(III) alkoxide complex: preparation and structure of Na2Fe6O(OCH3)18.cntdot.6CH3OH
Kaspar Hegetschweiler, Helmut W. Schmalle, Hans M. Streit, Volker Gramlich, Hans Ulrich Hund, and Isidor Erni
pp 1299 - 1302; DOI:
10.1021/ic00033a032
PDF
A novel and generalized approach to the synthesis of ML3n+ [M = ruthenium(II), rhodium(III); L = 2,2'-bipyridine, 1,10-phenanthroline, 2-(arylazo)pyridine; n = 2, 3]
Maushumi Kakoti, Alok K. Deb, and Sreebrata Goswami
pp 1302 - 1304; DOI:
10.1021/ic00033a033
PDF
High-pressure thermodynamic and kinetic NMR study of nonacarbonyl(.mu.3-(1,3,5-trithiane)tetrairidium: the "merry-go-round" process
Alessandra Orlandi, Urban Frey, Gianfranco Suardi, Andre E. Merbach, and Raymond Roulet
pp 1304 - 1306; DOI:
10.1021/ic00033a034
PDF
Lithium-transition metal complexes derived from meso-octaethylporphyrinogen which display .sigma.- and .pi.-bonding modes
Jayne Jubb, Denis Jacoby, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 1306 - 1308; DOI:
10.1021/ic00033a035
PDF
Binding of alkali-metal cations by self-assembling ionophore complexes of nickel(II)
Mark Wehr Jones, Nishi Gupta, Alanna Schepartz, and H. Holden Thorp
pp 1308 - 1310; DOI:
10.1021/ic00033a036
PDF
Synthesis and structures of the [MoFe6S6(CO)16]2-, [MoFe4S3(CO)13(PEt3)]2-, and [Mo2Fe2S2(CO)12]2- ions: high-nuclearity molybdenum-iron-sulfur clusters as potential precursors to models for the FeMo-cofactor of nitrogenase. [Erratum to document cited in CA114(24):239266a]
P. A. Eldredge, K. S. Bose, D. E. Barber, R. F. Bryan, E. Sinn, A. Rheingold, and Bruce A. Averill
pp 1310 - 1310; DOI:
10.1021/ic00033a037
PDF

Issue 8


Preparation of lanthanide nitrides via ammonolysis of molten {(Me3Si)2N}3Ln: onset of crystallization catalyzed by lithium amide and lithium chloride
Robert L. LaDuca and Peter T. Wolczanski
pp 1311 - 1313; DOI:
10.1021/ic00034a001
PDF
Isolation and characterization of a (diphenylamido)ruthenium(IV) porphyrin
Jie Sheng Huang, Chi Ming Che, Zao Ying Li, and Chung Kwong Poon
pp 1313 - 1315; DOI:
10.1021/ic00034a002
PDF
Syntheses and x-ray structures of novel phenoxo-bridged binuclear complexes: bis(.mu.-phenoxo)bis[bis(acetylacetonato)chromium(III)] complex and its para-substituted phenoxo analogs
Manabu Nakahanada, Takashi Fujihara, Akira Fuyuhiro, and Sumio Kaizaki
pp 1315 - 1316; DOI:
10.1021/ic00034a003
PDF
Dissolution of uranium metal using iodine and isopropyl alcohol. Synthesis and x-ray crystal structure of tetraiodotetrakis(isopropoxo)bis(isopropanol)diuranium
William G. Van der Sluys, John C. Huffman, Deborah S. Ehler, and Nancy N. Sauer
pp 1316 - 1318; DOI:
10.1021/ic00034a004
PDF
Electronic absorption and resonance Raman spectra of tricarbonyl(p-tolyl-1,4-diaza-1,3-butadiene)halorhenium. Evidence for a lowest ligand to ligand charge-transfer (LLCT) transition
Gerard J. Stor, Derk J. Stufkens, and Ad Oskam
pp 1318 - 1319; DOI:
10.1021/ic00034a005
PDF
Tris(phenylimido) complexes of niobium and tantalum: preparation and properties of the d0 [M(=NR)3]- (M = Nb, Ta) functional group
David P. Smith, Kevin D. Allen, Michael D. Carducci, and David E. Wigley
pp 1319 - 1320; DOI:
10.1021/ic00034a006
PDF
Synthesis and molecular structure of an iminophosphide/phosphinoamide anion: [Li(PhN-PPh2)(OEt2)]2
Michael T. Ashby and Zhong Li
pp 1321 - 1322; DOI:
10.1021/ic00034a007
PDF
The fluoro(hydrogen cyanide)xenon(II) cation. Preparation of HC.tplbond.NXeF+AsF6-: a multinuclear magnetic resonance and Raman spectroscopic study
Adel A. A. Emara and Gary J. Schrobilgen
pp 1323 - 1332; DOI:
10.1021/ic00034a008
PDF
Multiple-state emission from platinum(II) diimine dithiolate complexes. Solvent and temperature effects
Juan A. Zuleta, Joanne M. Bevilacqua, Julie M. Rehm, and Richard Eisenberg
pp 1332 - 1337; DOI:
10.1021/ic00034a009
PDF
Metal-thiolate bonding properties: single-crystal ESR, susceptibility, and polarized absorption evidence for a strong .pi. interaction in tetrakis(thiophenolato)cobaltate(II)
Kouichi Fukui, Norimichi Kojima, Hiroaki Ohya-Nishiguchi, and Noboru Hirota
pp 1338 - 1344; DOI:
10.1021/ic00034a010
PDF
Applications of two-photon spectroscopy to inorganic compounds. 2. Spectrum and electronic structure of cesium uranyl nitrate, CsUO2(NO3)3
Trevor J. Barker, Robert G. Denning, and Jonathan R. G. Thorne
pp 1344 - 1353; DOI:
10.1021/ic00034a011
PDF
Relaxation enhancement of water protons by manganese(III) porphyrins: influence of porphyrin aggregation
Kenneth E. Kellar and Natalie Foster
pp 1353 - 1359; DOI:
10.1021/ic00034a012
PDF
Metal substitutions at the diiron site of hemerythrin. A dicobalt(II) derivative
Ji Hu Zhang, Donald M. Kurtz, Michael J. Maroney, and Joyce P. Whitehead
pp 1359 - 1366; DOI:
10.1021/ic00034a013
PDF
Infrared and carbon-13 and nitrogen-15 NMR studies of cyano(ligand)cobaloximes: evidence for cobalt-to-cyanide .pi.-bonding
Kenneth L. Brown and S. Satyanarayana
pp 1366 - 1369; DOI:
10.1021/ic00034a014
PDF
Calorimetric studies of the heats of protonation of the metal in cis-M(CO)2(bidentate phosphine)2 complexes of chromium, molybdenum, and tungsten
John R. Sowa, Jeffrey B. Bonanno, Valerio Zanotti, and Robert J. Angelici
pp 1370 - 1375; DOI:
10.1021/ic00034a015
PDF
Redox and spectral properties of the four-electron oxidant trans-aquadioxo(terpyridine)ruthenium(2+) diperchlorate
S. Ajao Adeyemi, Angelos Dovletoglou, Ana R. Guadalupe, and Thomas J. Meyer
pp 1375 - 1383; DOI:
10.1021/ic00034a016
PDF
Iron(II)-diimine complex [Fe(CH3N:CHCH:NCH3)3]2+: its structure and its solvation and reactivity in aqueous-organic solvent mixtures
Michael J. Blandamer, John Burgess, John Fawcett, Pilar Guardado, Colin D. Hubbard, Sumchairuk Nuttall, Lesley J. S. Prouse, Stojan Radulovic, and David R. Russell
pp 1383 - 1389; DOI:
10.1021/ic00034a017
PDF
Chains of centered metal clusters with a novel range of distortions: praseodymium ruthenium iodide (Pr3I3Ru), ruthenium yttrium iodide (Y3I3Ru), and iridium yttrium iodide (Y3I3Ir)
Martin W. Payne, Peter K. Dorhout, Sung Jin Kim, Timothy R. Hughbanks, and John D. Corbett
pp 1389 - 1394; DOI:
10.1021/ic00034a018
PDF
Polymeric chain cleavage reactions in tetrakis(carboxylato)chlorodiruthenium (Ru2Cl(O2CR)4): x-ray crystal structures of [RuIICl(MeCN)3(PPh3)2]2[RuII2Cl2(O2CC6H4-p-Me)4] and [RuIICl(MeCN)4(PPh3)][RuIIRuIIICl2(O2CC6H4-p-OMe)4]
Birinchi K. Das and Akhil R. Chakravarty
pp 1395 - 1400; DOI:
10.1021/ic00034a019
PDF
Structural and spectroscopic correlations in cadmium(II) halide complexes of 2,2-dimethylpropane-1,3-diamine
N. Masciocchi, M. Moret, A. Sironi, S. Bruni, F. Cariati, A. Pozzi, T. Manfredini, L. Menabue, and G. C. Pellacani
pp 1401 - 1406; DOI:
10.1021/ic00034a020
PDF
Resolutions involving metal complexation. Optical resolution and photochemical rearrangement of (.+-.)-(2-mercaptoethyl)methylphenylphosphine
Pak Hing Leung, Anthony C. Willis, and S. Bruce Wild
pp 1406 - 1410; DOI:
10.1021/ic00034a021
PDF
Metal template synthesis of a 14-membered trans-P2S2 chelating macrocycle
Timothy L. Jones, Anthony C. Willis, and S. Bruce Wild
pp 1411 - 1416; DOI:
10.1021/ic00034a022
PDF
Preparation of 1,3,2,4,6-dithiatriazines with substituted aryl groups and the x-ray crystal structure of the (4-chlorophenyl)dithiatriazine dimer
Rene T. Boere, James Fait, Karen Larsen, and Judy Yip
pp 1417 - 1423; DOI:
10.1021/ic00034a023
PDF
Tetrakis(pentafluorooxotellurato)borate(1-): coordinating ability and reactivity of a very large weakly coordinating anion
Dawn M. Van Seggen, Paul K. Hurlburt, Mark D. Noirot, Oren P. Anderson, and Steven H. Strauss
pp 1423 - 1430; DOI:
10.1021/ic00034a024
PDF
Synthesis and characterization of novel chiral ortho-tellurated complexes derived from [(S)-1-(dimethylamino)ethyl]benzene: crystal and molecular structure of {2-[(S)-1-(dimethylamino)ethyl]phenyl}tellurium trichloride
Harkesh B. Singh, Narasimhan Sudha, and Ray T. Butcher
pp 1431 - 1435; DOI:
10.1021/ic00034a025
PDF
Dioxygen-copper reactivity and functional modeling of hemocyanins. Reversible binding of O2 and carbon monoxide to dicopper(I) complexes [CuI2(L)]2+ (L = dinucleating ligand) and the structure of a bis(carbonyl) adduct, [CuI2(L)(CO)2]2+
Kenneth D. Karlin, Zoltan Tyeklar, Amjad Farooq, Michael S. Haka, Phalguni Ghosh, Richard W. Cruse, Yilma Gultneh, Jon C. Hayes, Paul J. Toscano, and Jon Zubieta
pp 1436 - 1451; DOI:
10.1021/ic00034a026
PDF
Mono- and dinuclear zinc(II) complexes of biological relevance. Crystal structures of [L2Zn](PF6)2, [L'Zn(O2CPh)2(H2O)], [L'2Zn2(.mu.-OH)2](ClO4)2, and [L'2Zn2(.mu.-OH)(.mu.-CH3CO2)2](ClO4).cntdot.H2O (L = 1,4,7-triazacyclononane, L' = 1,4,7-trimethyl-1,4,7-triazacyclononane)
Phalguni Chaudhuri, Claudia Stockheim, Karl Wieghardt, Werner Deck, Ralf Gregorzik, Heinrich Vahrenkamp, Bernhard Nuber, and Johannes Weiss
pp 1451 - 1457; DOI:
10.1021/ic00034a027
PDF
Influence of the 5-substituent of uracils and uridines on .eta.2 coordination of [ethylenediaminetetraacetato(3-)]ruthenate(1-) at the C-5 C-6 bonds
Rex E. Shepherd, Songsheng Zhang, Fu Tyan Lin, and Richard A. Kortes
pp 1457 - 1462; DOI:
10.1021/ic00034a028
PDF
Effect of electrolyte concentration on axial anion ligation in manganese(III) meso-tetraphenylporphyrin chlorides
Garry J. Foran, Robert S. Armstrong, Maxwell J. Crossley, and Peter A. Lay
pp 1463 - 1470; DOI:
10.1021/ic00034a029
PDF
Ligand additivity effects and periodic trends in the stability and acidity of octahedral .eta.2-dihydrogen complexes of d6 transition metal ions
Robert H. Morris
pp 1471 - 1478; DOI:
10.1021/ic00034a030
PDF
Multimode coordination chemistry of [R2P(X)CHnP(Y)R'2](2-n)- ligands (X, Y = O, S, Se; n = 1, 2). Synthesis and phosphorus-31 NMR spectroscopy of platinum complexes
David E. Berry, Jane Browning, Keith R. Dixon, Robert W. Hilts, and Alan Pidcock
pp 1479 - 1487; DOI:
10.1021/ic00034a031
PDF
Stereochemical nonrigidity in heterobimetallic complexes containing the bent metallocene-thiolate fragment
Marcetta Y. Darensbourg, Magdalena Pala, Stephen A. Houliston, K. Paul Kidwell, David Spencer, Stephen S. Chojnacki, and Joseph H. Reibenspies
pp 1487 - 1493; DOI:
10.1021/ic00034a032
PDF
Stereochemical investigations of coordinated sulfur stereocenters. X-ray structures of diastereomers of (-)589-[Pd{(R)-CH3CH(1-C10H6)NMe2-C2,N}(R/S)-{Ph2PCH2SMe-P,S}]PF6
Simon Y. M. Chooi, T. S. Andy Hor, Pak Hing Leung, and K. F. Mok
pp 1494 - 1500; DOI:
10.1021/ic00034a033
PDF
Photochemical behavior of thioxophosphoranyl diazo compounds: evidence for transient .lambda.5-phosphathiirenes and for structural isomerizations of the diazo group
Michele Soleilhavoup, Antoine Baceiredo, Francoise Dahan, and Guy Bertrand
pp 1500 - 1504; DOI:
10.1021/ic00034a034
PDF
Preparation of the triiron phosphinidene-imido clusters Fe3(.mu.3-PBu-tert)(.mu.3-NR)(CO)9 (R = Et, Ph) and their reactions with alkynes
Jeong Sup Song, Gregory L. Geoffroy, and Arnold L. Rheingold
pp 1505 - 1509; DOI:
10.1021/ic00034a035
PDF
Tetrakis(.beta.-diketonate)dimolybdenum complexes. Preparations, properties, and solid-state and molecular structure of tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionato)dimolybdenum
Malcolm H. Chisholm, Kirsten Folting, and Elena F. Putilina
pp 1510 - 1513; DOI:
10.1021/ic00034a036
PDF
Cobalt hydroxide nitrate hydrate, Co(OH)(NO3).cntdot.H2O: a novel double-chain compound with competing interactions
S. Angelov, M. Drillon, E. Zhecheva, R. Stoyanova, M. Belaiche, A. Derory, and A. Herr
pp 1514 - 1517; DOI:
10.1021/ic00034a037
PDF
Hydroxo and azolate derivatives of pentafluorophenyl-nickel(II) complexes. Crystal structure of [NBu4]2[{Ni(C6F5)2(.mu.-OH)}2] and [NBu4]2[{Ni(C6F5)2}2(.mu.-OH)(.mu.-pyrazolato)]
Gregorio Lopez, Gabriel Garcia, Gregorio Sanchez, Joaquin Garcia, Jose Ruiz, Juan A. Hermoso, Angel Vegas, and Martin Martinez-Ripoll
pp 1518 - 1523; DOI:
10.1021/ic00034a038
PDF
Chemoselective oxidation of 3,5-di-tert-butylcatechol by molecular oxygen. Catalysis by an iridium(III) catecholate through its dioxygen adduct
Pierluigi Barbaro, Claudio Bianchini, Piero Frediani, Andrea Meli, and Francesco Vizza
pp 1523 - 1529; DOI:
10.1021/ic00034a039
PDF
Infrared study on the hydration of manganese(2+), iron(2+), cobalt(2+), lanthanum(3+), neodymium(3+), dysprosium(3+), and ytterbium(3+) ions in dilute aqueous solution
Pehr Aake Bergstroem and Jan Lindgren
pp 1529 - 1533; DOI:
10.1021/ic00034a040
PDF
Disproportionation of (alkoxy)borohydrides: a boron-11 NMR study of the reaction between sodium borohydride and fluorinated alcohols and phenols. The preparation of tris(fluoroalkoxy)- and tris(fluorophenoxy)borohydrides
Josh H. Golden, Cindy Schreier, Bakthan Singaram, and Stanley M. Williamson
pp 1533 - 1535; DOI:
10.1021/ic00034a041
PDF
Preparation and reactivity of molybdenum hydride and phenyldiazene complexes
Milton R. Smith, Tan Yun Cheng, and Gregory L. Hillhouse
pp 1535 - 1538; DOI:
10.1021/ic00034a042
PDF
Ortho-metalation of DPPE across a dirhodium(II,II) core. Synthesis and x-ray crystal structure of [Rh2(form)(O2CCF3){(C6H5)2P(CH2)2P(C6H5)(C6H4)}(DPPE)]CF3COO (form = N,N'-di-p-tolylformamidinate anion, DPPE = 1,2-bis(diphenylphosphino)ethane)
Giuseppe Bruno, Giovanni De Munno, Giuseppe Tresoldi, Sandra Lo Schiavo, and Pasquale Piraino
pp 1538 - 1540; DOI:
10.1021/ic00034a043
PDF
Photoredox pathways to spatially restricted metallopolymeric films
P. Subramanian, Hai Tao Zhang, and Joseph T. Hupp
pp 1540 - 1542; DOI:
10.1021/ic00034a044
PDF
Synthesis and semiconducting properties of bridged (phthalocyaninato)osmium compounds with bidendate N-donor ligands
Michael Hanack, Ahmet Gul, and L. R. Subramanian
pp 1542 - 1544; DOI:
10.1021/ic00034a045
PDF
Hydrolysis of phosphate diesters with copper(II) catalysts. [Erratum to document cited in CA109(15):129165f]
Janet R. Morrow and William C. Trogler
pp 1544 - 1544; DOI:
10.1021/ic00034a046
PDF

Issue 9


The redox chemistry of dimethyl(octaethylporphyrinato)ruthenium. Isolation of the bridging methylene complex Ru(OEP-N-.mu.-CH2-)(CH3)+
Jeffery W. Seyler, Lance K. Safford, Phillip E. Fanwick, and Charles R. Leidner
pp 1545 - 1547; DOI:
10.1021/ic00035a001
PDF
Detection of coordinated methyl and ethyl deuteron NMR signals and observation of alkyl group interchange for alkyliron(III) porphyrin complexes
Zijun Li and Harold M. Goff
pp 1547 - 1548; DOI:
10.1021/ic00035a002
PDF
Vibrational and electrochemical properties of a series of stable manganese(V)-oxo complexes
Jose M. Workman, Richard D. Powell, Alexander D. Procyk, Terrence J. Collins, and David F. Bocian
pp 1548 - 1550; DOI:
10.1021/ic00035a003
PDF
The barrier to rotation of dihydrogen in tricarbonyl(.eta.2-dihydrogen)bis(tricyclohexylphosphine)chromium, a complex with an unusually high difference in solid- and solution-state stabilities
Juergen Eckert, Gregory J. Kubas, and R. P. White
pp 1550 - 1551; DOI:
10.1021/ic00035a004
PDF
Facile .alpha./.beta. diastereomerism in organocobalt corrins. Access to minor isomers of alkylcobalt corrinoids by anaerobic photolysis
Xiang Zou, Kenneth L. Brown, and Chandra Vaughn
pp 1552 - 1554; DOI:
10.1021/ic00035a005
PDF
Preparation and x-ray crystal structure of potassium tetrakis(2,6-diisopropoxyphenolato)neodymate(1-): a one-dimensional chain of lanthanide aryloxide anions joined by bis(.eta.6-arene)-potassium interactions
David L. Clark, John G. Watkin, and John C. Huffman
pp 1554 - 1556; DOI:
10.1021/ic00035a006
PDF
Hexavanadium polyoxoalkoxide anion clusters: structures of the mixed-valence species (Me3NH)[VIV5VVO7(OH)3{CH3C(CH2O)3}3] and of the reduced complex Na2[VIV6O7{CH3CH2C(CH2O)3}4]
M. Ishaque Khan, Qin Chen, Jon Zubieta, and David P. Goshorn
pp 1556 - 1558; DOI:
10.1021/ic00035a007
PDF
Hexakis(acetato)oxotetrazinc, a well-tailored molecular model of zinc oxide. An experimental and theoretical investigation of the electronic structure of Zn4O(acetate)6 and ZnO by means of UV and x-ray photoelectron spectroscopies and first principle local density molecular cluster calculations
Renzo Bertoncello, Marco Bettinelli, Maurizio Casarin, Antonino Gulino, Eugenio Tondello, and Andrea Vittadini
pp 1558 - 1565; DOI:
10.1021/ic00035a008
PDF
Transient chiral induction in the reactions of optically active tris(oxalato)cobaltate(3-) with tris(phenanthroline)cobalt(2+) and derivatives
Robert M. L. Warren, A. Graham Lappin, and Akira Tatehata
pp 1566 - 1574; DOI:
10.1021/ic00035a009
PDF
Tetrahedrally distorted tetragonal copper complexes of a tridentate ligand
Gita Batra and Pavan Mathur
pp 1575 - 1580; DOI:
10.1021/ic00035a010
PDF
Surface-enhanced resonance Raman scattering study on the axial ligation states of manganese and chromium tetraphenylporphines adsorbed on silver electrode surfaces
Tatsushi Okumura, Shigeru Endo, Akio Ui, and Koichi Itoh
pp 1580 - 1584; DOI:
10.1021/ic00035a011
PDF
Bond valence sum analysis of metal-ligand bond lengths in metalloenzymes and model complexes
H. Holden Thorp
pp 1585 - 1588; DOI:
10.1021/ic00035a012
PDF
Variable photon energy photoelectron spectroscopy of osmium tetroxide and pseudopotential calculations of the valence ionization energies of OsO4 and ruthenium tetroxide
Jennifer C. Green, Martin F. Guest, Ian H. Hillier, Stephen A. Jarrett-Sprague, Nikolas Kaltsoyannis, Michael A. MacDonald, and Kong H. Sze
pp 1588 - 1594; DOI:
10.1021/ic00035a013
PDF
Spectroscopic, electrochemical, and spectroelectrochemical investigations of mixed-metal osmium(II)/ruthenium(II) bimetallic complexes incorporating polypyridyl bridging ligands
Mark M. Richter and Karen J. Brewer
pp 1594 - 1598; DOI:
10.1021/ic00035a014
PDF
Reduction of (.eta.1-acetonitrile)pentaammineosmium(2+) to pentaammine(.eta.2-iminioethane)osmium(3+)
Tai Hasegawa, Keh Shin Kwan, and Henry Taube
pp 1598 - 1600; DOI:
10.1021/ic00035a015
PDF
MLCT-dd energy gap in pyridyl-pyrimidine and bis(pyridine) complexes of ruthenium(II)
D. Paul Rillema, Charles B. Blanton, Randy J. Shaver, Donald C. Jackman, Massoud Boldaji, Stephanie Bundy, Laura A. Worl, and Thomas J. Meyer
pp 1600 - 1606; DOI:
10.1021/ic00035a016
PDF
Oxidative electropolymerization of iron and ruthenium complexes containing aniline-substituted 2,2'-bipyridine ligands
Colin P. Horwitz and Qi Zuo
pp 1607 - 1613; DOI:
10.1021/ic00035a017
PDF
Synthetic studies on the cyclopentadienylruthenium-triphenylphosphine-diselenium system: redox interconversions of Ru2(Se2)2 cores
Jayantha Amarasekera, Eric J. Houser, Thomas B. Rauchfuss, and Charlotte L. Stern
pp 1614 - 1620; DOI:
10.1021/ic00035a018
PDF
Semilocalized bonding schemes in extended systems; orbital localization in yttrium chloride (Y2Cl3) and interstitial derivatives
Kyeong Ae Yee and Timothy Hughbanks
pp 1620 - 1625; DOI:
10.1021/ic00035a019
PDF
Novel synthesis of 1,1,1,4,4,4-hexamethyl-2,2,3,3-tetrakis(trimethylsilyl)tetrasilane
S. P. Mallela, I. Bernal, and R. A. Geanangel
pp 1626 - 1627; DOI:
10.1021/ic00035a020
PDF
Facile solution routes to hydrocarbon-soluble Lewis base adducts of thorium tetrahalides. Synthesis, characterization, and x-ray structure of ThBr4(THF)4
David L. Clark, Tracey M. Frankcom, Mary M. Miller, and John G. Watkin
pp 1628 - 1633; DOI:
10.1021/ic00035a021
PDF
Reactions of perfluoromethyl-substituted cyclopolyphosphines with zerovalent group 10 metal complexes. Crystal and molecular structure of a [palladium] complex with a coordinated diphosphene, [Pd(.eta.2-CF3P:PCF3)(PPh3)2]
Ian G. Phillips, Richard G. Ball, and Ronald G. Cavell
pp 1633 - 1641; DOI:
10.1021/ic00035a022
PDF
Synthesis, structure, and bonding properties of a new volatile [N-tert-butyl(1H-pyrrol-2-ylmethylene)aminato]thallium(I) complex
Enrico Ciliberto, Santo Di Bella, Antonino Gulino, and Ignazio L. Fragala
pp 1641 - 1644; DOI:
10.1021/ic00035a023
PDF
Synthesis, structure, and properties of oxidized hexamolybdenum clusters [(Mo6X7Y)X'6]2- (X = X' = Cl, Br; Y = S, Se)
Masahiro Ebihara, Kiyoshi Isobe, Yoichi Sasaki, and Kazuo Saito
pp 1644 - 1649; DOI:
10.1021/ic00035a024
PDF
Structures in solution and in the solid state of the complexes of lanthanum(III) with 1,10-phenanthroline. X-ray crystallographic and proton, carbon-13, oxygen-17 and lanthanum-139 solution NMR studies
Monique Frechette, Ian R. Butler, Rosemary Hynes, and Christian Detellier
pp 1650 - 1656; DOI:
10.1021/ic00035a025
PDF
Resolved and unresolved crystallographic disorder between cyano-.eta.3-[hydrotris(3-tert-butylpyrazolyl)borato]zinc and the halo analogs.
Keum Yoon and Gerard Parkin
pp 1656 - 1662; DOI:
10.1021/ic00035a026
PDF
Biphasic reactions of DTNB with lobster Cd6- and Cd5Cu-metallothionein-2 which have two type-B (M3S9) clusters
Zhiwu Zhu, Mark Goodrich, Anvarhusein A. Isab, and C. Frank Shaw
pp 1662 - 1667; DOI:
10.1021/ic00035a027
PDF
Magnetic characterization of tetranuclear copper(II) and cobalt(II) exchange-coupled clusters encapsulated in heteropolyoxotungstate complexes. Study of the nature of the ground states
Carlos J. Gomez-Garcia, Eugenio Coronado, and Juan J. Borras-Almenar
pp 1667 - 1673; DOI:
10.1021/ic00035a028
PDF
Synthesis and structures of the bis(cis-1-methylthiostilbene-2-thiolate) of cadmium and its adducts with dimethyl sulfoxide, 4-(dimethylamino)pyridine, and 2,2'-bipyridyl: hexacoordination of cadmium vs pentacoordination in the corresponding zinc derivatives
Hussain K. Reddy, Cheng Zhang, E. O. Schlemper, and G. N. Schrauzer
pp 1673 - 1677; DOI:
10.1021/ic00035a029
PDF
Structures of the homologous series of square-planar metallotetrapyrroles palladium(II) octaethylporphyrin, palladium(II) trans-octaethylchlorin, and palladium(II) tct-octaethylisobacteriochlorin
Alan M. Stolzenberg, Leonard J. Schussel, Jack S. Summers, Bruce M. Foxman, and Jeffrey L. Petersen
pp 1678 - 1686; DOI:
10.1021/ic00035a030
PDF
Nature of the manganese(I)-dioxolene bonding as a function of the ligand oxidation state: UV-visible, IR, and resonance Raman spectroelectrochemical study of [Mn(CO)3Ln(Diox)]z (n = 0, 1; z = -2, -1, 0, +1) and [Mn(CO)2{P(OEt)3}m(Diox)]z (m = 1, 2; z = -1, 0, +1) complexes
Frantisek Hartl, Derk J. Stufkens, and Antonin Vlcek
pp 1687 - 1695; DOI:
10.1021/ic00035a031
PDF
Synthesis and chemistry of diborylphosphanes
Danan Dou, Gary L. Wood, Eileen N. Duesler, Robert T. Paine, and H. Noeth
pp 1695 - 1702; DOI:
10.1021/ic00035a032
PDF
Theoretical studies of borylphosphine and its conjugate base. 2. Internal rotation and inversion transition states
Thomas L. Allen and William H. Fink
pp 1703 - 1705; DOI:
10.1021/ic00035a033
PDF
Superoxide (O2-) on the surface of heat-treated ceria. Intermediates in the reversible oxygen to oxide transformation
Xiaolang Zhang and Kenneth J. Klabunde
pp 1706 - 1709; DOI:
10.1021/ic00035a034
PDF
Electron transfer. 112. Reactions of chromium(IV) with tin(II) and cerium(III)
M. C. Ghosh, R. N. Bose, E. Gelerinter, and E. S. Gould
pp 1709 - 1713; DOI:
10.1021/ic00035a035
PDF
Synthesis of the novel infinite-sheet and -chain copper(I) complex polymers {[Cu(C4H4N2)3/2(CH3CN)](PF)6).cntdot.0.5C3H6O}.infin. and {[Cu2(C8H12N2)3](ClO4)2}.infin. and their x-ray crystal structures
Susumu Kitagawa, Megumu Munakata, and Tadashi Tanimura
pp 1714 - 1717; DOI:
10.1021/ic00035a036
PDF
Ground-state and optical spectrum of metallophthalocyanine radical anions from low-temperature magnetic circular dichroism spectroscopy
John Mack, Scott Kirkby, Edward A. Ough, and Martin J. Stillman
pp 1717 - 1719; DOI:
10.1021/ic00035a037
PDF
Treatment of vitamin B12 and aquocobalamin (B12a) with the efficient hydrolytic agent [Co(trpn)(H2O)2]3+
Antonia M. Calafat and Luigi G. Marzilli
pp 1719 - 1722; DOI:
10.1021/ic00035a038
PDF
Towards a functional model of hydrogenase: electrocatalytic reduction of protons to dihydrogen by a nickel macrocyclic complex
Laura L. Efros, H. Holden Thorp, Gary W. Brudvig, and Robert H. Crabtree
pp 1722 - 1724; DOI:
10.1021/ic00035a039
PDF
Magnetochemistry of the tetrahaloferrate(III) ions. 3. Specific heat of bis[4-bromopyridinium tetrachloroferrate(III)]-4-bromopyridinium chloride
Roey Shaviv, K. E. Merabet, D. P. Shum, C. B. Lowe, D. Gonzalez, R. Burriel, and Richard L. Carlin
pp 1724 - 1726; DOI:
10.1021/ic00035a040
PDF
The first nickel(II) alternating chain with two different end-to-end azido bridges
Ramon Vicente, Albert Escuer, Joan Ribas, and Xavier Solans
pp 1726 - 1728; DOI:
10.1021/ic00035a041
PDF
Structural characterization of 1:2 tris(.mu.-benzenethiolato)bis[(hexamethylbenzeneruthenium] chloride-chloroform
Hans T. Schacht, R. C. Haltiwanger, and M. Rakowski DuBois
pp 1728 - 1730; DOI:
10.1021/ic00035a042
PDF
Metal complexes with tetrapyrrole ligands. 62. Carbon-13 NMR spectra of dicerium(III) and dipraseodymium(III) tris(octaethylporphyrinate). [Erratum to document cited in CA116(10):97921a]
Johann W. Buchler, Juergen Loeffler, and Mark Wicholas
pp 1730 - 1730; DOI:
10.1021/ic00035a043
PDF

Issue 10


Borane cluster photochemistry. 1. Photochemical decarbonylation and rearrangement chemistry of the .sigma.-metalated pentaborane cluster [Fe(.eta.5-C5H5)(CO)2B5H8]
Bruce H. Goodreau, Lianna R. Orlando, and James T. Spencer
pp 1731 - 1733; DOI:
10.1021/ic00036a001
PDF
Emission spectroscopic properties of 1,2-bis(dicyclohexylphosphino)ethane complexes of gold(I)
T. Mark McCleskey and Harry B. Gray
pp 1733 - 1734; DOI:
10.1021/ic00036a002
PDF
Distortions in the structure of calcium carbide: a theoretical investigation
Jeffrey R. Long, Roald Hoffmann, and H. Juergen Meyer
pp 1734 - 1740; DOI:
10.1021/ic00036a003
PDF
Electronic structures of dative metal-metal bonds; Ab initio molecular orbital calculations of (OC)5Os-M(CO)5 (M = tungsten, chromium) in comparison with (OC)5M-M(CO)5 (M = rhenium, manganese)
H. Nakatsuji, M. Hada, and A. Kawashima
pp 1740 - 1744; DOI:
10.1021/ic00036a004
PDF
EPR study of the toluene solution properties of the chromium(III)-alkyl complexes [CpCrMeCl]2, [Cp*CrRCl]2 (R = Me, Et, CH2SiMe3) and [Cp*CrMeBr]2: dimer-monomer equilibria in solution
Joseph A. Barrera and Dean E. Wilcox
pp 1745 - 1752; DOI:
10.1021/ic00036a005
PDF
Ligand isomerism and stacking in square planar platinum(II) complexes
M. J. Coyer, M. Croft, J. Chen, and R. H. Herber
pp 1752 - 1757; DOI:
10.1021/ic00036a006
PDF
From three- to four-coordination in copper(I) and silver(I)
Jeremy K. Burdett and Odile Eisenstein
pp 1758 - 1762; DOI:
10.1021/ic00036a007
PDF
Magnetic ordering in hexaamminecobalt(3+) pentachlorocuprate(3-): specific heat measurements
Roey Shaviv, Mary E. Redmond, and Richard L. Carlin
pp 1762 - 1763; DOI:
10.1021/ic00036a008
PDF
Studies on gold(II) complexes with hard and soft donor ligands. 3. Complexes with N-(2-pyridylmethyl)-2-mercaptoaniline
A. P. Koley, R. Nirmala, L. S. Prasad, S. Ghosh, and P. T. Manoharan
pp 1764 - 1769; DOI:
10.1021/ic00036a009
PDF
Vaporization and vapor complexation in the gold(III) chloride-aluminum(III) chloride system
L. Nalbandian, S. Boghosian, and G. N. Papatheodorou
pp 1769 - 1773; DOI:
10.1021/ic00036a010
PDF
The vapor phase formed by reaction of mixtures of aluminum, gold, and chlorine
D. S. Rustad and N. W. Gregory
pp 1774 - 1779; DOI:
10.1021/ic00036a011
PDF
Synthesis, structure, and electronic and EPR spectra of copper(II) complexes containing the tetrabromocuprate(2-) anion and triphenylarsine oxide
Antonio Carlos Massabni, Otaciro Rangel Nascimento, Kristopher Halvorson, and Roger D. Willett
pp 1779 - 1784; DOI:
10.1021/ic00036a012
PDF
Two new barium-copper-ethylene glycol complexes: synthesis and structure of BaCu(C2H6O2)n(C2H4O2)2 (n = 3, 6)
Craig P. Love, Charlie C. Torardi, and Catherine J. Page
pp 1784 - 1788; DOI:
10.1021/ic00036a013
PDF
Synthesis and structure of barium hafnium sulfides, Ba6Hf5S16 and Ba5Hf4S13: the n = 5 and 4 members of the An+1BnX3n+1 Ruddlesden-Popper phases
Bai Hao Chen, Bryan W. Eichhorn, and Philip E. Fanwick
pp 1788 - 1791; DOI:
10.1021/ic00036a014
PDF
Valence detrapping in mixed-valence biferrocenes: evidence for phase transitions
Robert J. Webb, Paula M. Hagen, Richard J. Wittebort, Michio Sorai, and David N. Hendrickson
pp 1791 - 1801; DOI:
10.1021/ic00036a015
PDF
Preparation and solid-state structures of (cyanophenyl)dithia- and (cyanophenyl)diselenadiazolyl radicals
A. W. Cordes, R. C. Haddon, R. G. Hicks, R. T. Oakley, and T. T. M. Palstra
pp 1802 - 1808; DOI:
10.1021/ic00036a016
PDF
Approaches to hexane-soluble cationic organometallic Lewis acids. Synthesis, structure, and reactivity of titanocene derivatives containing polysilylated cyclopentadienyl ligands
Charles H. Winter, Xiao Xing Zhou, and Mary Jane Heeg
pp 1808 - 1815; DOI:
10.1021/ic00036a017
PDF
Reactions of [(.eta.6-C6(CH3)6)Mn(CO)2(.eta.1-SCHSCPh3)]BF4: fast atom bombardment tandem mass spectrometry of dithioformate and thioformamide complexes. Crystal structure of [(.eta.6-C6(CH3)6)Mn(CO)2SCHNEt2]+ BF4-
Jeffrey L. Moler, Darrell P. Eyman, and Larry M. Mallis
pp 1816 - 1822; DOI:
10.1021/ic00036a018
PDF
Possible cooperative bonding between the ruthenium-bonded and the sulfur-bonded SO2 groups in CpRu(PPh3)(SO2)[S(SO2)-4-C6H4Me]
Alan Shaver and Pierre Yves Plouffe
pp 1823 - 1826; DOI:
10.1021/ic00036a019
PDF
Solid-state and solution dynamics of the reversible loss of hydrogen from the iridium nonclassical polyhydride complexes IrClH2(PR3)2(H2) (R = iso-Pr, Cy, tert-Bu)
Mario Mediati, Glen N. Tachibana, and Craig M. Jensen
pp 1827 - 1832; DOI:
10.1021/ic00036a020
PDF
Kinetics and mechanism of metal ion substitution on a cobalt(III) complex containing a pendant phenanthroline
Michael D. Johnson and Robert J. Balahura
pp 1832 - 1835; DOI:
10.1021/ic00036a021
PDF
Bimetallic reactivity, synthesis, structure and reactivity of homo- and heterobimetallic complexes of a binucleating macrocyclic ligand containing 6- and 4-coordination sites
Cassandra Fraser, Laura Johnston, Arnold L. Rheingold, Brain S. Haggerty, Graylon K. Williams, John Whelan, and B. Bosnich
pp 1835 - 1844; DOI:
10.1021/ic00036a022
PDF
Structural, Moessbauer, and EPR investigations on two oxidation states of a five-coordinate, high-spin synthetic heme. Quantitative interpretation of zero-field parameters and large quadrupole splitting
Emile L. Bominaar, Xiao Qi Ding, Abbasher Gismelseed, Eckhard Bill, Heiner Winkler, Alfred X. Trautwein, Habib Nasri, Jean Fischer, and Raymond Weiss
pp 1845 - 1854; DOI:
10.1021/ic00036a023
PDF
Spectroscopic studies of zinc benzenethiolate complexes: electron transfer to methyl viologen
Thomas Tuerk, Ute Resch, Marye Anne Fox, and Arnd Vogler
pp 1854 - 1857; DOI:
10.1021/ic00036a024
PDF
Chemistry of tetraboron tetrachloride. Synthesis and characterization of tetraboron tetrabromide (B4Br4) and observation of B4BrCl3, B4Br2Cl2, and B4Br3Cl
L. Ahmed, J. Castillo, and J. A. Morrison
pp 1858 - 1860; DOI:
10.1021/ic00036a025
PDF
Preparation and phosphorus-31 NMR characterization of structural isomers of 1,5-diphosphadithiatetrazocines: x-ray structures of 1,5-[(exo-CCl3,endo-Cl)P]2N4S2 and 1,5-Et4P2N4S2
Tristram Chivers, Mark Edwards, and Masood Parvez
pp 1861 - 1865; DOI:
10.1021/ic00036a026
PDF
Comparison of the crystalline adducts of tetrakis(triphenylacetato)dichromium(II) with benzene, p-difluorobenzene, and p-xylene
F. Albert Cotton, Lee M. Daniels, and Piotr A. Kibala
pp 1865 - 1869; DOI:
10.1021/ic00036a027
PDF
Preparation of bis(tetrabutylammonium) octa(.mu.3-chloro)hexakis(trifluoromethanesulfonato)-octahedro-hexamolybdate(2-), (Bu4N)2[Mo6Cli8(CF3SO3)a6]: a versatile starting material for substituted molybdenum(II) clusters containing the [Mo6Cli8]4+ core
Dean H. Johnston, Dennis C. Gaswick, Mark C. Lonergan, Charlotte L. Stern, and Duward F. Shriver
pp 1869 - 1873; DOI:
10.1021/ic00036a028
PDF
Ground-state variability in .mu.3-oxide trinuclear mixed-valence manganese complexes: spin frustration
James K. McCusker, Ho G. Jang, Sheyi Wang, George Christou, and David N. Hendrickson
pp 1874 - 1880; DOI:
10.1021/ic00036a029
PDF
Dinuclear complexes of platinum with the 4,4'-dipyrazolylmethane ligand. Synthesis, characterization, and x-ray crystal structure of .gamma.-bis(4,4'-dipyrazolylmethane-N,N')bis[dichloroplatinum(II)]-N,N-dimethylformamide (1/2) and related complexes
John A. Broomhead, Louis M. Rendina, and Meta Sterns
pp 1880 - 1889; DOI:
10.1021/ic00036a030
PDF
Exchange interaction through a croconato bridge: synthesis, crystal structure, and magnetic properties of (.mu.-croconato)bis[{bis(2-pyridylcarbonyl)amido}copper(II)] trihydrate
Isabel Castro, Jorunn Sletten, Juan Faus, Miguel Julve, Yves Journaux, Francesc Lloret, and Santiago Alvarez
pp 1889 - 1894; DOI:
10.1021/ic00036a031
PDF
Synthesis, characterization, and bonding of indium clusters: Na7In11.8, a novel network structure containing closo-In16 and nido-In11 clusters
Slavi C. Sevov and John D. Corbett
pp 1895 - 1901; DOI:
10.1021/ic00036a032
PDF
Thermodynamic and structural aspects of the interaction between macrocyclic polyammonium cations and complexed anions
Andrea Bencini, Antonio Bianchi, Paolo Dapporto, Enrique Garcia-Espana, Mauro Micheloni, Jose Antonio Ramirez, Piero Paoletti, and Paola Paoli
pp 1902 - 1908; DOI:
10.1021/ic00036a033
PDF
Density functional investigation of the structure and stability of SFnCl, n = 1-5, and their anions SFnCl-
G. L. Gutsev and Tom Ziegler
pp 1909 - 1913; DOI:
10.1021/ic00036a034
PDF
Pentacoordinated molecules. 92. Diequatorial and axial-equatorial orientations of eight-membered rings in monocyclic pentaoxyphosphoranes containing trifluoroethoxy groups
T. K. Prakasha, Roberta O. Day, and Robert R. Holmes
pp 1913 - 1920; DOI:
10.1021/ic00036a035
PDF
Spin state stabilities and distortions of the novel trinitridotransition metalate(6-), (M = vanadium, chromium, iron) ions
Kyeong Ae Yee and Timothy Hughbanks
pp 1921 - 1925; DOI:
10.1021/ic00036a036
PDF
Kinetics of oxidation of vanadium(IV) by alkyl hydroperoxides in acidic, aqueous solution
Rong Ma, Andreja Bakac, and James H. Espenson
pp 1925 - 1930; DOI:
10.1021/ic00036a037
PDF
Electron-transfer-induced isomerization .eta.2(C:C) .fwdarw. .eta.1(N) of the tetracyanoethylene complex, pentacarbonyl(tetracyanoethylene)tungsten (0/1-)
Thomas Roth and Wolfgang Kaim
pp 1930 - 1933; DOI:
10.1021/ic00036a038
PDF
Nuclear magnetic resonance study of the molecular and electronic structure of nickel(II) tetraphenyl-21-thiaporphyrins
Jerzy Lisowski, Lechoslaw Latos-Grazynski, and Ludmila Szterenberg
pp 1933 - 1940; DOI:
10.1021/ic00036a039
PDF
Photophysical properties of hexanuclear copper(I) and silver(I) clusters
F. Sabin, C. K. Ryu, P. C. Ford, and A. Vogler
pp 1941 - 1945; DOI:
10.1021/ic00036a040
PDF
Raman spectroscopic studies of metal-metal halide molten mixtures: the mercury-mercury(II) halide systems
G. A. Voyiatzis and G. N. Papatheodorou
pp 1945 - 1951; DOI:
10.1021/ic00036a041
PDF
Electronegativity, hardness, and chemical binding in simple molecular systems
Tapan K. Ghanty and Swapan K. Ghosh
pp 1951 - 1955; DOI:
10.1021/ic00036a042
PDF
Development of carborane synthons: synthesis and chemistry of (aminoalkyl)carboranes
J. Gerald Wilson, A. K. M. Anisuzzaman, F. Alam, and A. H. Soloway
pp 1955 - 1958; DOI:
10.1021/ic00036a043
PDF
Preparation of tin nitride via an amide-imide intermediate
Leon Maya
pp 1958 - 1960; DOI:
10.1021/ic00036a044
PDF
Bond lengths in covalent fluorides. A new value for the covalent radius of fluorine
Ronald J. Gillespie and Edward A. Robinson
pp 1960 - 1963; DOI:
10.1021/ic00036a045
PDF
A dinuclear vanadyl(IV) complex of 3,5-dicarboxypyrazole: synthesis, crystal structure, and electron spin resonance spectra
Carl W. Hahn, Paul G. Rasmussen, and J. Carlos Bayon
pp 1963 - 1965; DOI:
10.1021/ic00036a046
PDF
Conversion of chlorofluorocarbons into chlorofluorohydrocarbons using the Atherton-Todd reaction with dimethyl phosphonate
Emil Georgiev, D. Max Roundhill, and Koljo Troev
pp 1965 - 1968; DOI:
10.1021/ic00036a047
PDF
Electron-transfer reactivities of bis(.mu.-oxo)dimanganese(III,IV) dimers with tris(bipyridine)cobalt(2+) and hydroquinone
Matthew M. Monzyk and Robert A. Holwerda
pp 1969 - 1971; DOI:
10.1021/ic00036a048
PDF
Synthesis and characterization of bis(2,2'-bipyridyl)nitrocarbonylruthenium(II) hexafluorophosphate
Hiroaki Tanaka, Hirotaka Nagao, and Koji Tanaka
pp 1971 - 1973; DOI:
10.1021/ic00036a049
PDF
Synthesis, characterization, and x-ray structure of {[K(THF)2]2[U(NH-2,6-iso-Pr2C6H3)5]}.cntdot.THF
Janet E. Nelson, David L. Clark, Carol J. Burns, and Alfred P. Sattelberger
pp 1973 - 1976; DOI:
10.1021/ic00036a050
PDF
Technetium complexes of tripodal oxygen donor ligands
John Anthony Thomas and Alan Davison
pp 1976 - 1978; DOI:
10.1021/ic00036a051
PDF
Chemical applications of topology and group theory. 27. Covalent bonding in actinide derivatives
R. B. King
pp 1978 - 1980; DOI:
10.1021/ic00036a052
PDF

Issue 11


Structural and spectroscopic characterization of vanadium(V)-oxoimidazole complexes
Charles R. Cornman, Jeff Kampf, and Vincent L. Pecoraro
pp 1981 - 1983; DOI:
10.1021/ic00037a001
PDF
Gold(III) glycyl-L-histidine dipeptide complexes. Preparation and x-ray structures of monomeric and cyclic tetrameric species
Markus Wienken, Bernhard Lippert, Ennio Zangrando, and Lucio Randaccio
pp 1983 - 1985; DOI:
10.1021/ic00037a002
PDF
Synthesis and structure of a tungsten(IV) .eta.2-dimethyldiazene complex in which the diazene ligand behaves as a four-electron donor
Timothy E. Glassman, Michael G. Vale, and Richard R. Schrock
pp 1985 - 1986; DOI:
10.1021/ic00037a003
PDF
Long-lived chromium(IV) and chromium(V) metabolites in the chromium(VI)-glutathione reaction: NMR, ESR, HPLC, and kinetic characterization
Rathindra N. Bose, Shadi Moghaddas, and Edward Gelerinter
pp 1987 - 1994; DOI:
10.1021/ic00037a004
PDF
Mechanism of iron release from human serum C-terminal monoferric transferrin to pyrophosphate: kinetic discrimination between alternative mechanisms
Timothy J. Egan, David C. Ross, Langley R. Purves, and Paul A. Adams
pp 1994 - 1998; DOI:
10.1021/ic00037a005
PDF
Olefin epoxidation and alkane hydroxylation catalyzed by robust sulfonated manganese and iron porphyrins supported on cationic ion-exchange resins
Sandro Campestrini and Bernard Meunier
pp 1999 - 2006; DOI:
10.1021/ic00037a006
PDF
Iron octaethyltetraazaporphyrins: synthesis, characterization, coordination chemistry, and comparisons to related iron porphyrins and phthalocyanines
Jeffrey P. Fitzgerald, Brian S. Haggerty, Arnold L. Rheingold, Leopold May, and Gregory A. Brewer
pp 2006 - 2013; DOI:
10.1021/ic00037a007
PDF
Studies of electrocatalytic DNA cleavage by oxoruthenium(IV). X-ray crystal structure of [Ru(tpy)(tmen)OH2](ClO4)2 (tmen = N,N,N',N'-tetramethylethylenediamine, tpy = 2,2',2''-terpyridine)
Neena Grover, Nishi Gupta, Phirtu Singh, and H. Holden Thorp
pp 2014 - 2020; DOI:
10.1021/ic00037a008
PDF
Semiquinone imine complexes of ruthenium. Coordination and oxidation of the 1-hydroxy-2,4,6,8-tetra-tert-butylphenoxazinyl radical
Samaresh Bhattacharya and Cortlandt G. Pierpont
pp 2020 - 2029; DOI:
10.1021/ic00037a009
PDF
Synthesis, structure, and spectroscopic properties of vanadium(III) and -(IV) complexes containing hydridotris(pyrazolyl)borate ligands. 3
Madan Mohan, Stephen M. Holmes, Ray J. Butcher, Jerry P. Jasinski, and Carl J. Carrano
pp 2029 - 2034; DOI:
10.1021/ic00037a010
PDF
Modeling vanadium bromoperoxidase: synthesis, structure, and spectral properties of vanadium(IV) complexes with coordinated imidazole
Charles R. Cornman, Jeff Kampf, Myoung Soo Lah, and Vincent L. Pecoraro
pp 2035 - 2043; DOI:
10.1021/ic00037a011
PDF
.beta.-Halogenated-pyrrole porphyrins. Molecular structures of 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetramesitylporphyrin, nickel(II) 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetramesitylporphyrin, and nickel(II) 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin
D. Mandon, P. Ochenbein, J. Fischer, R. Weiss, K. Jayaraj, R. N. Austin, A. Gold, P. S. White, O. Brigaud, and et al.
pp 2044 - 2049; DOI:
10.1021/ic00037a012
PDF
Synthesis and molecular structure of nickel-antimony alkoxide, Ni5Sb3O2(OEt)15(HOEt)4
U. Bemm, R. Norrestam, M. Nygren, and G. Westin
pp 2050 - 2053; DOI:
10.1021/ic00037a013
PDF
Studies on the reactivity of S,N-derivatives of nickel with N-donor bases. Crystal structure and magnetic properties of the cubane cluster tetrakis(.mu.-hydroxo)tetrakis(.mu.-1,3-thiazolidine-2-thionato)tetrakis(pyridine)tetranickel(II)-dipyridine
Loreto Ballester, Eugenio Coronado, Angel Gutierrez, Angeles Monge, Maria Felisa Perpinan, Elena Pinilla, and Teresa Rico
pp 2053 - 2056; DOI:
10.1021/ic00037a014
PDF
Synthesis and characterization of group VI metal carbonyl tellurides: structures of [M4(CO)18(.mu.3-Te)2]2- (M = chromium, tungsten), [Cr4(CO)20(.eta.2-.mu.2Te2)]2-, and [Cr4(CO)20(.eta.2-.mu.2-Te3)]2-
Lisa C. Roof, William T. Pennington, and Joseph W. Kolis
pp 2056 - 2064; DOI:
10.1021/ic00037a015
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Reactions of chloro(diethylenetriamine)platinum(1+) chloride and chloro(terpyridine)platinum(1+) chloride with thiols, thioethers, and dialkyl disulfides: a platinum-195 NMR study
A. K. Fazlur-Rahman and J. G. Verkade
pp 2064 - 2069; DOI:
10.1021/ic00037a016
PDF
Cleavage of a cyclotriphosphine ring by iron carbonyls
Y. W. Li, M. G. Newton, N. K. Bhattacharyya, and R. B. King
pp 2069 - 2073; DOI:
10.1021/ic00037a017
PDF
Synthesis, absorption spectra, and luminescence properties of platinum(II) complexes with aminoquinoline and aminoacridine ligands
Luigi Monsu Scolaro, Giuseppe Alibrandi, Raffaello Romeo, Vittorio Ricevuto, and Sebastiano Campagna
pp 2074 - 2078; DOI:
10.1021/ic00037a018
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Photophysical properties of covalently attached tris(bipyridine)ruthenium(2+) and Mcyclam2+ (M = nickel, H2) complexes
Etsuko Fujita, Steven J. Milder, and Bruce S. Brunschwig
pp 2079 - 2085; DOI:
10.1021/ic00037a019
PDF
Fluorescence excitation spectra of quadruply bonded M2X4L4 complexes
Vincent M. Miskowski, Harry B. Gray, and Michael D. Hopkins
pp 2085 - 2091; DOI:
10.1021/ic00037a020
PDF
Gas-phase ion chemistry of HP2-, FP2-, and HP2+
Richard A. J. O'Hair, Michele Krempp, Robert Damrauer, and Charles H. DePuy
pp 2092 - 2096; DOI:
10.1021/ic00037a021
PDF
Cadmium-113 shielding tensors of cadmium compounds. 8. Solid-state 113Cd NMR studies of poly(bis(glycine)cadmium chloride)
Edwin Rivera and Paul D. Ellis
pp 2096 - 2103; DOI:
10.1021/ic00037a022
PDF
Chemistry of sulfur halides. 50. Structure-reactivity relationship for sulfur-fluorine compounds. Gas-phase structure of fluoro trifluoromethyl sulfoxide, CF3SOF, and trifluoro(trifluoromethyl)sulfurane, CF3SF3
Rolf Minkwitz, Walter Molsbeck, Heinz Oberhammer, and Ilse Weiss
pp 2104 - 2107; DOI:
10.1021/ic00037a023
PDF
Synthesis, structure, and properties of barium cobalt sulfide (Ba6Co25S27) a perovskite-like superstructure of Co8S6 and Ba6S clusters
G. Jeffrey Snyder, Michael E. Badding, and F. J. DiSalvo
pp 2107 - 2110; DOI:
10.1021/ic00037a024
PDF
Thermally and optically driven spin-state transitions in bis(isothiocyanato)bis(5,6-dimethylphenanthroline)iron and related complexes and the crystal structure of Fe(2,9-dmp)2 (NCS)2.cntdot.1/4H2O
D. C. Figg, R. H. Herber, and J. A. Potenza
pp 2111 - 2117; DOI:
10.1021/ic00037a025
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Homonuclear and heteronuclear metal complexes with a cyclic tetracopper(II) unit. Syntheses, crystal structures, and magnetic properties of [CuII4(dmap)3(OH)(O2CCH3)2(HO2CCH3)(H2O)][PF6]2, [CuII4(dmap)2(O2CCH3)4][PF6]2, [CuII4(dmap)2(O2CCH3)2(OH)2][HgII(O2CCH3)Cl2]2[HgIICl2], and [CuII4(dmap)2(O2CCH3)3(OH)2(H2O)][PF6] (dmap = 1,3-bis(dimethylamino)-2-propanolato)
Suning Wang, Steven J. Trepanier, Jian Chuan Zheng, Zhen Pang, and Michael J. Wagner
pp 2118 - 2127; DOI:
10.1021/ic00037a026
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Solid-state metathesis as a quick route to transition-metal mixed dichalcogenides
Philippe R. Bonneau, Robert F. Jarvis, and Richard B. Kaner
pp 2127 - 2132; DOI:
10.1021/ic00037a027
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Electronic structure and magnetic properties of the hexanuclear octahedral cluster .mu.3-octasulfidohexakis(triethylphosphine)hexacobalt(1+) tetraphenylborate
Alessandro Bencini, Stefano Midollini, and Claudia Zanchini
pp 2132 - 2137; DOI:
10.1021/ic00037a028
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Kinetic study of the reaction of 3-methylascorbic acid with aqueous iron(III)
M. J. Sisley and R. B. Jordan
pp 2137 - 2143; DOI:
10.1021/ic00037a029
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Iron(III)-catalyzed decomposition of the chlorite ion: an inorganic application of the quenched stopped-flow method
Istvan Fabian and Gilbert Gordon
pp 2144 - 2150; DOI:
10.1021/ic00037a030
PDF
Mechanism of oxidation of (meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) by hydroperoxyl free radicals in aqueous solutions. A pulse radiolysis study
Avraham Meshulam, Haim Cohen, Rudi Van Eldik, and Dan Meyerstein
pp 2151 - 2156; DOI:
10.1021/ic00037a031
PDF
Preparation and phosphorus-31 NMR investigations of monomeric and dimeric complexes of platinum and palladium with 1,5-diphosphadithiatetrazocines: x-ray structure of Pt(PPh3)2(1,5-Ph4P2N4S2).cntdot.CH2Cl2
Tristram Chivers, Mark Edwards, Auke Meetsma, Johan C. Van de Grampel, and Arie Van der Lee
pp 2156 - 2161; DOI:
10.1021/ic00037a032
PDF
Experimental and ab-initio stability correlations among isomeric methyl derivatives of closo- and nido-monocarbahexaboranes
Thomas Onak, James Tseng, Dan Tran, Mario Correa, Sergio Herrera, and Joachin Arias
pp 2161 - 2166; DOI:
10.1021/ic00037a033
PDF
A topological method for the enumeration of bridging modes and connectivity patterns of the clusters MmQnLl with four-coordinate metal sites and Q.mu.2,3,4 bridging atoms
Jing Feng You and R. H. Holm
pp 2166 - 2175; DOI:
10.1021/ic00037a034
PDF
Anisotropies of the phosphorus-31 chemical shift and 31P-195Pt indirect spin-spin coupling in platinum(II) phosphines
William P. Power and Roderick E. Wasylishen
pp 2176 - 2183; DOI:
10.1021/ic00037a035
PDF
Electronic absorption and magnetic ciruclar dichroism spectra for binuclear diplatinum(III) Pt2(SO4)4X2n- and Pt2(HPO4)4X2n- ions in aqueous solution
Gulsun Gokagac, Huseyin Isci, and W. Roy Mason
pp 2184 - 2191; DOI:
10.1021/ic00037a036
PDF
Effects of .pi.-.pi. interactions on molecular structure and resonance Raman spectra of crystalline copper(II) octaethylporphyrin
L. D. Sparks, W. Robert Scheidt, and J. A. Shelnutt
pp 2191 - 2196; DOI:
10.1021/ic00037a037
PDF
Luminescence of copper(I) arenethiolates and its relation to copper(I) luminescence in other complexes
D. Martin Knotter, George Blasse, Jacques P. M. Van Vliet, and Gerard Van Koten
pp 2196 - 2201; DOI:
10.1021/ic00037a038
PDF
Relationships between extended structures and molecular clusters of nickel and tellurium
Zafiria Nomikou, Boris Schubert, Roald Hoffmann, and M. L. Steigerwald
pp 2201 - 2209; DOI:
10.1021/ic00037a039
PDF
Binuclear lead(II) and copper(II) complexes of 1,4-dihydrazinophthalazine (DHPH). Stabilization of copper(II) in the presence of a hydrazine moiety and x-ray crystal structure and magnetic properties of [Cu2(DHPH)2 (H2O)2(ClO4)2](ClO4)2
Santokh S. Tandon, Laurence K. Thompson, and Rosemary C. Hynes
pp 2210 - 2214; DOI:
10.1021/ic00037a040
PDF
Copper coordination chemistry of novel octadentate, tetranucleating, bis(diazine) ligands. Structural and magnetic properties of tetranuclear complexes involving a rectangular array of copper(II) centers
Santokh S. Tandon, Sanat K. Mandal, Laurence K. Thompson, and Rosemary C. Hynes
pp 2215 - 2222; DOI:
10.1021/ic00037a041
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A new class of planar (platinum-mercury) mixed metal clusters containing a [Pt3(CO)3(PR3)3] moiety capped by two HgX units
Alberto Albinati, Klaus Hermann Dahmen, Francesco Demartin, Jennifer M. Forward, Cindy J. Longley, D. Michael P. Mingos, and Luigi M. Venanzi
pp 2223 - 2229; DOI:
10.1021/ic00037a042
PDF
High-pressure NMR kinetics. 54. N,N-dimethylformamide exchange on hexakis(N,N-dimethylformamide)titanium(III): a variable-temperature and pressure proton and oxygen-17 NMR study
Ivo Dellavia, Lothar Helm, and Andre E. Merbach
pp 2230 - 2233; DOI:
10.1021/ic00037a043
PDF
Syntheses and reactivity of nickel complexes of 8-aza-1,5-dithiacyclodecane and the macrobicyclic ligand 1,2-bis(8-aza-1,5-dithia-8-cyclodecanyl)ethane
S. Chandrasekhar and A. McAuley
pp 2234 - 2240; DOI:
10.1021/ic00037a044
PDF
Two bis(thiolethionedithiolato)nickelate (1-) compounds with a divalent closed-shell cation: synthesis, crystal structure, and electrical conductivity of [Me3N(CH2)4NMe3][Ni(dmit)2]5.cntdot.2dmf and [Me3N(CH2)4NMe3][Ni(dmit2]5.cntdot.CH3CN
Joost P. Cornelissen, Edgar Muller, Peter H. S. Vaassens, Jaap G. Haasnoot, Jan Reedijk, and Patrick Cassoux
pp 2241 - 2248; DOI:
10.1021/ic00037a045
PDF
Chemistry of iron oxophlorins. 1. Proton NMR and structural studies of five-coordinate iron(III) complexes
Alan L. Balch, Lechoslaw Latos-Grazynski, Bruce C. Noll, Marilyn M. Olmstead, and Edward P. Zovinka
pp 2248 - 2255; DOI:
10.1021/ic00037a046
PDF
Syntheses, structures, and properties of copper(II) and copper(I) complexes of the new binucleating ligand 1,3-bis[bis(2-pyridylmethyl)amino]benzene
Siegfried Schindler, David J. Szalda, and Carol Creutz
pp 2255 - 2264; DOI:
10.1021/ic00037a047
PDF
Subtle effects of solvate molecules on the rate of intramolecular electron transfer of mixed-valence complexes in the solid state
Ho G. Jang, Richard J. Wittebort, Michio Sorai, Yuki Kaneko, Motohiro Nakano, and David N. Hendrickson
pp 2265 - 2271; DOI:
10.1021/ic00037a048
PDF
Reinvestigation of the reaction of triphenylphosphine with tetracyanoethylene: molecular structure of N-(heptacyanocyclopent-1-enyl)triphenylphosphoranimine
T. Mohan, Roberta O. Day, and Robert R. Holmes
pp 2271 - 2273; DOI:
10.1021/ic00037a049
PDF
Synthesis, characterization, and x-ray crystal structure of the paramagnetic solid 5-(trifluoromethyl)-1,2,3,4-trithiazolium hexafluoroarsenate, containing the novel, planar 7.pi. CF3CNSSS+.bul. radical cation
T. Stanley Cameron, Robert C. Haddon, Saba M. Mattar, Simon Parsons, Jack Passmore, and Arthur P. Ramirez
pp 2274 - 2279; DOI:
10.1021/ic00037a050
PDF
Deriving chemical parameters from electrostatic potential maps of molecular anions
Shridhar R. Gadre, Christoph Koelmel, and Indira H. Shrivastava
pp 2279 - 2281; DOI:
10.1021/ic00037a051
PDF
Complexes of tetrathiomolybdate and -tungstate with copper(I) and silver(I): sulfur-33 NMR properties
M. Kony, R. T. C. Brownlee, and A. G. Wedd
pp 2281 - 2282; DOI:
10.1021/ic00037a052
PDF
Newly resolved ESR spectrum of a low-spin cobalt(II) macrocyclic complex in 3-methylpyridine
Abbas Pezeshk
pp 2282 - 2284; DOI:
10.1021/ic00037a053
PDF
Time-resolved infrared spectroscopy of tetrakis(1,3-diisocyanopropane)dirhodium(2+) tetraphenylborate
Stephen K. Doorn, Keith C. Gordon, R. Brian Dyer, and William H. Woodruff
pp 2284 - 2285; DOI:
10.1021/ic00037a054
PDF
Unexpected formation of a novel divanadium(IV) monophosphine complex
A. K. Fazlur-Rahman, V. G. Young, and J. G. Verkade
pp 2285 - 2287; DOI:
10.1021/ic00037a055
PDF
Simple, high yield syntheses of molybdenum(VI) bis(imido) complexes of the type Mo(NR)2Cl2(1,2-dimethoxyethane)
Harold H. Fox, Kimo B. Yap, Jennifer Robbins, Shiang Cai, and Richard R. Schrock
pp 2287 - 2289; DOI:
10.1021/ic00037a056
PDF
Crystal structure, infrared, and NMR spectra of tetrakis(pyridine-N)sodium octacarbonyldiiron {[(C5H5N)4Na]2[Fe2(CO)8]}.infin.: a two-dimensional extended structure due to sodium-isocarbonyl interactions
Haibin Deng and Sheldon G. Shore
pp 2289 - 2291; DOI:
10.1021/ic00037a057
PDF
Syntheses and molecular structures of an unusual cyclic tetrameric organometallic complex, [(CH3)2Al[.mu.-N(iso-C3H7)2]2Mg(CH3)]4, containing tricoordinate magnesiums, and a linear dimer, [(CH3)2Al[.mu.-N(C2H5)2]2Mg(CH3)]2, containing tetracoordinate magnesiums
Tzong Yih Her, Chung Cheng Chang, and Ling Kang Liu
pp 2291 - 2294; DOI:
10.1021/ic00037a058
PDF
Bonding properties of calcium gallium arsenide, Ca14GaAs11: a compound containing discrete GaAs4 tetrahedra and a hypervalent As3 polyatomic unit. [Erratum to document cited in CA116(4):28472t]
R. F. Gallup, C. Y. Fong, and Susan M. Kauzlarich
pp 2294 - 2294; DOI:
10.1021/ic00037a059
PDF
Reactions of a cobalt-molybdenum and related cobalt-tungsten tetrahedral clusters with phenylacetylene: formation of tetrametallic alkyne clusters or cluster fragmentation? [Erratum to document cited in CA115(25):280228y]
Michael J. Chetcuti, Phillip E. Fanwick, and John C. Gordon
pp 2294 - 2294; DOI:
10.1021/ic00037a060
PDF

Issue 12


Two unusual formate-bridged manganese(III) tetraphenylporphyrin complexes
Peter Turner, Maxwell J. Gunter, Trevor W. Hambley, Allan H. White, and Brian W. Skelton
pp 2295 - 2297; DOI:
10.1021/ic00038a001
PDF
Examples of large closo boron hydride analogs of carbon fullerenes
William N. Lipscomb and Lou Massa
pp 2297 - 2299; DOI:
10.1021/ic00038a002
PDF
Stereochemistry of six-coordinated silicon complexes. 2. Optical resolution of [Si(.alpha.-diimine)3]4+ (.alpha.-diimine = 2,2'-bipyridine, 1,10-phenanthroline)
Yasuharu Ohmori, Mizue Namba, Yasushige Kuroda, Masaaki Kojima, and Yuzo Yoshikawa
pp 2299 - 2300; DOI:
10.1021/ic00038a003
PDF
Complexes of platinum(II) with the polymeric amine ligand polyaziridine
Lidia Barbosa and Alex Von Zelewsky
pp 2300 - 2305; DOI:
10.1021/ic00038a004
PDF
Electrochemistry of rhodium and cobalt corroles. Characterization of (OMC)Rh(PPh3) and (OMC)Co(PPh3) where OMC is the trianion of 2,3,7,8,12,13,17,18-octamethylcorrole
K. M. Kadish, W. Koh, P. Tagliatesta, D. Sazou, R. Paolesse, S. Licoccia, and T. Boschi
pp 2305 - 2313; DOI:
10.1021/ic00038a005
PDF
Kinetics and mechanism of the reaction of a quasi-aromatic nickel(II) complex, [Ni((PnAO)-6H]0, with formaldehyde
Bin Song, Qi Yan Zhang, Yun Ti Chen, and R. Kent Murmann
pp 2314 - 2317; DOI:
10.1021/ic00038a006
PDF
Donor-acceptor electronic coupling as a function of bridging group: mixed-valence diruthenium(II,III) complexes bridged by isonicotinato and isonicotinamido ligands
Mei H. Chou, Carol Creutz, and Norman Sutin
pp 2318 - 2327; DOI:
10.1021/ic00038a007
PDF
Electrochemical studies of tris(acetylacetonato)ruthenium(III) in ambient-temperature chloroaluminate molten salts
Jinsong Tang, Kunio Shimizu, and Robert A. Osteryoung
pp 2328 - 2333; DOI:
10.1021/ic00038a008
PDF
Observation of radical intermediates for unusual carbon-nitrogen bond formation of .alpha.-aminomalonate to give an .alpha.-diamine linkage. ESR studies on electron transfer reactions in cobalt(III)-polyamine complexes
Takahiko Kojima, Junichi Tsuchiya, Satoru Nakashima, Hiroaki Ohya-Nishiguchi, Shigenobu Yano, and Masanobu Hidai
pp 2333 - 2340; DOI:
10.1021/ic00038a009
PDF
1,3,5-Triamino-1,3,5-trideoxy-cis-inositol, a new ligand with a remarkable versatility for metal ions. 1. Preparation, x-ray structure, and stability of the nickel(II), copper(II), and zinc(II) complexes
Kaspar Hegetschweiler, Volker Gramlich, Michele Ghisletta, and Heinz Samaras
pp 2341 - 2346; DOI:
10.1021/ic00038a010
PDF
Effect of "noncomplexing" anions on copper(II)-macrocyclic tetrathiaether complexes. Evaluation of dissociation kinetics in aqueous solution using mercury(II) ion as scavenger
Leonard L. Diaddario, L. A. Ochrymowycz, and D. B. Rorabacher
pp 2347 - 2353; DOI:
10.1021/ic00038a011
PDF
Stereochemical nonrigidity in thioether complexes
Huikang Wu and C. Robert Lucas
pp 2354 - 2358; DOI:
10.1021/ic00038a012
PDF
Rhenium polyhydride complexes that contain the tripodal phosphine CH3C(CH2PPh2)3 (triphos)
Michael T. Costello, Phillip E. Fanwick, Mark A. Green, and Richard A. Walton
pp 2359 - 2365; DOI:
10.1021/ic00038a013
PDF
Crystal and molecular structures of pentaphenylcyclopentadiene and of an isomer, 4,8-diphenyltribenzo[b,f,i]tricyclo[6.2.1.01,5]undecane, the product of a novel metal-assisted photoreaction
Leslie D. Field, Trevor W. Hambley, Charles M. Lindall, and Anthony F. Masters
pp 2366 - 2370; DOI:
10.1021/ic00038a014
PDF
Auration of an aryltris[(triarylphosphine)aurio(I)]phosphonium(+) cation to give a hypercoordinate aryltetrakis[(triarylphosphine)aurio(I)]phosphonium(2+) dication
Hubert Schmidbaur, Edgar Zeller, Gabriele Weidenhiller, Oliver Steigelmann, and Holger Beruda
pp 2370 - 2376; DOI:
10.1021/ic00038a015
PDF
Synthesis, characterization, and reactivity of ruthenium carbonyl complexes containing a chelating triphosphine ligand and two weakly coordinated anions
Patrick W. Blosser, Judith C. Gallucci, and Andrew Wojcicki
pp 2376 - 2384; DOI:
10.1021/ic00038a016
PDF
Further study of tetracarbonato diruthenium(II,III) compounds
F. Albert Cotton, Luca Labella, and Maoyu Shang
pp 2385 - 2389; DOI:
10.1021/ic00038a017
PDF
Electrochemistry of [.mu.-2,2'-bipyrimidinebis[bis(2,2'-bipyridine)ruthenium(2+)] hexafluorophosphate. Complete assignment of individual reduction steps
Michael Krejcik and A. A. Vlcek
pp 2390 - 2395; DOI:
10.1021/ic00038a018
PDF
Spectroscopic and theoretical studies on the excited state in diimine dithiolate complexes of platinum(II)
Juan A. Zuleta, Joanne M. Bevilacqua, Davide M. Proserpio, Pierre D. Harvey, and Richard Eisenberg
pp 2396 - 2404; DOI:
10.1021/ic00038a019
PDF
Structural information on chromium(V) complexes of 1,2-diols in solution, as determined by isotropic and anisotropic proton ENDOR spectroscopy
Mario Branca, Giovanni Micera, Ulderico Segre, and Alessandro Dessi
pp 2404 - 2408; DOI:
10.1021/ic00038a020
PDF
Structural analysis of platinum phosphine complexes by two-dimensional phosphorus-31 NMR spectroscopy
Jane V. Zeile Krevor, Ursula Simonis, and Julianne A. Richter
pp 2409 - 2414; DOI:
10.1021/ic00038a021
PDF
Diphosphiranes: formation and ionic ring opening, a theoretical approach
C. Tachon, M. Gouygou, M. Koenig, M. J. Herve, D. Gonbeau, and G. Pfister-Guillouzo
pp 2414 - 2422; DOI:
10.1021/ic00038a022
PDF
Synthesis, characterization, and 1/T1 NMRD profiles of gadolinium(III) complexes of monoamide derivatives of DOTA-like ligands. X-ray structure of the 10-[2-[[2-hydroxy-1-(hydroxymethyl)ethyl]amino]-1-[(phenylmethoxy)methyl]-2-oxoethyl]-1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid-gadolinium(III) complex
Silvio Aime, Pier Lucio Anelli, Mauro Botta, Franco Fedeli, Maurizio Grandi, Paola Paoli, and Fulvio Uggeri
pp 2422 - 2428; DOI:
10.1021/ic00038a023
PDF
Platinum(II) coordination to N1 and N7,N1 of guanine: cis-DDP model cross-links in the interior and simultaneous cross-links at the periphery and the interior of DNA
Gudrun Frommer, Ilpo Mutikainen, Ferdinand J. Pesch, Edda C. Hillgeris, Hans Preut, and Bernhard Lippert
pp 2429 - 2434; DOI:
10.1021/ic00038a024
PDF
Diplatinum and heteronuclear complexes derived from (tmeda)Pt(1-MeU)2 (tmeda = N,N,N',N'-tetramethylethylenediamine, 1-MeU = 1-methyluracilate-N3). Steric effect of the tmeda ligand on the orientation of the second metal
Gudrun Frommer, Francesca Lianza, Alberto Albinati, and Bernhard Lippert
pp 2434 - 2439; DOI:
10.1021/ic00038a025
PDF
Hydroxyl radical induced decarboxylation and deamination of 2-methylalanine catalyzed by copper ions
Sara Goldstein, Gidon Czapski, Haim Cohen, and Dan Meyerstein
pp 2439 - 2444; DOI:
10.1021/ic00038a026
PDF
Chiral recognition between dissymmetric Ln(dpa)33- and cobalt(III)-nucleotide complexes in aqueous solution. Enantioselective luminescence quenching as a probe of intermolecular chiral discrimination
David H. Metcalf, John M. M. Stewart, Seth W. Snyder, Charles M. Grisham, and F. S. Richardson
pp 2445 - 2455; DOI:
10.1021/ic00038a027
PDF
Unusual behavior of 5,10,15,20-tetraphenylporphine diacid toward oxygen Broensted bases
Rafik Karaman and Thomas C. Bruice
pp 2455 - 2459; DOI:
10.1021/ic00038a028
PDF
Molar volumes of coordination complexes in nonaqueous solution: correlation with computed van der Waals volumes, crystal unit cell volumes, and charge
Dat Tran, John P. Hunt, and Scot Wherland
pp 2460 - 2464; DOI:
10.1021/ic00038a029
PDF
Molecular structure of 1-thia-closo-dodecaborane(II) studied by electron diffraction complemented by ab initio calculations
Drahomir Hnyk, Erzsebet Vajda, Michael Buehl, and Paul v. R. Schleyer
pp 2464 - 2467; DOI:
10.1021/ic00038a030
PDF
Transition metal carbonyl clusters. A molecular mechanics approach to ligand stereochemistry
Angelo Sironi
pp 2467 - 2475; DOI:
10.1021/ic00038a031
PDF
Synthesis and spectra of cis-chloronitridobis(phenanethroline)technetium(1+) chloride hydrate and hexafluorophosphate and considerations of their structural distortions
M. J. Clarke and Jun Lu
pp 2476 - 2480; DOI:
10.1021/ic00038a032
PDF
New 12-membered and 24-membered macrocycles with pendent acetato groups and x-ray crystal structures of the copper(II) and manganese(II) complexes
Michiko B. Inoue, Carmen A. Villegas, Koichi Asano, Masanobu Nakamura, Motomichi Inoue, and Quintus Fernando
pp 2480 - 2483; DOI:
10.1021/ic00038a033
PDF
Synthesis and characterization of the pseudo-1-D mixed-valence (Et4-nMenN)Cu2X4 salts: pinned charge density wave systems exhibiting intervalence charge transfer
Brian Scott, Roger Willett, Leigh Porter, and Jack Williams
pp 2483 - 2492; DOI:
10.1021/ic00038a034
PDF
Formation of bimetallic, trimetallic, and pentametallic yttrium methoxide and methoxide oxide complexes from reactions of alkali-metal methoxides with bis(cyclopentadienyl)yttrium chloride
William J. Evans, Mark S. Sollberger, Julie L. Shreeve, Jeffrey M. Olofson, John H. Hain, and Joseph W. Ziller
pp 2492 - 2501; DOI:
10.1021/ic00038a035
PDF
Double oxidative carbon-carbon coupling of a dimeric orthopalladated amido complex leading to redox-active tetrapalladia units [Pd4]n+ (n = 0-4)
Pablo Espinet, Maria Y. Alonso, Gabriel Garcia-Herbosa, Jose M. Ramos, Y. Jeannin, and M. Philoche-Levisalles
pp 2501 - 2507; DOI:
10.1021/ic00038a036
PDF
Zinc, cadmium, and mercury tellurolates: hydrocarbon solubility and low coordination numbers enforced by sterically encumbered silyltellurolate ligands
Philip J. Bonasia and John Arnold
pp 2508 - 2514; DOI:
10.1021/ic00038a037
PDF
Kinetic, isotopic, and nitrogen-15 NMR study of N-hydroxybenzenesulfonamide decomposition: an nitrosyl hydride (HNO) source reaction
Francis T. Bonner and Younghee Ko
pp 2514 - 2519; DOI:
10.1021/ic00038a038
PDF
Mono- and bis(dibenzotetramethyltetraaza[14]annulene) complexes of Group IV metals including the structure of the lithium derivative of the macrocyclic ligand
Stefania De Angelis, Euro Solari, Emma Gallo, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 2520 - 2527; DOI:
10.1021/ic00038a039
PDF
Synthesis and properties of chloryl chloride, ClClO2
Holger S. P. Mueller and Helge Willner
pp 2527 - 2534; DOI:
10.1021/ic00038a040
PDF
Synthesis of .omega.-(aminoalkyl)-1,2-closo-dicarbadodecaboranes(12)
Jonas Malmquist and Stefan Sjoeberg
pp 2534 - 2537; DOI:
10.1021/ic00038a041
PDF
Trifluoromethylation and pentafluorophenylation of sulfur and carbon centers using (trifluoromethyl)- and (pentafluorophenyl)trimethylsilane
Nimesh R. Patel and Robert L. Kirchmeier
pp 2537 - 2540; DOI:
10.1021/ic00038a042
PDF
Facile .alpha./.beta. diastereomerism in organocobalt corrinoids. Studies of the interconversion of diastereomers by thermolysis, photolysis, and cobalt-to-cobalt alkyl group transfer
Kenneth L. Brown and Xiang Zou
pp 2541 - 2547; DOI:
10.1021/ic00038a043
PDF
Rates of substitution by sulfur nucleophiles in cis-diamminebis(guanosine) platinum(II) chloride
Julie A. Beaty and Mark M. Jones
pp 2547 - 2551; DOI:
10.1021/ic00038a044
PDF
Vibrational spectroscopic studies of a hydroxo-bridged dinuclear copper complex, a potential model for multicopper proteins
Jinshu Ling, Amjad Farooq, Kenneth D. Karlin, Thomas M. Loehr, and Joann Sanders-Loehr
pp 2552 - 2556; DOI:
10.1021/ic00038a045
PDF
Cluster synthesis. 38. Formation of high-nuclearity platinum-osmium cluster complexes. Synthesis, structural characterizations, and interrelationships of Pt4Os6(CO)22(COD), Pt5Os6(CO)21(COD)2, Pt4Os6(CO)19(COD)2, and Pt7Os6(CO)21(COD)2, (COD = cycloocta-1,5-diene)
Richard D. Adams, Jau Ching Lii, and Wengan Wu
pp 2556 - 2562; DOI:
10.1021/ic00038a046
PDF
Coordination of trialkoxysilyl ligands in triosmium cluster complexes. Complexes with edge and triply bridging trialkoxysilyl ligands
Richard D. Adams, Jeffrey E. Cortopassi, and Michael P. Pompeo
pp 2563 - 2568; DOI:
10.1021/ic00038a047
PDF
Formation of luminescent, metal-metal bonded, 3:5 complexes using palladium(II) or platinum(II) and iridium(I) through chelate ring openings
Alan L. Balch and Vincent J. Catalano
pp 2569 - 2575; DOI:
10.1021/ic00038a048
PDF
Coordination chemistry of higher oxidation states. 39. Structural and spectroscopic studies on manganese(IV) periodato complexes. Crystal structure of Na7[Mn(HIO6)2(H2IO6)].cntdot.18H2O
William Levason, Mark D. Spicer, and Michael Webster
pp 2575 - 2579; DOI:
10.1021/ic00038a049
PDF
Syntheses and reactions of the cis-PtCl2{Ph2P(CH2CH2O)nCH2CH2PPh2-P,P'} (n = 3-5) metallacrown ether complexes. The x-ray crystal structures of the n = 4 and 5 complexes and of [cis-Pt{Ph2P(CH2CH2O)4CH2CH2PPh2-P,P',O}(H2O)](BF4)2
Ashima Varshney, Mary L. Webster, and Gary M. Gray
pp 2580 - 2587; DOI:
10.1021/ic00038a050
PDF
Oxovanadium(IV)-amide binding. Synthetic, structural, and physical studies of {N-[2-(4-oxopent-2-en-2-ylamino)phenyl]pyridine-2-carboxamido}oxovanadium(IV) and {N-[2-(4-phenyl-4-oxobut-2-en-2-ylamino)phenyl]pyridine-2-carboxamido}oxovanadium(IV)
Graeme R. Hanson, Themistoklis A. Kabanos, Anastasios D. Keramidas, Dimitris Mentzafos, and Aris Terzis
pp 2587 - 2594; DOI:
10.1021/ic00038a051
PDF
Formation of the trans-[dioxorhenium(1+)] group from the reactions of ReNCl2(PPh3)2, ReCl4(PPh3)2, and ReCl3(CH3CN)(PPh3)2 with chelating amines and tetraazamacrocycles. Crystal structure of trans-[ReO2(cyclam)](PF6) (cyclam = 1,4,8,11-tetraazacyclotetradecane)
Silvio Alvarez Luna, Cristina Bolzati, Adriano Duatti, Gian Luigi Zucchini, Giuliano Bandoli, and Fiorenzo Refosco
pp 2595 - 2598; DOI:
10.1021/ic00038a052
PDF
Low-dimensional molecular metals bis(maleonitriledithiolato)bis(perylene)metal, metal = iron and cobalt
Vasco Gama, Rui T. Henriques, Gregoire Bonfait, Laura C. Pereira, Joao C. Waerenborgh, Isabel C. Santos, M. Teresa Duarte, Joao M. P. Cabral, and Manuel Almeida
pp 2598 - 2604; DOI:
10.1021/ic00038a053
PDF
Pressure dependence of the rate constants for the electron/atom self-exchange between MII (cp2 and MIV) (cp)2 = X+ (M = ruthenium, osmium; X = bromide, iodide; cp = cyclopentadienide) as a function of solvent
Kim A. Anderson, Karl Kirchner, Harold W. Dodgen, John P. Hunt, and Scot Wherland
pp 2605 - 2608; DOI:
10.1021/ic00038a054
PDF
Compounds containing linked, multiply-bonded dimetal units. 1. Tetrakis-(.mu.-6-chloro-2-hydroxypyridinato)diruthenium(II,III) cations linked axially by pyrazine. Comparison with a single molecule axially coordinated by pyridine
F. Albert Cotton, Youngmee Kim, and Tong Ren
pp 2608 - 2612; DOI:
10.1021/ic00038a055
PDF
Small heteroborane cluster systems. 5. Factors affecting the 2D 11B-11B (boron-11) COSY NMR spectra of terminal- and bridge-substituted pentaborane cluster systems
Bruce H. Goodreau and James T. Spencer
pp 2612 - 2621; DOI:
10.1021/ic00038a056
PDF
Interaction of metal cluster ketenylidenes, [M3(CO)9(CCO)]2- (M = iron, ruthenium) with the soft electrophiles copper(I) iodide and CuPR3+
Anuradha S. Gunale, Michael P. Jensen, David A. Phillips, Charlotte L. Stern, and Duward F. Shriver
pp 2622 - 2626; DOI:
10.1021/ic00038a057
PDF
New nickel(II)-copper(II) heterodinuclear complexes with hexa- and pentacoordinated nickel(II) ions. Magnetostructural correlations
Albert Escuer, Ramon Vicente, Joan Ribas, Ramon Costa, and Xavier Solans
pp 2627 - 2633; DOI:
10.1021/ic00038a058
PDF
Synthesis, structure and magnetic properties of hexakis(.mu.-tert-butoxo)bis(perfluoro-tert-butoxo)tetracopper and tetrakis(.mu.-tert-butoxo)bis(perfluoro-tert-butoxo)tricopper
A. P. Purdy, C. F. George, and G. A. Brewer
pp 2633 - 2638; DOI:
10.1021/ic00038a059
PDF
Molecular mechanics calculations of transition metal complexes
Paul V. Bernhardt and Peter Comba
pp 2638 - 2644; DOI:
10.1021/ic00038a060
PDF
Determination of solution structures of binuclear copper(II) complexes
Paul V. Bernhardt, Peter Comba, Trevor W. Hambley, Salah S. Massoud, and Sandra Stebler
pp 2644 - 2651; DOI:
10.1021/ic00038a061
PDF
Why the addition of carbon monoxide leads to acyl decarbonylation in a supported rhodium dimer complex
S. F. Jen and Alfred B. Anderson
pp 2651 - 2654; DOI:
10.1021/ic00038a062
PDF
A new and convenient synthesis of sodium carboxylatotrihydroborate (Na2BH3CO2) a boron analog of sodium acetate
Anup Sood and Bernard F. Spielvogel
pp 2654 - 2655; DOI:
10.1021/ic00038a063
PDF
Oxidation state of platinum in oxidative-addition reactions and .eta.1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic x-ray photoelectron spectroscopy
J. C. Muijsers, J. W. Niemantsverdriet, I. C. M. Wehman-Ooyevaar, D. M. Grove, and G. Van Koten
pp 2655 - 2658; DOI:
10.1021/ic00038a064
PDF
Syntheses of the seven-metal [nickel-osmium] carbide cluster [PPN]2[Os3Ni4C(CO)15] and of [PPN]2[Os3Ni3C(CO)13]
G. B. Karet, R. L. Espe, C. L. Stern, and D. F. Shriver
pp 2658 - 2660; DOI:
10.1021/ic00038a065
PDF
Two salts of bis(ethanol)(meso-tetraphenylporphinato)iron(III). Molecular structures and magnetic susceptibilities
W. Robert Scheidt, David K. Geiger, Young Ja Lee, Pierre Gans, and Jean Claude Marchon
pp 2660 - 2663; DOI:
10.1021/ic00038a066
PDF
Evidence for ligand isomerism in the palladium(II) complex of 1,4,7-trithiacyclodecane
S. Chandrasekhar and A. McAuley
pp 2663 - 2665; DOI:
10.1021/ic00038a067
PDF
Synthesis and solvolysis of benzylamine-boranes
Kevin E. Bell and Henry C. Kelly
pp 2665 - 2667; DOI:
10.1021/ic00038a068
PDF
Comments on the synthesis of trisulfonated triphenylphosphine: reaction monitoring by NMR spectroscopy
Tamas Bartik, Berit Bartik, Brian E. Hanson, Tom Glass, and William Bebout
pp 2667 - 2670; DOI:
10.1021/ic00038a069
PDF
Unusual metalloporphycenes. First syntheses of carbonyl- and dioxo-containing osmium and ruthenium tetrapropylporphycene complexes
Zao Ying Li, Jie Sheng Huang, Chi Ming Che, and C. K. Chang
pp 2670 - 2672; DOI:
10.1021/ic00038a070
PDF
Transition-metal clusters as substituents. Synthesis, structure, and thermal decomposition of Zn4O[(CO)9Co3(.mu.3-CCO2)]6. [Erratum to document cited in CA116(5):41702n]
Wei Cen, Kenneth J. Haller, and Thomas P. Fehlner
pp 2672 - 2672; DOI:
10.1021/ic00038a071
PDF

Issue 13


Gallane/phosphine adducts: air-stable H3Ga.cntdot.P(C6H11)3 and gallane rich 2H3Ga.cntdot.(PMe2CH2)2
Jerry L. Atwood, Frederick R. Bennett, Fiona M. Elms, George A. Koutsantonis, Colin L. Raston, Kerry D. Robinson, and David J. Young
pp 2673 - 2674; DOI:
10.1021/ic00039a001
PDF
Synthesis of pyridine complexes of zirconium(III) chloride and the apparent oxidation to zirconium(IV) by a nitrile
David M. Hoffman and Samkeun Lee
pp 2675 - 2676; DOI:
10.1021/ic00039a002
PDF
Reversible cleavage of the chromium-chromium multiple bond in [(TAA)Cr]2 (TAA = tetramethyldibenzotetraaza[14]annulene)
Shoukang Hao, Jilles H. H. Edema, Sandro Gambarotta, and Corinne Bensimon
pp 2676 - 2678; DOI:
10.1021/ic00039a003
PDF
Mixed-valence nitride-bridged vanadium compounds. Synthesis and structure of V2(N)Cl5(TMEDA)2
Kate L. Sorensen, Megan E. Lerchen, Joseph W. Ziller, and Nancy M. Doherty
pp 2678 - 2679; DOI:
10.1021/ic00039a004
PDF
Isomerism in coordinatively unsaturated tricarbonyl-.eta.2-etheneiron complexes
Terence M. Barnhart, Richard F. Fenske, and Robert J. McMahon
pp 2679 - 2681; DOI:
10.1021/ic00039a005
PDF
Catalytic and stereoselective activities of manganese achiral and chiral porphyrins in dioxygenation of tryptophan derivatives
Katsutoshi Ohkubo, Takashi Sagawa, and Hitoshi Ishida
pp 2682 - 2688; DOI:
10.1021/ic00039a006
PDF
Resonance Raman and magnetic resonance spectroscopic characterization of the Fe(I), Fe(II), Fe(III), and Fe(IV) oxidation states of Fe(2-TMPyP)n+(aq)
Kenton R. Rodgers, Robert A. Reed, Y. Oliver Su, and Thomas G. Spiro
pp 2688 - 2700; DOI:
10.1021/ic00039a007
PDF
Kinetics of iron removal from monoferric and cobalt-labeled monoferric transferrins by diethylenetriaminepenta(methylenephosphonic acid) and diethylenetriaminepentaacetic acid
Wesley R. Harris, Pawan K. Bali, and Michael M. Crowley
pp 2700 - 2705; DOI:
10.1021/ic00039a008
PDF
Synthesis of poly(3,5-dicarbomethoxypyrazolato)copper and its reactions with carbon monoxide and cyclohexyl isocyanide. Crystal structures of [Cu2(dcmpz)2(py)2(CO)] and [Cu(dcmpz)(RNC)]2 (Hdcmpz = 3,5-dicarbomethoxypyrazole, R = cyclohexyl)
G. Attilio Ardizzoia, Egle M. Beccalli, Girolamo La Monica, Norberto Masciocchi, and Massimo Moret
pp 2706 - 2711; DOI:
10.1021/ic00039a009
PDF
Synthesis of the monooxoruthenium(V) complexes containing the aminopolycarboxylic acid ligands EDTA and PDTA and their reactivities in the oxidation of organic substrates. X-ray crystal structures of K[RuIII(EDTA-H)Cl].cntdot.2H2O and K[RuIII(PDTA-H)Cl].cntdot.0.5H2O
M. M. Taqui Khan, Debabrata Chatterjee, R. R. Merchant, P. Paul, S. H. R. Abdi, D. Srinivas, M. R. H. Siddiqui, M. A. Moiz, M. M. Bhadbhade, and K. Venkatasubramanian
pp 2711 - 2718; DOI:
10.1021/ic00039a010
PDF
Mononuclear-dinuclear equilibrium for the pyridine adducts of chromium(II) saccharinates
Nuria M. Alfaro, F. Albert Cotton, Lee M. Daniels, and Carlos A. Murillo
pp 2718 - 2723; DOI:
10.1021/ic00039a011
PDF
Compounds containing linked multiply-bonded dimetal units. 2. An antiferromagnetic compound containing infinite chains of Ru2(O2CR)4+ units linked by bridging phenazine molecules
F. Albert Cotton, Youngmee Kim, and Tong Ren
pp 2723 - 2726; DOI:
10.1021/ic00039a012
PDF
A pentavalent tungsten-sulfur W4S4 cuboidal cluster
Michael L. Sampson, John F. Richardson, and Mark E. Noble
pp 2726 - 2730; DOI:
10.1021/ic00039a013
PDF
Reactivity of complexes with weak metal-metal bonds. Reactions of Lewis acids with bis-.mu.-[bis(diphenylphosphino)methane]carbonylchlorogoldiridium(1+) hexafluorophosphate
Alan L. Balch and Vincent J. Catalano
pp 2730 - 2734; DOI:
10.1021/ic00039a014
PDF
Synthesis and structure of small-molecule cyclic phosphazenes bearing ortho-substituted aryloxy and phenoxy substituents
Harry R. Allcock, Alexa A. Dembek, Michael N. Mang, Geoffrey H. Riding, Masood Parvez, and Karyn B. Visscher
pp 2734 - 2739; DOI:
10.1021/ic00039a015
PDF
Preparation of novel palladium(I)-palladium(I) bonded complexes, Pd2(diiso)2X2 (diiso: dmb = 1,8-diisocyano-p-menthane, tmb = 2,5-dimethyl-2,5-diisocyanohexane) (X = Cl, Br), and their photoinduced oxidative addition reactivities toward chlorocarbons. Crystal and molecular structures of Pd2(dmb)2Cl4.cntdot.H2O, Pd2(tmb)2Cl4.cntdot.2CH3CN, and Pd2(dmb)2Br2Cl2
Daniel Perreault, Marc Drouin, Andre Michel, and Pierre D. Harvey
pp 2740 - 2746; DOI:
10.1021/ic00039a016
PDF
Coordination chemistry of a new tetratertiary phosphine ligand
M. R. Mason, C. M. Duff, L. L. Miller, R. A. Jacobson, and J. G. Verkade
pp 2746 - 2755; DOI:
10.1021/ic00039a017
PDF
Complexes of divalent lanthanides (ytterbium(II), europium(II), and samarium(II)) with decaborates
James P. White and Sheldon G. Shore
pp 2756 - 2761; DOI:
10.1021/ic00039a018
PDF
Electron-transfer chain catalysis in the electrochemical deligation of bis(arene)iron(II) dications. Application of pulse voltammetric techniques as a mechanistic tool
Z. J. Karpinski and J. K. Kochi
pp 2762 - 2767; DOI:
10.1021/ic00039a019
PDF
Supramolecular adducts between the hexacyanocobaltate(III) anion and poly(ethyleneimines): influence on the photoaquation efficiency of the complex
M. F. Manfrin, L. Setti, and L. Moggi
pp 2768 - 2771; DOI:
10.1021/ic00039a020
PDF
Activation-controlled outer-sphere oxidation of thiosulfate: reaction with bis(1,4,7-triazacyclononane)nickel(III)
Rajeshuni Sarala and David M. Stanbury
pp 2771 - 2777; DOI:
10.1021/ic00039a021
PDF
Ligand addition reactions and the electron-transfer properties of tin dichloride dihydrate and tin tetrachloride pentahydrate. Molecular structure of bis(ethyl cysteinato)tin(II)
J. E. Anderson, S. M. Sawtelle, J. S. Thompson, S. A. Kretchmar Nguyen, and J. Calabrese
pp 2778 - 2785; DOI:
10.1021/ic00039a022
PDF
Emitting-state potential energy surface and distortions calculated from the excitation spectrum of bis(hexafluoroacetylacetonato)platinum(II) in a molecular beam
Christian Reber and Jeffrey I. Zink
pp 2786 - 2790; DOI:
10.1021/ic00039a023
PDF
Theoretical studies of inorganic and organometallic reaction mechanisms. 5. Substitution reactions of 17- and 18-electron transition-metal hexacarbonyl complexes
Zhenyang Lin and Michael B. Hall
pp 2791 - 2797; DOI:
10.1021/ic00039a024
PDF
On Pearson's HSAB principle
Dipankar Datta
pp 2797 - 2800; DOI:
10.1021/ic00039a025
PDF
Rhenium(V) oxo complexes relevant to technetium renal imaging agents derived from mercaptoacetylglycylglycylaminobenzoic acid isomers. Structural and molecular mechanics studies
Lory Hansen, Renzo Cini, Andrew Taylor, and Luigi G. Marzilli
pp 2801 - 2808; DOI:
10.1021/ic00039a026
PDF
One- and two-photon spectroscopy of the hexafluoroplatinate(IV) ion
Cecelia Campochiaro, Donald S. McClure, and Howard H. Patterson
pp 2809 - 2813; DOI:
10.1021/ic00039a027
PDF
Optical absorption and luminescence spectra of rhodium(3+)-doped cesium sodium metal chloride Cs2NaMCl6 (M = yttrium, indium, scandium) single crystals
S. Catherine Weaver and Donald S. McClure
pp 2814 - 2820; DOI:
10.1021/ic00039a028
PDF
Synthesis, crystal structures, and coordination intercalation behavior of two copper phosphonates
Yiping Zhang and Abraham Clearfield
pp 2821 - 2826; DOI:
10.1021/ic00039a029
PDF
Protein surface recognition and covalent binding by chromium nitrilotriacetate complexes: elucidation using NMR and CD spectroscopies
Jeffrey R. Bocarsly and Jacqueline K. Barton
pp 2827 - 2834; DOI:
10.1021/ic00039a030
PDF
Electronic structure of tetracoordinate transition-metal complexes. 5. Comparative theoretical ab initio/Hartree-Fock-Slater and ultraviolet-photoelectron spectroscopic studies of building blocks for low-dimensional conductors. Dibenzo[b,i][1,4,8,11]tetraazacyclotetradecine complexes of nickel(II) and palladium(II)
Maurizio Casarin, Enrico Ciliberto, Santo Di Bella, Antonino Gulino, Ignazio Fragala, and Tobin J. Marks
pp 2835 - 2842; DOI:
10.1021/ic00039a031
PDF
Synthesis, crystal structure, magnetic susceptibility, and single-crystal EPR studies of bis(diazafluorenone)dichlorocopper(II): a novel Cu(NN)2X2 system with an unusual distortion
C. Balagopalakrishna, M. V. Rajasekharan, S. Bott, J. L. Atwood, and B. L. Ramakrishna
pp 2843 - 2846; DOI:
10.1021/ic00039a032
PDF
Synthesis and characterization of two novel oxo-persulfido complexes with a doubly bridging heptasulfide(2-) ligand and an "end-to-end" bridging hydrazine ligand: [Et4N]2[{MO(S2)2}2(.mu.2-S7)(.mu.2-NH2NH2)].CH3CN (M = molybdenum, tungsten)
Shaowu Du, Nianyong Zhu, Xintao Wu, and Jiaxi Lu
pp 2847 - 2853; DOI:
10.1021/ic00039a033
PDF
Spin crossover, dimerization, and structural dynamics of manganocenes probed by deuterium NHR spectroscopy
Frank H. Koehler and Bjoern Schlesinger
pp 2853 - 2859; DOI:
10.1021/ic00039a034
PDF
Optical study of the near-infrared emission and absorption in the strongly exchange-coupled dimer tricesium nonachlorodimolybdate(III)
Robert Stranger, Grainne Moran, Elmars Krausz, Lucjan Dubicki, Hans Guedel, and Naomi Furer
pp 2860 - 2864; DOI:
10.1021/ic00039a035
PDF
Carbon-13 and argon-17, NMR studies of the solution and equilibrium behavior of selected oxocyanorhenate(V) complexes
Andreas Roodt, Johann G. Leipoldt, Lothar Helm, and Andre E. Merbach
pp 2864 - 2868; DOI:
10.1021/ic00039a036
PDF
Rhenium(I) carbonyl dioxolene complexes: electrochemical and spectroelectrochemical (resonance Raman, UV-visible and IR) study of [Re(CO)3L(Diox)]z and [Re(CO)2(PPh3)2(Diox)]z (L = Co, PPh3, P-dppe, THF, Ph3PO, Me2Co, py; z = -1, 0, +1) redox series
Frantisek Hartl and Antonin Vlcek
pp 2869 - 2876; DOI:
10.1021/ic00039a037
PDF
A ferrochelatase transition-state model. Rapid incorporation of copper(II) into nonplanar dodecaphenylporphyrin
Jun Takeda, Toshie Ohya, and Mitsuo Sato
pp 2877 - 2880; DOI:
10.1021/ic00039a038
PDF
Kinetics of the reaction of copper(II) with cobalt(II) sepulchrate: catalysis by chloride ion and imidazole
M. J. Sisley and R. B. Jordan
pp 2880 - 2884; DOI:
10.1021/ic00039a039
PDF
Xenon-129 NMR spectroscopy of molybdenum carbonyls in Na-Y zeolite
Cathy L. Tway and Tom M. Apple
pp 2885 - 2888; DOI:
10.1021/ic00039a040
PDF
Synthesis of monosubstituted derivatives of closo-decahydrodecaborate(2-). X-ray crystal structures of [closo-2-B10H9CO]- and [closo-2-B10H9NCO]2-
Kenneth Shelly, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 2889 - 2892; DOI:
10.1021/ic00039a041
PDF
Reactions at metal-bound nitrogen atoms. Formation of molybdenum and tungsten phosphoraniminato complexes from silylimido complexes and synthesis of a nitride-bridged tungsten derivative
Joseph D. Lichtenhan, Joseph W. Ziller, and Nancy M. Doherty
pp 2893 - 2900; DOI:
10.1021/ic00039a042
PDF
Mixed rhodium-osmium carbonyl clusters. Synthesis of the anions [OsRh5(CO)16]- and [OsRh3(CO)12]- and crystal structures of their (.mu.-nitrido)bis(triphenylphosphorus)(1+) salts
Alessandro Fumagalli, Secondo Martinengo, Gianfranco Ciani, Massimo Moret, and Angelo Sironi
pp 2900 - 2906; DOI:
10.1021/ic00039a043
PDF
Ruthenatetraboranes: synthesis of [Ru(B3H8)(PPh3)}HB(pz)3}] and crystal structure of [RuCl(PPh3)2{HB(pz)3}] (pz = pyrazol-1-yl)
Nathaniel W. Alcock, Ian D. Burns, Kanwaljit S. Claire, and Anthony F. Hill
pp 2906 - 2908; DOI:
10.1021/ic00039a044
PDF
Importance of ion association in the substitution reactions of cobalt(III)-acido complexes. 8. Spontaneous isomerization of pentaammine(thiocyanato)cobalt(2+) in aqueous solution
David A. Buckingham, Charles R. Clark, and Gerrard F. Liddell
pp 2909 - 2914; DOI:
10.1021/ic00039a045
PDF
Structural and magnetic characterization of calcium copper formates, CaCu(HCOO)4 and Ca2Cu(HCOO)6: two new one-dimensional ferromagnetic bis(.mu.-oxo-ligand)-bridged chains
Maria J. Sanchis, Pedro Gomez-Romero, Jose Vicente Folgado, Fernando Sapina, Rafael Ibanez, Aurelio Beltran, Juana Garcia, and Daniel Beltran
pp 2915 - 2919; DOI:
10.1021/ic00039a046
PDF
Mono- and diprotonation of the [(.eta.5-C5H5)Ti(W5O18)]3- and [(.eta.5-C5Me5)Ti(W5O18)]3- anions
T. M. Che, V. W. Day, L. C. Francesconi, W. G. Klemperer, D. J. Main, A. Yagasaki, and O. M. Yaghi
pp 2920 - 2928; DOI:
10.1021/ic00039a047
PDF
Synthesis and substitution reactions of dinuclear molybdenum complexes containing Mo-Mo quadruple bonds and labile solvent ligands
Roger H. Cayton, Malcolm H. Chisholm, Elena F. Putilina, Kirsten Folting, John C. Huffman, and Kandasamy G. Moodley
pp 2928 - 2934; DOI:
10.1021/ic00039a048
PDF
Comparison of the crystal structures of tris heterocyclic ligand complexes of ruthenium(II)
D. Paul Rillema, Daniel S. Jones, Clifton Woods, and Henri A. Levy
pp 2935 - 2938; DOI:
10.1021/ic00039a049
PDF
Organometallic chemistry on the basic magnesium oxide surface: formation of [HIr4(CO)11]-, [Ir6(CO)15]2-, and [Ir8(CO)22]2-
Sibudjing Kawi and Bruce C. Gates
pp 2939 - 2947; DOI:
10.1021/ic00039a050
PDF
Steric control in the synthesis and stereochemistry of the asymmetric "head-to-head" isomer of rhodium binuclear [Rh2(.mu.-HTP5)2(.mu.-dppm)2](PF6)2 (HTP5 = 1,5-diisocyano-1,1,5-triphenylpentane; dppm = bis(diphenylphosphino)methane)
Charles A. Daws, Michael G. Hill, John P. Bullock, and Kent R. Mann
pp 2948 - 2955; DOI:
10.1021/ic00039a051
PDF
Oxamidato complexes. 5. Influence of the steric constraints on the complex formation between copper(II) and N,N'-(alkyl-substituted)oxamides. Synthesis and crystal structure of [Cu2(mapox)(N3)2]n (H2mapox = N,N'-bis([3-(methylamino)propyl]oxamide)
Francesc Lloret, Miguel Julve, Jose Antonio Real, Juan Faus, Rafael Ruiz, Miquel Mollar, Isabel Castro, and Claudette Bois
pp 2956 - 2961; DOI:
10.1021/ic00039a052
PDF
Photooxidation of matrix-isolated iron pentacarbonyl. 1. Peroxo- and oxoiron carbonyl reaction intermediates
Michael Fanfarillo, Helen E. Cribb, Anthony J. Downs, Tim M. Greene, and Matthew J. Almond
pp 2962 - 2973; DOI:
10.1021/ic00039a053
PDF
Photooxidation of matrix-isolated iron pentacarbonyl. 2. Binary iron oxide reaction products and the overall reaction mechanism
Michael Fanfarillo, Anthony J. Downs, Tim M. Greene, and Matthew J. Almond
pp 2973 - 2979; DOI:
10.1021/ic00039a054
PDF
Irreversible addition of arenediazonium ligands to a platinum-platinum bond. Solid-state structure of [Pt2Cl2(.mu.-Ph2PCH2PPh2)2(.mu.-N2-p-C6H4OCH3)]BF4
Francesco Neve, Mauro Ghedini, Giovanni De Munno, and Alessandra Crispini
pp 2979 - 2982; DOI:
10.1021/ic00039a055
PDF
A tridecanuclear ruthenium(II)-polypyridine supramolecular species: synthesis, absorption and luminescence properties and electrochemical oxidation
Sebastiano Campagna, Gianfranco Denti, Scolastica Serroni, Mauro Ciano, Alberto Juris, and Vincenzo Balzani
pp 2982 - 2984; DOI:
10.1021/ic00039a056
PDF
Complexes of zinc finger peptides with nickel(2+) and iron(2+)
Beth Allyn Krizek and Jeremy M. Berg
pp 2984 - 2986; DOI:
10.1021/ic00039a057
PDF
Reactions of tellurium halides with sulfur N,N'-bis(trimethylsilyl)diimide-preparation of the first fluorotellurium nitride
J. Muenzenberg, H. W. Roesky, S. Besser, R. Herbst-Irmer, and G. M. Sheldrick
pp 2986 - 2987; DOI:
10.1021/ic00039a058
PDF
A chloroalkane-silver complex with a monodentate RCl .fwdarw. Ag(I) interaction
Dawn M. Van Seggen, Oren P. Anderson, and Steven H. Strauss
pp 2987 - 2990; DOI:
10.1021/ic00039a059
PDF
Synergism in a transition metal cluster compound. Crystal and molecular structure of a polysilver cluster molecule with an unusual bridging sulfur atom, Ag11S(Et2dtc)9
Zhiying Huang, Xinjian Lei, Maochun Hong, and Hanqin Liu
pp 2990 - 2991; DOI:
10.1021/ic00039a060
PDF
Discrete mononuclear nickel(II) selenolate complexes: syntheses, structures, and properties of K2[Ni(SeCH2CH2Se)2].cntdot.2C2H5OH and (Me4N)2[Ni(SeCH2CH2Se)2].cntdot.1.2H2O
Christine A. Marganian, Narayan Baidya, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 2992 - 2994; DOI:
10.1021/ic00039a061
PDF

Issue 14


Activation and cleavage of the carbon-sulfur bond in niobium tert-butanethiolato complexes. Syntheses and structural characterizations of the tetrahedral and trigonal bipyramidal [Ph4P][NbV(S)2(tert-BuS)2] and [Et4N][NbV(S)(tert-BuS)4] complexes
D. Coucouvanis, Saleem Al-Ahmad, C. G. Kim, and Sang Man Koo
pp 2996 - 2998; DOI:
10.1021/ic00040a001
PDF
Nickel(II) complexes with the [NiNxSey] chromophore in different coordination geometries: search for a model of the active site of [FeNiSe] hydrogenases
Narayan Baidya, Bruce C. Noll, Marilyn M. Olmstead, and Pradip K. Mascharak
pp 2999 - 3000; DOI:
10.1021/ic00040a002
PDF
New thermally stable hydroperoxo- and peroxo-copper complexes
Mohammad Mahroof-Tahir, Narasappa Narasimha Murthy, Kenneth D. Karlin, Ninian J. Blackburn, Shahid N. Shaikh, and Jon Zubieta
pp 3001 - 3003; DOI:
10.1021/ic00040a003
PDF
Synthesis of polypyridyl complexes of ruthenium(II) containing three different bidentate ligands
Geoffrey F. Strouse, Peter A. Anderson, Jon R. Schoonover, Thomas J. Meyer, and F. Richard Keene
pp 3004 - 3006; DOI:
10.1021/ic00040a004
PDF
Theoretical study of bonding and electrical conductivity in compounds with the NbAs2 structure
Pere Alemany and Santiago Alvarez
pp 3007 - 3010; DOI:
10.1021/ic00040a005
PDF
Kinetics of 1:1 thiocyanate (and chloride) substitution at molybdenum on the cuboidal clusters [Mo4S4(H2O)12]4+ and [Mo4S4(H2O)12]5+ in aqueous solution
Yue Jin Li, Mohamed Nasreldin, M. Humanes, and A. Geoffrey Sykes
pp 3011 - 3017; DOI:
10.1021/ic00040a006
PDF
Solvent effect on the isotopomerization of (carbonyl-13C)carbonyliodo(methyl)trimethylphosphine)iron: implication on the mechanism of carbon monoxide insertion
Gianfranco Bellachioma, Giuseppe Cardaci, Alceo Macchioni, and Gustavo Reichenbach
pp 3018 - 3022; DOI:
10.1021/ic00040a007
PDF
Ammine ligand exchange in tetraammineplatinum(II) in aqueous solution
Birthe Broennum, H. Saaby Johansen, and L. H. Skibsted
pp 3023 - 3025; DOI:
10.1021/ic00040a008
PDF
Water-soluble tris(hydroxymethyl)phosphine complexes with nickel, palladium, and platinum. Crystal structure of [Pd{P(CH2OH)3}4].cntdot.CH3
James W. Ellis, Karl N. Harrison, Peter A. T. Hoye, A. Guy Orpen, Paul G. Pringle, and Martin B. Smith
pp 3026 - 3033; DOI:
10.1021/ic00040a009
PDF
Synthesis, properties, and the ring-ring transformation reactions of cyclic siloxanes incorporating skeletal boron atoms: x-ray crystal structures of the strained boracyclotrisiloxane (PhBO)(Ph2SiO)2 and the boracyclotetrasiloxane (PhBO)(Ph2SiO)3
Daniel A. Foucher, Alan J. Lough, and Ian Manners
pp 3034 - 3043; DOI:
10.1021/ic00040a010
PDF
Complexation of organotin halides with ambidentate, S, N, and O donor ligands
Gerimario F. De Sousa, Carlos A. L. Filgueiras, Marcetta Y. Darensbourg, and Joseph H. Reibenspies
pp 3044 - 3049; DOI:
10.1021/ic00040a011
PDF
Hydrothermal synthesis of a layered zinc molybdenum phosphate with octahedral and tetrahedral zinc: structure of (TMA)2(H3O)2[Zn3Mo12O30(HPO4)2(H2PO4)6].cntdot.11.5H2O
Linda A. Mundi and Robert C. Haushalter
pp 3050 - 3053; DOI:
10.1021/ic00040a012
PDF
Reorientational motions of permethylated cyclopentadienyl rings in polycrystalline organometallic compounds
Silvio Aime, Dario Braga, Lucia Cordero, Roberto Gobetto, Fabrizia Grepioni, Sandra Righi, and Silvana Sostero
pp 3054 - 3059; DOI:
10.1021/ic00040a013
PDF
An ab initio/IGLO/NMR study of the nido-carborane C2B6H10
Joseph W. Bausch, G. K. Surya Prakash, Michael Buehl, Paul v. R. Schleyer, and Robert E. Williams
pp 3060 - 3062; DOI:
10.1021/ic00040a014
PDF
Nido-n (n = 8, 10, 12) borane and carborane clusters and second moment scaling
Stephen Lee
pp 3063 - 3066; DOI:
10.1021/ic00040a015
PDF
Dirhenium polyhydrides that contain bidentate chelating and/or bridging phosphine ligands
Karen E. Meyer, Dawn R. Root, Phillip E. Fanwick, and Richard A. Walton
pp 3067 - 3076; DOI:
10.1021/ic00040a016
PDF
Aspects of the solution chemistry of trans-diammineplatinum(II) complexes
Trevor G. Appleton, Alicia J. Bailey, Kevin J. Barnham, and John R. Hall
pp 3077 - 3082; DOI:
10.1021/ic00040a017
PDF
Synthesis by ligand exchange, structural characterization, and aqueous chemistry of ortho-palladated oximes
A. D. Ryabov, G. M. Kazankov, A. K. Yatsimirskii, L. G. Kuz'mina, O. Yu. Burtseva, N. V. Dvortsova, and V. A. Polyakov
pp 3083 - 3090; DOI:
10.1021/ic00040a018
PDF
Stereochemical alterations of 2E chromium(III) excited-state behavior in dicyanotetraazacyclotetradecane complexes. Ground-state x-ray crystal structures, photophysical behavior, and molecular mechanics simulations of stereochemical effects
Ronald B. Lessard, Mary Jane Heeg, Tione Buranda, Marc W. Perkovic, Carolyn L. Schwarz, Rudong Yang, and John F. Endicott
pp 3091 - 3103; DOI:
10.1021/ic00040a019
PDF
Synthesis and reactivity of a new microporous Lewis base
Guy L. Rosenthal and James Caruso
pp 3104 - 3106; DOI:
10.1021/ic00040a020
PDF
Bond reactivities, acidities, and basicities within AMo3X3 phases (A = Li, Na, K, In; X = Se, Te)
Richard Dronskowski and Roald Hoffmann
pp 3107 - 3113; DOI:
10.1021/ic00040a021
PDF
Gaseous borate and polyborate anions
Marina Attina, Fulvio Cacace, Giorgio Occhiucci, and Andreina Ricci
pp 3114 - 3117; DOI:
10.1021/ic00040a022
PDF
Solid-state photochemistry and structure of trans-diazidobis(triethylphosphine)nickel: photodeposition of nickel
A. Becalska, R. J. Batchelor, F. W. B. Einstein, Ross H. Hill, and B. J. Palmer
pp 3118 - 3123; DOI:
10.1021/ic00040a023
PDF
Preparation and structure of ruthenium tetrafluoride and a structural comparison with ruthenium trifluoride and ruthenium pentafluoride
William J. Casteel, Angus P. Wilkinson, Horst Borrmann, Robert E. Serfass, and Neil Bartlett
pp 3124 - 3131; DOI:
10.1021/ic00040a024
PDF
Lewis-base-catalyzed diimine-ligand-substitution reactions at copper(I)
Urs M. Frei and Gerhard Geier
pp 3132 - 3137; DOI:
10.1021/ic00040a025
PDF
Angle-selected nitrogen-14-ENDOR study of copper(II) complexes with distorted N2S2 and N2O2 coordination structures
Ryo Miyamoto, Yasunori Ohba, and Masamoto Iwaizumi
pp 3138 - 3149; DOI:
10.1021/ic00040a026
PDF
Unusually high redox potentials of two copper(II) compounds of 1,8-bis(3,5-dimethyl-1-pyrazolyl)-3,6-dithiaoctane
Willem G. Haanstra, M. Fernanda Cabral, Joao de O. Cabral, Willem L. Driessen, and Jan Reedijk
pp 3150 - 3151; DOI:
10.1021/ic00040a027
PDF
Electronic relaxation of the titanium(III) hexaaqua complex detected by solvent water proton-NMRD spectroscopy
Ivano Bertini, Claudio Luchinat, and Zhicheng Xia
pp 3152 - 3154; DOI:
10.1021/ic00040a028
PDF
Synthesis and structure of osmium-tungsten carbonyl tert-butyl isocyanide (OC)4(tert-BuNC)OsOs(CO)3(CNBu-tert)W(CO)5, a second example of a compound with dative metal-metal bonds in tandem
Raymond J. Batchelor, Frederick W. B. Einstein, Roland K. Pomeroy, and John A. Shipley
pp 3155 - 3157; DOI:
10.1021/ic00040a029
PDF
Convenient room-temperature synthesis of the ruthenium phosphinidene-capped clusters [(Ph3P)2N][(.mu.-H)Ru3(CO)9(.mu.3-PR)] (R = Ph, tert-Bu)
Steven P. Rowley, Peter S. White, and Cynthia K. Schauer
pp 3158 - 3161; DOI:
10.1021/ic00040a030
PDF
Isolation and characterization of a new polycyclic system from the reaction of (dimethylamino)diethylborane with 2,2'-biimidazole
Kurt Niedenzu, Haibin Deng, David Knoeppel, Jeanette Krause, and Sheldon G. Shore
pp 3162 - 3164; DOI:
10.1021/ic00040a031
PDF
The first discrete structure for the heptaiodide ion
Rinaldo Poli, John C. Gordon, Raj K. Khanna, and Phillip E. Fanwick
pp 3165 - 3167; DOI:
10.1021/ic00040a032
PDF
Isolation of stable tetraalkylammonium tetraalkylaurate(III) complexes
Sanshiro Komiya, Shinichiro Ochiai, and Yasushi Ishizaki
pp 3168 - 3169; DOI:
10.1021/ic00040a033
PDF
Electrochemical variational study of donor/acceptor orbital mixing and electronic coupling in cyanide-bridged mixed-valence complexes
Yuhua Dong and Joseph T. Hupp
pp 3170 - 3172; DOI:
10.1021/ic00040a034
PDF
Infrared spectra of phosphorus sulfides, P4S10, P4S9, and P4S7 in solid argon
Lester Andrews, Craig Thompson, and Michel C. Demarcq
pp 3173 - 3175; DOI:
10.1021/ic00040a035
PDF
Molecular interactions, band structure, and BEDT-TTF oxidation states in the molecular conductor (BEDT-TTF)3[V(dmit)3]2
James D. Martin, Enric Canadell, and Patrick Batail
pp 3176 - 3178; DOI:
10.1021/ic00040a036
PDF
Molecular and electronic structure of the electron-transfer probe analog [trans-(NH3)4Ru(imidazole)(isonicotinamide)](CF3CO2)3.cntdot.2-propanol
James F. Wishart, Xiaohua Zhang, Stephan S. Isied, Joseph A. Potenza, and Harvey J. Schugar
pp 3179 - 3181; DOI:
10.1021/ic00040a037
PDF
Structural determination of chlorobis(triisopropylphosphine)rhodium compounds in the +2 and +3 oxidative states. [Erratum to document cited in CA116(14):140584g]
Richard L. Harlow, David L. Thorn, R. Thomas Baker, and Nancy L. Jones
pp 3182 - 3182; DOI:
10.1021/ic00040a038
PDF
Editorial - Important Changes in Journal Policies

pp 2995 - 2995; DOI:
10.1021/ic00040a600
PDF

Issue 15


John C. Bailar, Jr. 1904-1991 in memoriam
Gregory S. Girolami
pp 3183 - 3184; DOI:
10.1021/ic00041a001
PDF
Assignment of electronic transitions in mixed-valence complexes by resonance Raman spectroscopy
Jon R. Schoonover, Cliff J. Timpson, Thomas J. Meyer, and Carlo A. Bignozzi
pp 3185 - 3186; DOI:
10.1021/ic00041a002
PDF
Synthesis and structure of a high nuclearity oxomolybdenum(V) complex, [(C5Me5RhIII)8(MoV12O36)(MoVIO4)]2+
H. K. Chae, W. G. Klemperer, D. E. Paez-Loyo, V. W. Day, and T. A. Eberspacher
pp 3187 - 3189; DOI:
10.1021/ic00041a003
PDF
Spectroscopic assessment of the degree of .pi.-stabilization of unsaturation in ruthenium complex, RuH(X)CO(P-tert-Bu2Me)2
Jason T. Poulton, Kirsten Folting, William E. Streib, and Kenneth G. Caulton
pp 3190 - 3191; DOI:
10.1021/ic00041a004
PDF
Synthesis and preliminary photophysical studies of intramolecular electron transfer in crown-linked donor- (chromophore-) acceptor complexes
Dong I. Yoon, Christine A. Berg-Brennan, Hong Lu, and Joseph T. Hupp
pp 3192 - 3194; DOI:
10.1021/ic00041a005
PDF
Synthesis and structure of fac-tris[(8-quinolyl)dimethylsilyl]rhodium(III) and -iridium(III)
Peter I. Djurovich, Adam L. Safir, Nancy L. Keder, and Richard J. Watts
pp 3195 - 3196; DOI:
10.1021/ic00041a006
PDF
Syntheses and structural characterizations of hypho- and arachno-metalladithiaborane clusters
Khaled Mazighi, Patrick J. Carroll, and Larry G. Sneddon
pp 3197 - 3204; DOI:
10.1021/ic00041a007
PDF
Dinuclear barium alkoxides and siloxides displaying variable coordination numbers and asymmetric dispositions of ligands
Simon R. Drake, William E. Streib, Kirsten Folting, Malcolm H. Chisholm, and Kenneth G. Caulton
pp 3205 - 3210; DOI:
10.1021/ic00041a008
PDF
Products of the redox reactions of cis-Re2(O2CCH3)2Cl4L2 (L = H2O, py) with bis(dimethylphosphino)methane and the isolation and structural characterization of a grossly unsymmetrical mixed-valent dirhenium complex of composition bis[bis(dimethylphosphino)methane]dichlorotrioxodirhenium
Irene Ara, Phillip E. Fanwick, and Richard A. Walton
pp 3211 - 3215; DOI:
10.1021/ic00041a009
PDF
Low-valent iron porphyrins. NMR evidence for .pi.-anion-radical character in two-electron-reduced iron(III) meso- or .beta.-pyrrole-substituted porphyrins
Kazuya Yamaguchi and Isao Morishima
pp 3216 - 3222; DOI:
10.1021/ic00041a010
PDF
Identification of the cyanide stretching frequency in the cyano derivative of copper/zinc-superoxide dismutase by IR and Raman spectroscopy
Jane Han, Ninian J. Blackburn, and Thomas M. Loehr
pp 3223 - 3229; DOI:
10.1021/ic00041a011
PDF
Excited-state properties of platinum(II) complexes containing biphenyl as a ligand: complexes of the type [(bph)PtL2], where L = monodentate or saturated bidentate ligands
Charles B. Blanton, Zakir Murtaza, Randy J. Shaver, and D. Paul Rillema
pp 3230 - 3235; DOI:
10.1021/ic00041a012
PDF
Luminescent mononuclear gold(I) phosphines
Christopher King, Mohammed N. I. Khan, Richard J. Staples, and John P. Fackler
pp 3236 - 3238; DOI:
10.1021/ic00041a013
PDF
Systematic design of chemical oscillators. 83. Equilibria and kinetics of the fast interaction between copper(II) and thiosulfate ions in aqueous solution
Gyula Rabai and Irving R. Epstein
pp 3239 - 3242; DOI:
10.1021/ic00041a014
PDF
Equilibria and reaction mechanism of the complexation of methylboronic acid with polyols
Richard Pizer and Cherryl Tihal
pp 3243 - 3247; DOI:
10.1021/ic00041a015
PDF
A cis-folded macrocyclic nickel(II) complex: molecular structure and thermal reaction of cis-diaqua(1,4,7,11-tetraazacyclotetradecane)nickel(II) chloride
Yasuhiro Satake, Yoshinori Ihara, Hitoshi Senda, Masatatsu Suzuki, and Akira Uehara
pp 3248 - 3251; DOI:
10.1021/ic00041a016
PDF
Zero field splitting and exchange interactions in bis(cyclopentadienyl)titanium(III) dinuclear compounds with short metal-metal distances: synthesis, x-ray structure, and EPR spectroscopy of methoxo- and ethoxo-bridged dimers
Edmond Samuel, John Frank Harrod, Didier Gourier, Yves Dromzee, Francis Robert, and Yves Jeannin
pp 3252 - 3259; DOI:
10.1021/ic00041a017
PDF
Crystal structure of magnesium sesquicarbide
Helmer Fjellvaag and Pavel Karen
pp 3260 - 3263; DOI:
10.1021/ic00041a018
PDF
Transition metal complexes with thiosemicarbazide-based ligands. 14. Iron(IV) complexes with 2,4-pentanedione bis(S-alkylisothiosemicarbazone). Crystal and molecular structure of iodo{2,4-pentanedione bis(S-ethylisothiosemicarbazonato)(3-)}iron(IV)
N. V. Gerbeleu, Yu. A. Simonov, V. B. Arion, V. M. Leovac, K. I. Turta, K. M. Indrichan, D. I. Gradinaru, V. E. Zavodnik, and T. I. Malinovskii
pp 3264 - 3268; DOI:
10.1021/ic00041a019
PDF
Novel and stable metal-metal-bonded diruthenium(I) complexes containing TCNX0/.bul.- in both the inner and the outer coordination sphere (TCNX = TCNE, TCNQ). A combined EPR/ENDOR-, UV/visible/near-IR-, and IR-spectroscopic and electrochemical investigation
Sharon E. Bell, John S. Field, Raymond J. Haines, Michael Moscherosch, Walter Matheis, and Wolfgang Kaim
pp 3269 - 3276; DOI:
10.1021/ic00041a020
PDF
Photoluminescence of germanium(II), tin(II), and lead(II) chloride complexes in solution
Hans Nikol, Alexander Becht, and Arnd Vogler
pp 3277 - 3279; DOI:
10.1021/ic00041a021
PDF
Electrocatalytic reduction of nitrite and nitrosyl by iron(III) protoporphyrin IX dimethyl ester immobilized in an electropolymerized film
Janet N. Younathan, Karen S. Wood, and Thomas J. Meyer
pp 3280 - 3285; DOI:
10.1021/ic00041a022
PDF
Thiacyclophanes containing the -S(CH2)3S(CH2)3S- linkage. Synthesis and structures of 2,6,10-trithia[11]-o-cyclophane (TT[ll]OC), 2,6,10-trithia[11]-m-cyclophane (TT[11]MC), and the palladation product [Pd(TT[11]MC)][BF4]
Garth R. Giesbrecht, Garry S. Hanan, James E. Kickham, and Stephen J. Loeb
pp 3286 - 3291; DOI:
10.1021/ic00041a023
PDF
Synthesis and characterization of stable tin porphyrins with a carbon .sigma.-bonded axial ligand
K. M. Kadish, D. Dubois, S. Koeller, J. M. Barbe, and R. Guilard
pp 3292 - 3294; DOI:
10.1021/ic00041a024
PDF
Design of a homonuclear ferromagnetic chain: structures and magnetic properties of oxalato-bridged copper(II) complexes with one-dimensional structures
Hiroki Oshio and Umpei Nagashima
pp 3295 - 3301; DOI:
10.1021/ic00041a025
PDF
Tungsten(VI) fluoride dimethylhydrazide complexes: .eta.2 and .eta.1 isomerism
S. G. Sakharov, S. A. Zarelua, Yu. V. Kokunov, and Yu. A. Buslaev
pp 3302 - 3305; DOI:
10.1021/ic00041a026
PDF
Multiple structural variants of LnCuI(.mu.-X)2CuILn (n = 1, 2). Influence of halide on a "soft" potential energy surface
Grigorii L. Soloveichik, Odile Eisenstein, Jason T. Poulton, William E. Streib, John C. Huffman, and Kenneth G. Caulton
pp 3306 - 3312; DOI:
10.1021/ic00041a027
PDF
Ruthenium(II) macrocyclic complexes with inert chloride and labile azines. Synthesis and properties of the macrocyclic complexes trans-chloro(azine)(1,4,8,11-tetraazacyclotetradecane)ruthenium(II), trans-[RuCl(cyclam)L]+
Roberto Santana da Silva and Elia Tfouni
pp 3313 - 3316; DOI:
10.1021/ic00041a028
PDF
Electronic structure and bonding energetics of a complex undergoing intramolecular disproportionation: Ab initio two-configuration SCF and CI investigation on dichlorobis(diphosphinomethane)trioxodirhenium
Miquel Costas, Thierry Leininger, Gwang Hi Jeung, and Marc Benard
pp 3317 - 3321; DOI:
10.1021/ic00041a029
PDF
Thermochromic effects in an asymmetric mixed-valence system
Yuhua Dong and Joseph T. Hupp
pp 3322 - 3324; DOI:
10.1021/ic00041a030
PDF
Synthesis and characterization of tetracarbonylmolybdenum(0) complexes bound to the novel bridging ligand dipyrido[2,3-a:2',3'-h]phenazine (DPOP)
Ronald R. Ruminski, Cynthia DeGroff, and Sandra J. Smith
pp 3325 - 3328; DOI:
10.1021/ic00041a031
PDF
Sulfur(IV) compounds as ligands. Part 15. Ligand-centered oxidations of organometallic thiolates using dimethyldioxirane
Wolfdieter A. Schenk, Juergen Frisch, Waldemar Adam, and Frank Prechtl
pp 3329 - 3331; DOI:
10.1021/ic00041a032
PDF
Synthesis, characterization, and block copolymerization of bifunctional zirconium coordination complex: bis[2,2'-[[4-[[[(3-isocyanato-4-methylphenyl)amino]carbonyl]amino]-1,2-phenylene]bis(nitrilomethylidyne)]bis[phenolato](2-)(N,N',O,O')]zirconium(IV)
Wenyan Tong and Ronald D. Archer
pp 3332 - 3335; DOI:
10.1021/ic00041a033
PDF
Cluster chemistry. 72. An octanuclear heterometallic iron ruthenium dicarbido cluster with an unusual geometry: x-ray structure of Fe3Ru5(.mu.6-C)(.mu.5-C)(.mu.-PPh2)2(CO)17
Chris J. Adams, Michael I. Bruce, Brian W. Skelton, and Allan H. White
pp 3336 - 3338; DOI:
10.1021/ic00041a034
PDF

Issue 16


11-Vertex polyhedral rhodathiacarbaborane chemistry. Part 21. Synthesis and characterization of nido-structured [8,8-(PPh3)2-8-H-8,7,9-RhCSB8H10] and closo-structured [1,1-(PPh3)2-1,2,3-RhCSB8H9]
Karl Nestor, John D. Kennedy, Mark Thornton-Pett, Josef Holub, and Bohumil Stibr
pp 3339 - 3341; DOI:
10.1021/ic00042a001
PDF
Synthesis and molecular structures of diferrous complexes containing a bis(hydroxo) or a hydroxo carboxylato bridge
Nobumasa Kitajima, Nobuchika Tamura, Masako Tanaka, and Yoshihiko Morooka
pp 3342 - 3343; DOI:
10.1021/ic00042a002
PDF
Influence of a cis hydride on a coordinated molecular hydrogen ligand cis hydride, Ab initio calculations
Jean Frederic Riehl, Michel Pelissier, and Odile Eisenstein
pp 3344 - 3345; DOI:
10.1021/ic00042a003
PDF
Carbon-13-carbon-13 double bond isotope effect for Tc and consequences regarding the superconducting pairing mechanism in .kappa.-(ET)2X superconductors
K. Douglas Carlson, Aravinda M. Kini, Richard A. Klemm, H. Hau Wang, Jack M. Williams, Urs Geiser, S. Kalyan Kumar, John R. Ferraro, Keith R. Lykke, and et al.
pp 3346 - 3348; DOI:
10.1021/ic00042a004
PDF
Formation, x-ray structure, and deprotonation of an S,S'-methylene-bridged P2N4S2 ring
Tristram Chivers, Martin Cowie, Mark Edwards, and Robert W. Hilts
pp 3349 - 3350; DOI:
10.1021/ic00042a005
PDF
Methanol bonding to and electron-transfer reactivity of chloro(tetraphenylporphinato)manganese(III)
Xi Hai Mu and Franklin A. Schultz
pp 3351 - 3357; DOI:
10.1021/ic00042a006
PDF
Electron transfer. 113. Reduction of bound superoxide with thiols. Catalysis by copper(II)
S. K. Ghosh, S. K. Saha, M. C. Ghosh, R. N. Bose, J. W. Reed, and E. S. Gould
pp 3358 - 3362; DOI:
10.1021/ic00042a007
PDF
Silver binding to rabbit liver zinc metallothionein and zinc .alpha. and .beta. fragments. Formation of silver metallothionein with silver(I):protein ratios of 6, 12, and 18 observed using circular dichroism spectroscopy
Andrzej J. Zelazowski and Martin J. Stillman
pp 3363 - 3370; DOI:
10.1021/ic00042a008
PDF
Synthesis and photochemical properties of aluminum, gallium, silicon, and tin naphthalocyanines
William E. Ford, Michael A. J. Rodgers, Lee A. Schechtman, James R. Sounik, Boris D. Rihter, and Malcolm E. Kenney
pp 3371 - 3377; DOI:
10.1021/ic00042a009
PDF
Imido-gold clusters: synthesis and magnetic resonance spectroscopy of "gilded" diamines
Andreas Grohmann and Hubert Schmidbaur
pp 3378 - 3380; DOI:
10.1021/ic00042a010
PDF
FxXe(OTeF5)3-x+, O:XeFx(OTeF5)3-x+ (x = 0-2), and O2XeOTeF5+ cations: their preparation and characterization in solution by xenon-129 and fluorine-19 NMR spectroscopy
Robert G. Syvret, Kenneth M. Mitchell, Jeremy C. P. Sanders, and Gary J. Schrobilgen
pp 3381 - 3385; DOI:
10.1021/ic00042a011
PDF
A phosphorus-31 solid-state nuclear magnetic resonance study of thiaphospholium cations
Ronald D. Curtis, Bruce W. Royan, Roderick E. Wasylishen, Michael D. Lumsden, and Neil Burford
pp 3386 - 3390; DOI:
10.1021/ic00042a012
PDF
Pentacoordinated molecules. 93. Conformational variation of sulfur-bridged eight-membered rings in four-, five-, and six-coordinated oxygen-ligated phosphorus compounds
T. K. Prakasha, Roberta O. Day, and Robert R. Holmes
pp 3391 - 3397; DOI:
10.1021/ic00042a013
PDF
Complexation of alkali metal ions by the cryptand 4,7,13,16-tetraoxa-1,10-diazabicyclo[8.8.5]tricosane, C22C5. A structural and equilibrium study
Philip Clarke, Jacqueline M. Gulbis, Stephen F. Lincoln, and Edward R. T. Tiekink
pp 3398 - 3404; DOI:
10.1021/ic00042a014
PDF
Osmium(IV) complexes with 2,3-diamino-2,3-dimethylbutane (tmen): syntheses, properties, and structures
Ayyub Patel, Andreas Ludi, Hans Beat Buergi, Andrea Raselli, and Peter Bigler
pp 3405 - 3410; DOI:
10.1021/ic00042a015
PDF
Relativistic effects in gold chemistry. 4. Gold(III) and gold(V) compounds
Peter Schwerdtfeger, Peter D. W. Boyd, Stephane Brienne, and Anthony K. Burrell
pp 3411 - 3422; DOI:
10.1021/ic00042a016
PDF
Characterization of the equilibrium axial(trifluoromethyl)tetrafluorophosphorane .dblarw. equatorial(trifluoromethyl)tetrafluorophosphorus by matrix isolation FTIR spectroscopy
O. Loesking, H. Willner, H. Oberhammer, J. Grobe, and D. Le Van
pp 3423 - 3427; DOI:
10.1021/ic00042a017
PDF
Anionic Group 6 metal carbonyl oxalate complexes. X-ray structures of [Et4N]2[W(CO)4C2O4] and [PPN]2[W2(CO)8C2O4].cntdot.1/2(CH3CH2)2O
Donald J. Darensbourg, Jennifer A. Chojnacki, and Joseph H. Reibenspies
pp 3428 - 3433; DOI:
10.1021/ic00042a018
PDF
Preparation and structure studies of monomeric and dimeric [bis(diphenylphosphino)pentane]tricarbonyliron(0)
Ling Kang Liu, Lung Shiang Luh, and Han Mou Gau
pp 3434 - 3437; DOI:
10.1021/ic00042a019
PDF
Synthesis and electronic properties of triply bonded hexakis(fluoroalkoxy)dimolybdenum complexes. Structure of Mo2[OCMe(CF3)2]6 and investigation of the nature of the frontier orbitals in triply bonded M2X6 compounds
Thomas M. Gilbert, Arden M. Landes, and Robin D. Rogers
pp 3438 - 3444; DOI:
10.1021/ic00042a020
PDF
Cluster synthesis. 39. New platinum-ruthenium carbonyl cluster complexes with bridging hydride ligands. Synthesis and structural characterizations of Ru4Pt(CO)13(COD)(.mu.-H)2, Ru3Pt(CO)9(.mu.-CO)(COD)(.mu.-H)2, Ru4Pt2(CO)11(COD)2(.mu.3-H)2, and Ru5Pt5(CO)18(COD)2(.mu.-H)2 (COD = cycloocta-1,5-diene)
Richard D. Adams, Zhaoyang Li, Jau Ching Lii, and Wengan Wu
pp 3445 - 3450; DOI:
10.1021/ic00042a021
PDF
Trimethylsilyl halide adducts of dinuclear phosphine-bridged palladium halide complexes: synthesis, spectroscopy, and reactions of Pd2X2(dppm)2.cntdot.Me3SiX' (X, X' = Cl, Br, I)
Rein U. Kirss
pp 3451 - 3458; DOI:
10.1021/ic00042a022
PDF
Reactions of bis(nitro)[.alpha.,.alpha.,.alpha.,.alpha.-meso-tetrakis(o-pivalamidophenyl)porphinato]iron(III) with 2,3,5,6-tetrafluorothiophenol and 2,3,5,6-tetrafluorothiophenolate. EPR and Moessbauer spectra and molecular structures
Habib Nasri, Kenneth J. Haller, Yaning Wang, Huynh Boi Hanh, and W. Robert Scheidt
pp 3459 - 3467; DOI:
10.1021/ic00042a023
PDF
Generation of singlet oxygen from hydrogen peroxide disproportionation catalyzed by molybdate ions
K. Boehme and H. D. Brauer
pp 3468 - 3471; DOI:
10.1021/ic00042a024
PDF
Singlet molecular oxygen generation from the decomposition of sodium peroxotungstate and sodium peroxomolybdate
Q. J. Niu and C. S. Foote
pp 3472 - 3476; DOI:
10.1021/ic00042a025
PDF
Crystal structure of (methyl 2-(methylamino)-1-cyclopentene-1-dithiocarboxylato-.kappa.N,.kappa.S)-carbonyl(triphenylphosphine)rhodium(I) and kinetics of iodomethane oxidative addition
Gideon J. J. Steyn, Andreas Roodt, and Johann G. Leipoldt
pp 3477 - 3481; DOI:
10.1021/ic00042a026
PDF
Octahedral metal carbonyls. 77. Kinetics of chelate ring closure via olefin-tungsten bond formation in chlorobenzene solvates of tungsten carbonyl intermediates
Shulin Zhang, I Hsiung Wang, Paul H. Wermer, Charles B. Dobson, and Gerard R. Dobson
pp 3482 - 3488; DOI:
10.1021/ic00042a027
PDF
Synthesis and x-ray structure analysis of [(.eta.5-C5Me5)TaCl2]2(.mu.-O)(.mu.-OH)2
Daekeun Kwon, M. David Curtis, Arnold L. Rheingold, and Brian S. Haggerty
pp 3489 - 3490; DOI:
10.1021/ic00042a028
PDF
Carbon-13 NMR study and observation of restricted phenyl rotation in the cobalt alkyne complex Co2(CO)6(.mu.-PhC.tplbond.CH)
P. Yuan, M. J. Don, M. G. Richmond, and M. Schwartz
pp 3491 - 3492; DOI:
10.1021/ic00042a029
PDF
Reaction of a stable phosphinocarbene with germane- and stannanediyls: evidence for C-phosphinogerma and C-phosphinostannaethene to C-germyl- and C-stannylphosphaalkene rearrangements
V. D. Romanenko, A. O. Gudima, A. N. Chernega, and Guy Bertrand
pp 3493 - 3494; DOI:
10.1021/ic00042a030
PDF

Issue 17


Inert cobalt complexes as mechanistic probes of the biochemistry of magnesium cofactors. Application to topoisomerase I
Soodan Kim and J. A. Cowan
pp 3495 - 3496; DOI:
10.1021/ic00043a001
PDF
Preparations and structures of a zinc(II) dimer and zinc(II)/nickel(II) pentanuclear derivatives of N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane: [(BME-DACO)Zn]2 and {[(BME-DACO)Ni]3[ZnCl]2}{BF4}2
Thawatchai Tuntulani, Joseph H. Reibenspies, Patrick J. Farmer, and Marcetta Y. Darensbourg
pp 3497 - 3499; DOI:
10.1021/ic00043a002
PDF
Synthesis and characterization of new water soluble tertiary phosphines having terminally substituted alkylene sulfonate or alkylene phosphonate chains
Sanjoy Ganguly, Joel T. Mague, and D. Max Roundhill
pp 3500 - 3501; DOI:
10.1021/ic00043a003
PDF
Dinuclear manganese(II) complexes with water and carboxylate bridges
Shi Bao Yu, Stephen J. Lippard, Itzhak Shweky, and Avi Bino
pp 3502 - 3504; DOI:
10.1021/ic00043a004
PDF
Effect of transition metal coordination on the photophysical properties of fullerene, C60. Triplet formation and lifetime in (.eta.5-C9H7)Ir(CO)(.eta.2-C60)
Yong Zhu, Robert S. Koefod, C. Devadoss, John R. Shapley, and Gary B. Schuster
pp 3505 - 3506; DOI:
10.1021/ic00043a005
PDF
Kinetic, equilibrium, and ion-pairing studies on seven-coordinate molybdenum(II) and tungsten(II) isocyanide complexes in acetonitrile
Alan F. Lindmark
pp 3507 - 3513; DOI:
10.1021/ic00043a006
PDF
Chain lengths in the decomposition of peroxomonosulfate catalyzed by cobalt and vanadium. Rate law for catalysis by vanadium
Zuomin Zhang and John O. Edwards
pp 3514 - 3517; DOI:
10.1021/ic00043a007
PDF
Electrochemical and photophysical properties of new triazole-bridged heterobimetallic ruthenium-rhodium and ruthenium-iridium complexes
John H. Van Diemen, Ronald Hage, Jaap G. Haasnoot, Hans E. B. Lempers, Jan Reedijk, Johannes G. Vos, Luisa De Cola, Francesco Barigelletti, and Vincenzo Balzani
pp 3518 - 3522; DOI:
10.1021/ic00043a008
PDF
Oxidation of ferrous ions by ozone in acidic solutions
Tine Loegager, Jerzy Holcman, Knud Sehested, and Thorvald Pedersen
pp 3523 - 3529; DOI:
10.1021/ic00043a009
PDF
Self-assembly of ion-paired electron-transfer centers in a clay-modified electrode
D. Petridis, P. Falaras, and T. J. Pinnavaia
pp 3530 - 3533; DOI:
10.1021/ic00043a010
PDF
Hypochlorous acid decomposition in the pH 5-8 region
Luke C. Adam, Istvan Fabian, Kazunori Suzuki, and Gilbert Gordon
pp 3534 - 3541; DOI:
10.1021/ic00043a011
PDF
Linkage isomerization reactions of (acetone)pentaammineruthenium(III) and -ruthenium(II) complexes
David W. Powell and Peter A. Lay
pp 3542 - 3550; DOI:
10.1021/ic00043a012
PDF
High-pressure stopped-flow study of kinetics and mechanism for complex formation reactions of tetraaquapalladium(II) and platinum(II) with thioethers in aqueous solution
S. Elmroth, Z. Bugarcic, and L. I. Elding
pp 3551 - 3554; DOI:
10.1021/ic00043a013
PDF
Crystal and molecular structure of a (dibenzylideneacetone)platinum dimer with partial Pt occupancy
Larry N. Lewis, Terry A. Krafft, and John C. Huffman
pp 3555 - 3557; DOI:
10.1021/ic00043a014
PDF
Synthesis and structural characterization of metallacarboranes containing bridged dicarbollide ligands
Frank A. Gomez, Stephen E. Johnson, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 3558 - 3567; DOI:
10.1021/ic00043a015
PDF
Band structures of and bonding in 10-electron solids: Aluminum-manganese (MnAl), chromium silicide (CrSi), vanadium phosphide (VP), titanium sulfide (TiS)
R. J. Kematick and C. E. Myers
pp 3568 - 3572; DOI:
10.1021/ic00043a016
PDF
Formation of the {MO(S2)2} (M = molybdenum, tungsten) moiety by a MO42--polysulfide reaction: synthesis and structure of MO(S2)2(bpy)
Prasanta K. Chakrabarty, Samaresh Bhattacharya, Cortlandt G. Pierpont, and Ramgopal Bhattacharyya
pp 3573 - 3577; DOI:
10.1021/ic00043a017
PDF
Ferromagnetic behavior of nickel(II)-imino nitroxide derivatives
Dominique Luneau, Paul Rey, Jean Laugier, Elie Belorizky, and Andre Cogne
pp 3578 - 3584; DOI:
10.1021/ic00043a018
PDF
Synthesis, x-ray crystal structures, and magnetic properties of tetranickel complexes of a macrocyclic tetranucleating ligand
Alison J. Edwards, Bernard F. Hoskins, Edward H. Kachab, Andrew Markiewicz, Keith S. Murray, and Richard Robson
pp 3585 - 3591; DOI:
10.1021/ic00043a019
PDF
Reactivity of hydrazines with organometallic samarium complexes and the x-ray crystal structures of (C5Me5)2Sm(.eta.2-PhNHNPh)(THF), (C5Me5)2Sm(NHPh)(THF), and [(C5Me5)2Sm]2(.mu.-.eta.2:.eta.2-HNNH)
William J. Evans, Gabriele Kociok-Koehn, Voon S. Leong, and Joseph W. Ziller
pp 3592 - 3600; DOI:
10.1021/ic00043a020
PDF
Stereochemical nonrigidity and ligand dynamics in hypervalent tin(IV) compounds. Heteronuclear NMR and crystallographic studies of triorganoyltin(IV) and diorganoyltin(IV) complexes with dithiolate ligands
Dainis Dakternieks, Hongjian Zhu, Dante Masi, and Carlo Mealli
pp 3601 - 3606; DOI:
10.1021/ic00043a021
PDF
Synthesis, structure, and characterization of a phenolate-bridged dimanganese(II) complex of a dinucleating phenol ligand
Yilma Gultneh, Amjad Farooq, Shuncheng Liu, Kenneth D. Karlin, and Jon Zubieta
pp 3607 - 3611; DOI:
10.1021/ic00043a022
PDF
X-ray absorption spectra of nickel complexes with N3S2 chromophores and spectroscopic studies on hydride and carbon monoxide binding at these nickel centers: relevance to the reactivity of the nickel site(s) in [FeNi] hydrogenases
Narayan Baidya, Marilyn M. Olmstead, Joyce P. Whitehead, Csaba Bagyinka, Michael J. Maroney, and Pradip K. Mascharak
pp 3612 - 3619; DOI:
10.1021/ic00043a023
PDF
Synthesis, properties, and x-ray structures of nickel(I) complexes of polyaza macrotricyclic ligands
Myunghyun Paik Suh, Hyun Kyung Kim, Myung Jin Kim, and Kye Young Oh
pp 3620 - 3625; DOI:
10.1021/ic00043a024
PDF
Electrochemical synthesis and the molecular structure of a benzeneselenolato complex of copper, Ph3PCu(.mu.-SePh)2Cu(PPh3)2.cntdot.CH3CN, containing both three- and four-coordinate copper
Jeff Kampf, Rajesh Kumar, and John P. Oliver
pp 3626 - 3629; DOI:
10.1021/ic00043a025
PDF
Oxygenation of cobalt(II)-substituted Limulus polyphemus hemocyanin: kinetics, CD, and MCD studies
James A. Larrabee, Theodore F. Baumann, Sarah J. Chisdes, and Thomas J. Lyons
pp 3630 - 3635; DOI:
10.1021/ic00043a026
PDF
Synthesis and characterization of a series of achiral and chiral mono- and bis[(dien)Pt(II)I]I derivatives as potential DNA and RNA structure probes and anticancer drugs
Rushdi Alul, Martin B. Cleaver, and John Stephen Taylor
pp 3636 - 3646; DOI:
10.1021/ic00043a027
PDF
Quantum mechanical ab initio studies of the structures and stabilities of halogen azides XN3 (X = F, Cl, Br, I)
M. Otto, S. D. Lotz, and G. Frenking
pp 3647 - 3655; DOI:
10.1021/ic00043a028
PDF
Structural, far-IR and phosphorus-31 NMR studies of two-coordinate complexes of tris(2,4,6-trimethoxyphenyl)phosphine with silver(I) halides
Lisa Jane Baker, Graham A. Bowmaker, David Camp, Effendy, Peter C. Healy, Hubert Schmidbaur, Oliver Steigelmann, and Allan H. White
pp 3656 - 3662; DOI:
10.1021/ic00043a029
PDF
Nonredox reactions between dihydrogen sulfide and cis-Re2(.mu.-O2CR)2Cl2(.mu.-dppm)2 (R = CH3, C2H5; dppm = Ph2PCH2PPh2). Isolation and characterization of bis(.mu.-hydrosulfido) and .mu.-gem-dithiolato complexes of dirhenium(II)
Keng Yu Shih, Phillip E. Fanwick, and Richard A. Walton
pp 3663 - 3668; DOI:
10.1021/ic00043a030
PDF
Structural analysis of the e2 and a2 isomers of octadecahydroeicosaborate (4-)
Lai Ling Ng, Bradford K. Ng, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 3669 - 3671; DOI:
10.1021/ic00043a031
PDF
Hydroxo-bridged fac-tricarbonylmolybdenum(0) complexes: synthesis, molybdenum-95 NMR spectroscopy, and crystal structure of Cs4[Mo4(.mu.3-OH)4(CO)12].cntdot.nH2O
Arne Beyerholm, Michael Brorson, Martin Minelli, and Lars K. Skov
pp 3672 - 3675; DOI:
10.1021/ic00043a032
PDF
Crystallographic disorder in the orthorhombic form of carbonyl(chlorobis(triphenylphosphine)rhodium: relevance to the reported structure of the paramagnetic impurity in Wilkinson's catalyst
Kim. R. Dunbar and Steven C. Haefner
pp 3676 - 3679; DOI:
10.1021/ic00043a033
PDF
Electrocatalytic reduction of carbon dioxide with iron, cobalt, and nickel complexes of terdentate ligands
C. Arana, S. Yan, J. Keshavarz, K. T. Potts, and H. D. Abruna
pp 3680 - 3682; DOI:
10.1021/ic00043a034
PDF

Issue 18


Ferrate(VI), a novel near-infrared luminophore
Markus Herren and Hans U. Guedel
pp 3683 - 3684; DOI:
10.1021/ic00044a001
PDF
Competing metal-metal bonding in heterometallic complexes of gold and mercury. Synthesis of contrasting iron-gold-gold-iron and iron-mercury-iron complexes
Pierre Braunstein, Michael Knorr, Antonio Tiripicchio, and Marisa Tiripicchio Camellini
pp 3685 - 3687; DOI:
10.1021/ic00044a002
PDF
Luminescent unidimensional organometallic materials. Structural and emission properties of the {[Ag(dmb)2](Y)}n polymers (dmb = 1,8-diisocyano-p-menthane; Y = PF6, BF4, NO3)
Daniel Perreault, Marc Drouin, Andre Michel, and Pierre D. Harvey
pp 3688 - 3689; DOI:
10.1021/ic00044a003
PDF
Triiron-triangle opening and closing by a single two-electron process in the bicapped triiron clusters Fe3(CO)9(.mu.3-PMLn)2 (MLn = CpFe(CO)2, CpMn(CO)2)
Yoshihiro Koide, Maria T. Bautista, Peter S. White, and Cynthia K. Schauer
pp 3690 - 3692; DOI:
10.1021/ic00044a004
PDF
Facile and complete four electron two oxygen atom transfer reactions involving manganese bis(.mu.-oxo) dimers
Gregory C. Dailey and Colin P. Horwitz
pp 3693 - 3694; DOI:
10.1021/ic00044a005
PDF
High-pressure kinetic evidence for a dissociative interchange (Id) substitution mechanism for aquated chromium(II)
Rudi Van Eldik, Wolfgang Gaede, Haim Cohen, and Dan Meyerstein
pp 3695 - 3696; DOI:
10.1021/ic00044a006
PDF
Synthesis and molecular structure of bis(tetrabutylammonium)bis[tetrakis(perfluorophenyl)palladium]plumbate(2-), the first lead(II) compound linearly bonded to two metal atoms
Rafael Uson, Juan Fornies, Larry R. Falvello, Miguel A. Uson, and Isabel Uson
pp 3697 - 3698; DOI:
10.1021/ic00044a007
PDF
The chemistry of methyl(octaethylporphyrinato)ruthenium. A methyl to carbon monoxide transformation
Jeffery W. Seyler, Phillip E. Fanwick, and Charles R. Leidner
pp 3699 - 3700; DOI:
10.1021/ic00044a008
PDF
Cadmium binding by biological ligands. 5. Solution studies of cadmium and zinc binding by sulfhydryl ligands N,N'-dimethyl-N,N'-bis(2-mercaptoethyl)ethylenediamine and (2-mercaptoethyl)amine
Alex Avdeef, Frances Hartenstein, Alfred R. Chemotti, and Jessica A. Brown
pp 3701 - 3705; DOI:
10.1021/ic00044a009
PDF
Phosphorus-31 NMR studies of the formation of a (cysteine-34)(.mu.-thiolato)bis(gold(I) triethylphosphine) species of bovine serum albumin and a related model titration
Jun Xiao and C. Frank Shaw
pp 3706 - 3710; DOI:
10.1021/ic00044a010
PDF
Transition-metal complexes with sulfur ligands. 88. Dependence of spin state, structure, and reactivity of [FeII(L) ('NH)S4')] complexes on the coligand L (L = CO, N2H2, N2H4, NH3, pyridine, NHCH3NH2, CH3OH, THF, P(OCH3)3, P(OPh)3): model complexes for iron nitrogenases ('NHS4'2-dianion of 2,2'-bis[(2-mercaptophenyl)thio]diethylamine)
Dieter Sellmann, Wolfgang Soglowek, Falk Knoch, Gerhard Ritter, and Joachim Dengler
pp 3711 - 3717; DOI:
10.1021/ic00044a011
PDF
Periodic trends in charge distribution for transition metal complexes containing catecholate and semiquinone ligands. Metal-mediated spin coupling in the bis(3,5-di-tert-butyl-1,2-semiquinone) complexes of palladium(II) and platinum(II) M(DBSQ)2 (M = Pd, Pt)
Glenn A. Fox and Cortlandt G. Pierpont
pp 3718 - 3723; DOI:
10.1021/ic00044a012
PDF
Monomeric uranyl alkoxide and amide complexes
C. J. Burns, D. C. Smith, A. P. Sattelberger, and H. B. Gray
pp 3724 - 3727; DOI:
10.1021/ic00044a013
PDF
Crystallographic evidence of preferred N(9)-coordination of xanthine: structures of CuII(xan)2(NO3)2.cntdot.2H2O, CuII(xan)2Cl2.cntdot.2H2O, and ZnII(xan)2Cl2 (xan = xanthine)
Erich Dubler, Gaby Haenggi, and Helmut Schmalle
pp 3728 - 3736; DOI:
10.1021/ic00044a014
PDF
Mono- and dinuclear titanium(III)/titanium(IV) complexes with 1,4,7-trimethyl-1,4,7-triazacyclononane (L). Crystal structures of a compositionally disordered green and a blue form of [LTiCl3]. Structures of [LTi(O)(NCS)2], [LTi(OCH3)Br2](ClO4), and [L2Ti2(O)2F2(.mu.-F)](PF6)
Axel Bodner, Peter Jeske, Thomas Weyhermueller, Karl Wieghardt, Erich Dubler, Helmut Schmalle, and Bernhard Nuber
pp 3737 - 3748; DOI:
10.1021/ic00044a015
PDF
Terminal vs bridging imido ligation in complexes of zirconium(IV) and hafnium(IV): structural characterization of a .mu.-[.eta.1(N):.eta.2(N,C)] imido ligand
David J. Arney, Michael A. Bruck, Susan R. Huber, and David E. Wigley
pp 3749 - 3755; DOI:
10.1021/ic00044a016
PDF
Synthesis and structures of P2(BNR2)3 cages
Danan Dou, Gary L. Wood, Eileen Duesler, Robert T. Paine, and Heinrich Noeth
pp 3756 - 3762; DOI:
10.1021/ic00044a017
PDF
An ab initio/IGLO/NMR study of carboranes, closo-C2B6H8, closo-CB7H8-, closo-B8H82-, and C3B5H7
Joseph W. Bausch, G. K. Surya Prakash, and Robert E. Williams
pp 3763 - 3768; DOI:
10.1021/ic00044a018
PDF
The structure of octahydrooctaborate(2-) in solution. Is nonahydrooctaborate(1-) also involved? An ab initio/IGLO/NMR study
Michael Buehl, A. M. Mebel, O. P. Charkin, and Paul v. R. Schleyer
pp 3769 - 3775; DOI:
10.1021/ic00044a019
PDF
A novel synthesis of N-fluoroperfluoroalkanimines. Reaction of perfluorinated secondary amines with antimony pentafluoride
V. A. Petrov and D. D. DesMarteau
pp 3776 - 3778; DOI:
10.1021/ic00044a020
PDF
Electronic structure of metal chalcogen cubane clusters: photoelectron spectroscopic, electrochemical, and theoretical studies of [(.eta.-C5H4Me)TiS]4, [(.eta.-C5H4Me)VS]4, [(.eta.-C5H5)CrO]4, [(.eta.-C5H4Me)CrO]4, [(.eta.-C5H4Me)CrS]4, [(.eta.-C5H4Me)CrSe]4, [(.eta.-C5H4-iso-Pr)MoS]4, and [(.eta.-C5H4-iso-Pr)MoSe]4
Cathryn E. Davies, Jennifer C. Green, Nikolas Kaltsoyannis, Michael A. MacDonald, Jingui Qin, Thomas B. Rauchfuss, Catherine M. Redfern, Graham H. Stringer, and Mark G. Woolhouse
pp 3779 - 3791; DOI:
10.1021/ic00044a021
PDF
Trifluoromethyl-substituted 2,2'-bipyridine ligands. Synthetic control of excited-state properties of ruthenium(II) tris-chelate complexes
Masaoki Furue, Kazunori Maruyama, Tadayoshi Oguni, Masahiro Naiki, and Mikiharu Kamachi
pp 3792 - 3795; DOI:
10.1021/ic00044a022
PDF
Kinetic and thermodynamic measurements on branched amino polythiaether ligands: a family of complexing agents analogous to EDTA and NTA exhibiting enhanced selectivity for copper(II)
Thomas H. Cooper, Michael J. Mayer, Kwan Hang Leung, L. A. Ochrymowycz, and D. B. Rorabacher
pp 3796 - 3804; DOI:
10.1021/ic00044a023
PDF
Kinetics and mechanism of the acetate-catalyzed heterolysis of the metal-carbon .sigma. bond of (.alpha.-hydroxyalkyl)chromium(III) complexes. Effects of nonparticipating ligands, temperature, and pressure
Haim Cohen, Wolfgang Gaede, Achim Gerhard, Dan Meyerstein, and Rudi Van Eldik
pp 3805 - 3809; DOI:
10.1021/ic00044a024
PDF
Disproportionation of sulfur dioxide to octasulfur and sulfur trioxide on Cp*2Cr2S5. Crystallographic and sulfur-34-labeling evidence for an oxygen-transfer mechanism and observation of facile exchange of Cr2S5 core sulfurs with 34S. Structures of Cp*2Cr2(.mu.-S)(.mu.-.eta.2-S2)(.mu.-.eta.1-SS.cntdot.SO2).cntdot.SO2 and Cp*2Cr2(.mu.-S)(.mu.-.eta.2-S2)(.mu.-SSO3)
Andreas Toupadakis, Gregory J. Kubas, and Carol J. Burns
pp 3810 - 3817; DOI:
10.1021/ic00044a025
PDF
Synthesis and characterization of the heterometallic phosphinidene clusters (C5Me5)WRu3(CO)10(.mu.3-H)(.mu.3-PPh), (C5H5)WRu2(CO)8(.mu.-H)(.mu.3-PPh), and (C5Me5)WRu2(CO)8(.mu.-H)(.mu.3-PPh)
Ren Chiun Lin, Yun Chi, Shie Ming Peng, and Gene Hsiang Lee
pp 3818 - 3824; DOI:
10.1021/ic00044a026
PDF
Seven-coordinate tungsten(II) hydridotris(3,5-dimethylpyrazolyl)borate tricarbonyl phosphine complexes with a capped octahedral geometry
C. C. Philipp, P. S. White, and J. L. Templeton
pp 3825 - 3830; DOI:
10.1021/ic00044a027
PDF
Formation of monometallic bis(bicarbonato) complexes of palladium(II) by the insertion of carbon dioxide into palladium(II)-hydroxide bonds
Sanjoy Ganguly, Joel T. Mague, and D. Max Roundhill
pp 3831 - 3835; DOI:
10.1021/ic00044a028
PDF
Platinum(IV)-mediated redox coupling of 2-propanone oximes in cis-[Pt(Me2C=NOH)2Cl4]. Crystal structure of [Pt(N(=O)CMe2ONCMe2)Cl2]
V. Yu. Kukushkin, V. K. Bel'skii, E. A. Aleksandrova, V. E. Konovalov, and G. A. Kirakosyan
pp 3836 - 3840; DOI:
10.1021/ic00044a029
PDF
Mixed iridium-gold hydrides as model compounds for elucidating the interconversion between classical and nonclassical polyhydrides
Claudio Bianchini, Andrea Meli, Maurizio Peruzzini, Alberto Vacca, Francesco Vizza, and Alberto Albinati
pp 3841 - 3850; DOI:
10.1021/ic00044a030
PDF
A new magnetic lattice in the "cdta family". Structure and magnetic properties of the novel homo- and heterometallic chains Cu3[M(cdta)]2(NO3)2.cntdot.15H2O (M = copper, nickel)
F. Sapina, E. Escriva, J. V. Folgado, A. Beltran, D. Beltran, A. Fuertes, and M. Drillon
pp 3851 - 3858; DOI:
10.1021/ic00044a031
PDF
Structural, EPR, and magnetic characterization of bis(piperazinium) hexachlorocuprate-methanol and bis(1-methylpiperazinium) hexachlorocuprate
A. Bonamartini-Corradi, L. P. Battaglia, J. Rubenacker, R. D. Willett, T. E. Grigereit, P. Zhou, and J. E. Drumheller
pp 3859 - 3863; DOI:
10.1021/ic00044a032
PDF
Fluorination of calcium cyanamide: a convenient laboratory scale synthesis of carbon tetrafluoride
Inis C. Tornieporth-Oetting, Matthias Broschag, and Thomas M. Klapoetke
pp 3864 - 3864; DOI:
10.1021/ic00044a033
PDF
Electrospray mass spectrometric study of ionic derivatives of platinum(II) dithiolates with polyphosphines
Ray Colton, Vanda Tedesco, and John C. Traeger
pp 3865 - 3866; DOI:
10.1021/ic00044a034
PDF
Release of platinum from cysteine residues induced by N,S-donor chelation
Katherine S. Wyatt, Karl N. Harrison, and Craig M. Jensen
pp 3867 - 3868; DOI:
10.1021/ic00044a035
PDF
New triborate-pillared hydrotalcites
Alak Bhattacharyya and Daniel B. Hall
pp 3869 - 3870; DOI:
10.1021/ic00044a036
PDF

Issue 19


Macrocyclic (C22H22N4) complexes of germanium(II), tin(II), gallium(III), and indium(III). Main group functionalities in unusual environments
David A. Atwood, Vicki O. Atwood, Alan H. Cowley, Jerry L. Atwood, and Enrique Roman
pp 3871 - 3872; DOI:
10.1021/ic00045a001
PDF
Direct observations of the intermediate species in the photodissociation of bis(S-benzyl-1,2-diphenyl-1,2-ethylenedithiolato) nickel by time-resolved EPR and UV-visible absorption spectroscopy
Miharu Ohtani, Shinichi Ohkoshi, Masatsugu Kajitani, Takeo Akiyama, Akira Sugimori, Seigo Yamauchi, Yasunori Ohba, and Masamoto Iwaizumi
pp 3873 - 3874; DOI:
10.1021/ic00045a002
PDF
Synthesis and structure of unprecedented copper(I)-rhodium(III) CuI4RhIII4 and copper(I)-iridium(III) CuI4IrIII4 S-bridged polynuclear complexes containing .mu.2- and .mu.3-thiolato and coordinated disulfide: spontaneous reduction of copper(II) to trigonal-planar copper(I)
Takumi Konno, Kenichi Okamoto, and Jinsai Hidaka
pp 3875 - 3876; DOI:
10.1021/ic00045a003
PDF
Bridging amido complexes of dirhodium and diiridium tetracarbonyls
Manoj K. Kolel-Veetil, Marufur Rahim, Andrew J. Edwards, Arnold L. Rheingold, and Kazi J. Ahmed
pp 3877 - 3878; DOI:
10.1021/ic00045a004
PDF
Multielectron-transfer kinetics for cis- versus trans-dioxorhenium(V) species: isoelectronic modeling with osmium(VI/V) and control of interfacial reactivity by rhenium(IV) accessibility
Lisa M. Jones-Skeens, Xiao Lian Zhang, and Joseph T. Hupp
pp 3879 - 3881; DOI:
10.1021/ic00045a005
PDF
Synthesis, characterization, and x-ray structure of the zirconium bis(porphyrinate) di(.pi.-radical-cation) complex [Zr(TPP)2][SbCl6]2, and x-ray structure of the mono(.pi.-radical-cation) complex [Zr(TPP)2][SbCl6]
Hee Joon Kim, Dongmok Whang, Jaheon Kim, and Kimoon Kim
pp 3882 - 3886; DOI:
10.1021/ic00045a006
PDF
Amido complexes of (cyclopentadienyl)dichlorotitanium(IV): titanium-nitrogen multiple-bond character
Dean M. Giolando, Kristin Kirschbaum, Lisa J. Graves, and Urs Bolle
pp 3887 - 3890; DOI:
10.1021/ic00045a007
PDF
Synthesis, structure, and characterization of the diimido-bridged, bimetallic molybdenum(V) complex oxobis[(diethyldithiocarbamato)(.mu.-2-aminothiophenolato)molybdenum(V)]-bis(dichloromethane), (dtc)MoO(.mu.-NC6H4S)2Mo(dtc).2CH2Cl2, and of the precursor in the formation of this bimetallic molybdenum(V) complex, bis(diethyldithiocarbamato)(2-aminothiophenolato)(methoxy)molybdenum(VI), Mo(NC6H4S)(OCH3)(dtc)2
Martin Minelli, Roger L. Kuhlman, Steven J. Shaffer, and Michael Y. Chiang
pp 3891 - 3896; DOI:
10.1021/ic00045a008
PDF
Organotransition-metal metallacarboranes. 28. Controlled substitution at cage carbon atoms in CoC2B4 clusters. Linkage of bis(cobaltacarborane) sandwich complexes via carbon-bound bridging groups
Mark A. Benvenuto and Russell N. Grimes
pp 3897 - 3903; DOI:
10.1021/ic00045a009
PDF
Organotransition-metal metallacarboranes. 29. Synthesis of selectively C- and B-substituted double- and triple-decker sandwiches. (.eta.5-C5Me5)CoIII(.eta.5-R2C2B3R'3H2) cobaltocenium analogs
Mark A. Benvenuto, Michal Sabat, and Russell N. Grimes
pp 3904 - 3909; DOI:
10.1021/ic00045a010
PDF
Cage opening of closo-C2B6H8 with hydride ion and with trimethylamine: preparation of a new carborane anion and of a trimethylamine adduct of C2B6H8
Thomas Onak, James Tseng, Dan Tran, Sergio Herrera, Bryant Chan, Joachin Arias, and Martin Diaz
pp 3910 - 3913; DOI:
10.1021/ic00045a011
PDF
Stretched H2 complexes: structural control in ReH7{P(C6H4-p-X)3}2 (X = CH3, H, F, CF3, OMe) complexes by electronic ligand effects
Demetrius Michos, Xiao Liang Luo, Judith A. K. Howard, and Robert H. Crabtree
pp 3914 - 3916; DOI:
10.1021/ic00045a012
PDF
Phosphato-titanium coordination chemistry. New phosphato-bridged chlorotitanium, imidotitanium, and oxotitanium compounds
David L. Thorn and Richard L. Harlow
pp 3917 - 3923; DOI:
10.1021/ic00045a013
PDF
Synthesis and structures of hexanuclear tantalum clusters with the [Ta6Cl12(CH3OH)6]3+ unit
N. Brnicevic, D. Nothig-Hus, B. Kojic-Prodic, Z. Ruzic-Toros, Z. Danilovic, and R. E. McCarley
pp 3924 - 3928; DOI:
10.1021/ic00045a014
PDF
Conversion of the (.mu.2-sulfido)dirhenium(III) complexes Re2(.mu.-S)(.mu.-X)X3(CS)(.mu.-LL)2 (X = Cl, Br; LL = dppm, dpam) and related species to the analogous .mu.2-sulfur dioxide compounds
Paul W. Schrier, Phillip E. Fanwick, and Richard A. Walton
pp 3929 - 3933; DOI:
10.1021/ic00045a015
PDF
Structural motifs in dinuclear d8 metal complexes. Structural and spectroscopic characteristics of an alternative unsymmetrical 3:5 ligand distribution as compared to the symmetrical 4:4 or face-to-face arrangement
Alan L. Balch and Vincent J. Catalano
pp 3934 - 3942; DOI:
10.1021/ic00045a016
PDF
Spectroscopic analysis, coordination geometry, and x-ray structures of nickel(II) compounds with sterically demanding tris(pyrazolyl)borate ligands and azide or (thio)cyanate anions. Crystal and molecular structures of bis[(.mu.-thiocyanato-N,S)(hydrotris(3-isopropyl-4-bromopyrazol-1-yl)borato)nickel(II)]-3-heptane and (thiocyanato-N)(hydrotris(3-tert-butyl-5-methylpyrazol-1-yl)borato)nickel(II)
S. Trofimenko, J. C. Calabrese, J. K. Kochi, S. Wolowiec, F. B. Hulsbergen, and J. Reedijk
pp 3943 - 3950; DOI:
10.1021/ic00045a017
PDF
A linear, monomeric copper(I) acetate derivative, bis[bis(phenanthroline)copper] bis(acetato)cuprate(1-) hydrogen bis(acetate). An effective catalyst for the decarboxylation of carboxylic acids
Donald J. Darensbourg, Elisabeth M. Longridge, Earl V. Atnip, and Joseph H. Reibenspies
pp 3951 - 3955; DOI:
10.1021/ic00045a018
PDF
Structures and properties of copper(II) and copper(I) complexes containing an ethane-bridged dimeric phenanthroline ligand
Yuan Yao, Marc W. Perkovic, D. Paul Rillema, and Clifton Woods
pp 3956 - 3962; DOI:
10.1021/ic00045a019
PDF
Immobilization of thallium by tandem oxidation/reduction-complexation of thallium(I/III)
Ishenkumba A. Kahwa, Dionne Miller, Maurene Mitchel, Frank R. Fronczek, R. G. Goodrich, David J. Williams, Caroline A. O'Mahoney, Alexandra M. Z. Slawin, Steven V. Ley, and Christopher J. Groombridge
pp 3963 - 3970; DOI:
10.1021/ic00045a020
PDF
Oxidation of thiolato complexes of ruthenium(III) by peroxymonosulfate
Michael D. Johnson and Darren Nickerson
pp 3971 - 3974; DOI:
10.1021/ic00045a021
PDF
A multinuclear ligand NMR investigation of cyanide, cyanate, and thiocyanate binding to zinc and cobalt carbonic anhydrase
Ivano Bertini, Claudio Luchinat, Roberta Pierattelli, and Alejandro J. Vila
pp 3975 - 3979; DOI:
10.1021/ic00045a022
PDF
Proton speciation in ambient-temperature chloroaluminate ionic liquids
Paul C. Trulove and Robert A. Osteryoung
pp 3980 - 3985; DOI:
10.1021/ic00045a023
PDF
High-pressure pulse-radiolysis study of intramolecular and intermolecular reduction of cytochrome c by ruthenium(II) ammine complexes
James F. Wishart, Rudi Van Eldik, Ji Sun, Chang Su, and Stephan S. Isied
pp 3986 - 3989; DOI:
10.1021/ic00045a024
PDF
Thermodynamics of copper(II) complexation by macrocyclic tetrathioethers at 25.degree.C in water-methanol mixtures and acetonitrile: correlations of complexation enthalpy and ligand conformational preferences
A. Yu. Nazarenko, R. M. Izatt, J. D. Lamb, J. M. Desper, B. E. Matysik, and S. H. Gellman
pp 3990 - 3993; DOI:
10.1021/ic00045a025
PDF
Toward artificial metallopeptidases: mechanisms by which platinum(II) and palladium(II) complexes promote selective, fast hydrolysis of unactivated amide bonds in peptides
Longgen Zhu and Nenad M. Kostic
pp 3994 - 4001; DOI:
10.1021/ic00045a026
PDF
Transition metal complexes of the cis-dithiosquaramide ligand family
Greg R. Frauenhoff, Fusao Takusagawa, and Daryle H. Busch
pp 4002 - 4007; DOI:
10.1021/ic00045a027
PDF
Synthesis, structure, and characterization of bis(diethyldithiocarbamato)(diethylthiocarbamyl)sulfidoniobium(V) and its tantalum analog
P. F. Gilletti, D. A. Femec, F. I. Keen, and T. M. Brown
pp 4008 - 4012; DOI:
10.1021/ic00045a028
PDF
Hydrogenation of benzylideneacetone catalyzed by chlorodihydridobis(diisopropylphosphine)iridium: kinetic evidence for the participation of an iridium-.eta.2-dihydrogen complex in the activation of molecular hydrogen
Miguel A. Esteruelas, Juana Herrero, Ana M. Lopez, Luis A. Oro, Michael Schulz, and Helmut Werner
pp 4013 - 4014; DOI:
10.1021/ic00045a029
PDF
A convenient synthesis of 1,1,1,3,3,3-hexaphenyldiplumbathiane and 1,1,1,3,3,3-hexaphenyldiplumbaselenane
Steven R. Bahr and Philip Boudjouk
pp 4015 - 4016; DOI:
10.1021/ic00045a030
PDF
Kinetics of iron(III) reduction by hemoglobin and its isolated .alpha.-subunits
Bruce R. Van Dyke, Louis Katen, Jack Hegenauer, and Paul Saltman
pp 4017 - 4018; DOI:
10.1021/ic00045a031
PDF
Substitution or nucleophilic attack by phosphines on tetrachlorobis(tetrahydrofuran)zirconium
Tricia L. Breen and Douglas W. Stephan
pp 4019 - 4022; DOI:
10.1021/ic00045a032
PDF
A heptaruthenium carbonyl cluster: synthesis and structural characterization of [PPN][HRu7(CO)20]
Catherine E. Housecroft, Arnold L. Rheingold, and Xuejing Song
pp 4023 - 4025; DOI:
10.1021/ic00045a033
PDF
Structural information on chromium(V) complexes of 1,2-diols in solution, as determined by isotropic and anisotropic proteon ENDOR spectroscopy. [Erratum to document cited in CA116(26):267652h]
Mario Branca, Giovanni Micera, Ulderico Segre, and Alessandro Dessi
pp 4026 - 4026; DOI:
10.1021/ic00045a034
PDF

Issue 20


1,3,5-Trideoxy-1,3,5-tris((2-hydroxybenzyl)amino)-cis-inositol, a novel multidentate ligand providing various N,O coordination sites. Structure of the rhenium(V) complex
Kaspar Hegetschweiler, Andre Egli, Roger Alberto, and Helmut W. Schmalle
pp 4027 - 4028; DOI:
10.1021/ic00046a001
PDF
An unusual elimination of ammonia from cobalt-bound alkylamine dimer ions
Lin Zhi Chen and Jack M. Miller
pp 4029 - 4031; DOI:
10.1021/ic00046a002
PDF
Tridecavanadate, [H12V13O40]3-
Lage Pettersson, Ingegaerd Andersson, and Oliver W. Howarth
pp 4032 - 4033; DOI:
10.1021/ic00046a003
PDF
Convenient synthesis of diacyl complexes of platinum(II) via novel stereoselective carbon monoxide-insertion and acyl scrambling of trans acyl alkyl complexes of platinum. A mechanistic model of palladium-catalyzed coupling and carbonylative coupling of acid halides with organometals
Gwo Liang Huang, Tsang Miao Huang, and Jwu Ting Chen
pp 4034 - 4035; DOI:
10.1021/ic00046a004
PDF
Synthesis, characterization, and molecular structure of the first metal complex containing thallium chloride as a ligand. A novel carrier of thallium(I)
Claudio Bianchini, Dante Masi, Klaus Linn, Carlo Mealli, Maurizio Peruzzini, and Fabrizio Zanobini
pp 4036 - 4037; DOI:
10.1021/ic00046a005
PDF
Detection of a rotation barrier around a bond between heavier Main Group 3 and 5 elements
Mark A. Petrie, Karin Ruhlandt-Senge, and Philip P. Power
pp 4038 - 4039; DOI:
10.1021/ic00046a006
PDF
An unusual example of multiple proton-coupled electron transfers in a high-valent oxomanganese dimer, [(phen)2MnIII(O)2MnIV(phen)2](ClO4)3 (phen = 1,10 phenanthroline)
Rajesh Manchanda, H. Holden Thorp, Gary W. Brudvig, and Robert H. Crabtree
pp 4040 - 4041; DOI:
10.1021/ic00046a007
PDF
Preparation and characterization of a novel oxoiron(IV) chlorin .pi.-cation radical complex. The first model for compound I of chlorin-containing heme enzymes
Shinji Ozawa, Yoshihito Watanabe, and Isao Morishima
pp 4042 - 4043; DOI:
10.1021/ic00046a008
PDF
Excited-state proton transfer in trans-dioxorhenium(V)
Wentian Liu, Thomas W. Welch, and H. Holden Thorp
pp 4044 - 4045; DOI:
10.1021/ic00046a009
PDF
X-ray diffraction and fluorine-19 and thallium-205 NMR evidence for electrophile binding to an organofluorine substituent
John A. Samuels, Josef W. Zwanziger, Emil B. Lobkovsky, and Kenneth G. Caulton
pp 4046 - 4047; DOI:
10.1021/ic00046a010
PDF
Iron oxo aggregation: Fe3 to Fe6. Synthesis, structure, and magnetic properties of the hexanuclear dication [Fe6(.mu.4-O)2(.mu.2-OMe)8(OMe)4(tren)2]2+, a soluble, crystalline model of iron oxo hydroxo nanoparticles, the core of ferritin and rust formation
Vinod S. Nair and Karl S. Hagen
pp 4048 - 4050; DOI:
10.1021/ic00046a011
PDF
Comparison of the ligand substitution rates of the 17-electron radicals (Arene)M(CO)3+ (M = chromium, molybdenum, tungsten)
Q. Meng, Y. Huang, W. J. Ryan, and D. A. Sweigart
pp 4051 - 4052; DOI:
10.1021/ic00046a012
PDF
Evidence for intramolecular NH---S hydrogen bonds from deuterium-NMR spectroscopy of reduced-rubredoxin model iron(II) complexes with bidentate peptide ligands
Norikazu Ueyama, Wei Yin Sun, and Akira Nakamura
pp 4053 - 4059; DOI:
10.1021/ic00046a013
PDF
In situ spectroelectrochemical studies of oxygen reduction in dimethyl sulfoxide and pyridine
Doo Soon Shin, Narayan Doddapaneni, and Su Moon Park
pp 4060 - 4064; DOI:
10.1021/ic00046a014
PDF
Synthesis and metal complex selectivity of macrocyclic DTPA and EDTA bis(amide) ligands
Joan F. Carvalho, Sook Hui Kim, and C. Allen Chang
pp 4065 - 4068; DOI:
10.1021/ic00046a015
PDF
Amide complexes of (diethylenetriamine)platinum(II)
Tai Chin Woon and David P. Fairlie
pp 4069 - 4074; DOI:
10.1021/ic00046a016
PDF
New transition metal-gold clusters: synthesis and characterization of the tungsten-gold clusters [W(CO)4(AuPPh3)5](PF6). [W(CO)3(AuPPh3)7](PF6), and [W(CO)4(AuPPh3)6](NO3)2. Crystal structures of [W(CO)4(AuPPh3)5](PF6).cntdot.CH2Cl2 and [W(CO)3(AuPPh3)7](PF6)
T. G. M. M. Kappen, A. C. M. Van den Broek, P. P. J. Schlebos, J. J. Bour, W. P. Bosman, J. M. M. Smits, P. T. Beurskens, and J. J. Steggerda
pp 4075 - 4080; DOI:
10.1021/ic00046a017
PDF
Reactions of the 12-electron alkoxide-supported tungsten clusters W4(OR)12 (R = CH2-iso-Pr, cyclopentylmethyl) with isocyanides, nitriles, nitric oxide, and alkynes. Comparison with the reactivity of W2(OR)6 compounds
Malcolm H. Chisholm, Victor J. Johnston, and William E. Streib
pp 4081 - 4083; DOI:
10.1021/ic00046a018
PDF
Site selectivity studies on heterobimetallic complexes: substitution reactions of (.eta.5-C5H5)MM'(CO)8 (M = Mo, W; M' = Mn, Re)
Wayne L. Ingham and Neil J. Coville
pp 4084 - 4090; DOI:
10.1021/ic00046a019
PDF
Photochemical generation of a reactive rhenium(III) oxo complex and its curious mode of cleavage of dioxygen
Seth N. Brown and James M. Mayer
pp 4091 - 4100; DOI:
10.1021/ic00046a020
PDF
Physical and photophysical properties of rhenium(I) tetracarbonyl complexes
Randy J. Shaver and D. Paul Rillema
pp 4101 - 4107; DOI:
10.1021/ic00046a021
PDF
IR spectroelectrochemical investigation of the disproportionation of bis(benzenemethanethiolato)octacarbonylditungstate(2-)
Michael G. Hill, Laurence D. Rosenhein, Kent R. Mann, Xi Hai Mu, and Franklin A. Schultz
pp 4108 - 4111; DOI:
10.1021/ic00046a022
PDF
Photoinduced process in dyads and triads: an osmium(II)-bis(terpyridine) photosensitizer covalently linked to electron donor and acceptor groups
Jean Paul Collin, Stephane Guillerez, Jean Pierre Sauvage, Francesco Barigelletti, Luisa De Cola, Lucia Flamigni, and Vincenzo Balzani
pp 4112 - 4117; DOI:
10.1021/ic00046a023
PDF
Delocalization mechanism of ferromagnetic exchange interactions in complexes of copper(II) with nitroxyl radicals
R. N. Musin, P. V. Schastnev, and S. A. Malinovskaya
pp 4118 - 4121; DOI:
10.1021/ic00046a024
PDF
The near-infrared spectrum of the guanidinium ion: a local-mode analysis
Ian M. Walker and Paul J. McCarthy
pp 4122 - 4127; DOI:
10.1021/ic00046a025
PDF
Syntheses and multinuclear NMR characterizations of .alpha.-[SiMo2W9O39]8- and .alpha.-[SiMo3-xVxW9O40](4+x)- (x = 1, 2) heteropolyoxometalates
Emmanuel Cadot, Rene Thouvenot, Andre Teze, and Gilbert Herve
pp 4128 - 4133; DOI:
10.1021/ic00046a026
PDF
Synthesis and structural characterization of low-valent Group V phosphine complexes
John D. Protasiewicz, Patricia A. Bianconi, Ian D. Williams, Shuncheng Liu, C. Pulla Rao, and Stephen J. Lippard
pp 4134 - 4142; DOI:
10.1021/ic00046a027
PDF
Preparation and structural characterization of dioxane-coordinated alkali metal bis(trimethylsilyl)amides
Frank T. Edelmann, Frank Pauer, Michael Wedler, and Dietmar Stalke
pp 4143 - 4146; DOI:
10.1021/ic00046a028
PDF
Bis(trifluoromethyl)trisulfane, CF3SSSCF3, and bis(trifluoromethyl)tetrasulfane, CF3SSSSCF3: simple syntheses, spectroscopic data, and gas-phase structures
Marcus Gaensslen, Rolf Minkwitz, Walter Molzbeck, and Heinz Oberhammer
pp 4147 - 4150; DOI:
10.1021/ic00046a029
PDF
High-pressure NMR kinetics. 55. Mechanisms of axial and equatorial dimethyl sulfoxide exchange on pentakis(dimethyl sulfoxide) oxotitanium(2+). A variable-temperature and -pressure proton NMR study
Ivo Dellavia, Lothar Helm, and Andre E. Merbach
pp 4151 - 4154; DOI:
10.1021/ic00046a030
PDF
Hydrolytic oligomers of rhodium(III): a multinuclear NMR study of the doubly hydroxo-bridged dimer and trimer in aqueous solution
Michael C. Read, Julius Glaser, Magnus Sandstroem, and Imre Toth
pp 4155 - 4159; DOI:
10.1021/ic00046a031
PDF
Photosensitization of tetrakis(amine)rhodium(III) complexes [Rh(L)4XY]+
Mariel M. Muir and Hector M. Torres
pp 4160 - 4163; DOI:
10.1021/ic00046a032
PDF
Effect of pH on the kinetics and thermodynamics of oxygen coordination to a macrocyclic cobalt(II) complex
Adam Marchaj, Andreja Bakac, and James H. Espenson
pp 4164 - 4168; DOI:
10.1021/ic00046a033
PDF
Some general conditions for hidden Fermi surface nesting
M. H. Whangbo, J. Ren, W. Liang, E. Canadell, J. P. Pouget, S. Ravy, J. M. Williams, and M. A. Beno
pp 4169 - 4173; DOI:
10.1021/ic00046a034
PDF
Infrared and mass spectroscopic study of the reaction of silyl iodide and ammonia. Infrared spectrum of silylamine
David B. Beach
pp 4174 - 4177; DOI:
10.1021/ic00046a035
PDF
Thermodynamics and structures of nickel(II) chloro complexes in N,N-dimethylacetamide
Honoh Suzuki and Shinichi Ishiguro
pp 4178 - 4183; DOI:
10.1021/ic00046a036
PDF
Organotin clusters. 7. Polynuclear chlorine containing organooxotin clusters
K. C. Kumara Swamy, Roberta O. Day, and Robert R. Holmes
pp 4184 - 4193; DOI:
10.1021/ic00046a037
PDF
Transition metal complexes of the novel tridentate di-2-pyridylmethanamine (dipa)
Paul V. Bernhardt, Peter Comba, Anne Mahu-Rickenbach, Sandra Stebler, Silvio Steiner, Katalin Varnagy, and Margareta Zehnder
pp 4194 - 4200; DOI:
10.1021/ic00046a038
PDF
Occurrence of hydrogen single bridges in main group chemistry
Gabin Treboux and Georges Trinquier
pp 4201 - 4202; DOI:
10.1021/ic00046a039
PDF
Complexes with functional phosphines. 20. Synthesis of iron complexes with keto phosphine ligands and crystal structure of the bis(phosphino enolato) complex cis-Fe[Ph2PCH.cntdot..cntdot..cntdot.C(.cntdot..cntdot..cntdot.O)Ph]2(CO)2
Pierre Braunstein, Silverio Coco Cea, Andre DeCian, and Jean Fischer
pp 4203 - 4206; DOI:
10.1021/ic00046a040
PDF
Strategy for synthesis of an yttrium/copper(I) complex with an oxo ligand environment
Paul S. Coan, John C. Huffman, and Kenneth G. Caulton
pp 4207 - 4209; DOI:
10.1021/ic00046a041
PDF
Reactions at metal-bound nitrogen atoms. Formation of chloroimido complexes from tungsten phosphoraniminato complexes
Joseph D. Lichtenhan, Joseph W. Ziller, and Nancy M. Doherty
pp 4210 - 4212; DOI:
10.1021/ic00046a042
PDF

Issue 21


Introduction of diphenylphosphinite functional groups onto selected positions on the lower rim of calix[4]arenes and calix[6]arenes
Justin K. Moran and D. Max Roundhill
pp 4213 - 4215; DOI:
10.1021/ic00047a001
PDF
Models of the cytochromes b. 10. Application of proton COSY to delineate the spin density distribution at the pyrrole .beta. positions of unsymmetrically substituted low-spin iron(III) tetraphenylporphyrins
Qing Lin, Ursula Simonis, Alicia Rene Tipton, Cynthia J. Norvell, and F. Ann Walker
pp 4216 - 4217; DOI:
10.1021/ic00047a002
PDF
Sulfur-hydrogen and sulfur-sulfur oxidative addition to low-valent vanadium: synthesis and structure of monocyclopentadienyl- and dicyclopentadienylvanadium dithiolate derivatives
Douglas W. Stephan
pp 4218 - 4223; DOI:
10.1021/ic00047a003
PDF
Halide nucleophilic attack on the [(.eta.5-C5R5)Re(CO)2(NO)]+ cations: (.eta.5-C5R5)Re(CO)(NO)X and [fac-X3Re(CO)2(NO)]- formation through competitive loss of carbon monoxide and (.eta.5-C5R5) (R = H, CH3)
John L. Hubbard, Kirk L. Kimball, Robert M. Burns, and Vivienne Sum
pp 4224 - 4230; DOI:
10.1021/ic00047a004
PDF
Heteroatomic chelation of mixed phosphine (or arsine) and phosphine oxide ligands with rhenium(V). Synthesis, characterization, and x-ray structural investigations of new rhenium(V) metallacyclic compounds: (O)PPh2(CH2)nEPh2Re(O)Cl3 (E = P, As)
Kattesh V. Katti and Charles L. Barnes
pp 4231 - 4235; DOI:
10.1021/ic00047a005
PDF
Phosphine and phosphite complexes of a coordinatively unsaturated triplatinum hydride: structure of [Pt3(.mu.3-H)(.mu.-Ph2PCH2PPh2)3{P(OMe)3}]PF6
Ravindranath Ramachandran, Dong Sheng Yang, Nicholas C. Payne, and Richard J. Puddephatt
pp 4236 - 4240; DOI:
10.1021/ic00047a006
PDF
The barrier to rotation of the dihydrogen ligand in the complexes [MH(.eta.2-H2)PP3]BPh4 (M = iron, ruthenium): evidence for stronger back-donation in the iron complex
Juergen Eckert, Alberto Albinati, Ross P. White, Claudio Bianchini, and M. Peruzzini
pp 4241 - 4244; DOI:
10.1021/ic00047a007
PDF
Synthesis and spectroscopic characterization of ruthenium(II) .eta.2-dihydrogen complexes of the type [RuH(.eta.2-H2)(L)(triphos)]+ (L = CO, P(OCH2)3CEt, PMe2Ph; triphos = PPh(CH2CH2PPh2)2)
Demetrius Michos, Xiao Liang Luo, and Robert H. Crabtree
pp 4245 - 4250; DOI:
10.1021/ic00047a008
PDF
New procedures for the synthesis of mixed-metal and/or mixed-ligand ruthenium(II) and osmium(II) polypyridine supramolecules and the use of these procedures in the preparation of hexanuclear species
Scolastica Serroni and Gianfranco Denti
pp 4251 - 4255; DOI:
10.1021/ic00047a009
PDF
A metal-to-ligand charge-transfer excited state of a biruthenium(II) compound bridged by 2,6-bis(2-pyridyl)benzodiimidazole
Takeshi Ohno, Koichi Nozaki, and Masaaki Haga
pp 4256 - 4261; DOI:
10.1021/ic00047a010
PDF
Transition metal polyhydride complexes. 4. Highly stable nonclassical isomers with octahedral structures
Zhenyang Lin and Michael B. Hall
pp 4262 - 4265; DOI:
10.1021/ic00047a011
PDF
Bonding and structure in L4M2(.mu.-XRn)2 diamonds of tetrahedral d10 ions. Effect of substituents on the M- -M interaction
Pere Alemany and Santiago Alvarez
pp 4266 - 4275; DOI:
10.1021/ic00047a012
PDF
Theoretical study of the electronic properties of niobium iodide sulfide (Nb6I9S) and its hydride (Nb6(H)I9S)
H. Juergen Meyer and John D. Corbett
pp 4276 - 4280; DOI:
10.1021/ic00047a013
PDF
Nitrogen-15 solid-state NMR study of ligands in platinum mixed-valence complexes
Elliot J. W. Austin, Patrick J. Barrie, and Robin J. H. Clark
pp 4281 - 4285; DOI:
10.1021/ic00047a014
PDF
A bonding-reactivity relationship for (carbon dioxide)bis(tricyclohexylphosphine)nickel: a comparative solid-state-solution nuclear magnetic resonance study (phosphorus-31, carbon-13) as a diagnostic tool to determine the mode of bonding of carbon dioxide to a metal center
Michele Aresta, Roberto Gobetto, Eugenio Quaranta, and Immacolata Tommasi
pp 4286 - 4290; DOI:
10.1021/ic00047a015
PDF
NMR study of solution structures and dynamics of lanthanide(III) complexes of DOTA
Silvio Aime, Mauro Botta, and Giuseppe Ermondi
pp 4291 - 4299; DOI:
10.1021/ic00047a016
PDF
Reactivity of bis(aryl)(octaethylporphyrinato)ruthenium complexes in extreme oxidation states
Jeffery W. Seyler, Lance K. Safford, and Charles R. Leidner
pp 4300 - 4307; DOI:
10.1021/ic00047a017
PDF
Complexes of vanadium(III) and vanadium(IV) containing bipyridine and tetrachlorocatecholate ligands. Insights into the tunicate vanadium(III) coordination environment
Cathy L. Simpson and Cortlandt G. Pierpont
pp 4308 - 4313; DOI:
10.1021/ic00047a018
PDF
pH-dependent coordination mode of new bleomycin synthetic analogs with copper(II), iron(II), and zinc(II)
Eiichi Kimura, Hiromasa Kurosaki, Yasuhisa Kurogi, Mitsuhiko Shionoya, and Motoo Shiro
pp 4314 - 4321; DOI:
10.1021/ic00047a019
PDF
Reactions of dioxygen (O2) with mononuclear copper(I) complexes: temperature-dependent formation of peroxo- or oxo- (and dihydroxo-) bridged dicopper(II) complexes
Indrajit Sanyal, Mohammad Mahroof-Tahir, M. Sarwar Nasir, Phalguni Ghosh, Brett I. Cohen, Yilma Gultneh, Richard W. Cruse, Amjad Farooq, Kenneth D. Karlin, and et al.
pp 4322 - 4332; DOI:
10.1021/ic00047a020
PDF
Group 5 tetrathiometalates: simplified syntheses and structures
Sonny C. Lee, Jiguo Li, Jason C. Mitchell, and R. H. Holm
pp 4333 - 4338; DOI:
10.1021/ic00047a021
PDF
Molybdenum(VI)-copper(II) Schiff-base chain complexes having Cu2Mo2O4 cubane-like cores. Synthesis, crystal structure, and magnetic properties of [Cu2Mo2O4(SALADHP)2(MeO)2.cntdot.2CH3CN]n [H3SALADHP = 1,3-dihydroxy-2-methyl-2-(salicylideneamino)propane]
Dimitris P. Kessissoglou, Catherine P. Raptopoulou, Evangelos G. Bakalbassis, Aris Terzis, and Jerzy Mrozinski
pp 4339 - 4345; DOI:
10.1021/ic00047a022
PDF
Structural, spectroscopic, and electrochemical investigation of luminescent bimetallic complexes of rhenium(I)
Rongguang Lin, Yigang Fu, Carolyn P. Brock, and Thomas F. Guarr
pp 4346 - 4353; DOI:
10.1021/ic00047a023
PDF
Synthesis of transannular- and spiro-substituted cyclotriphosphazenes: x-ray crystal structures of 1,1-[N3P3(OCH2CF3)4{O2C12H8}], 1,3-[N3P3(OCH2CF3)4{O2C12H8}], 1,1-[N3P3(OCH2CF3)4{O2C10H6}], and 1,3-[N3P3(OCH2CF3)4}O2C10H6}]
Harry R. Allcock, Michael L. Turner, and Karyn B. Visscher
pp 4354 - 4364; DOI:
10.1021/ic00047a024
PDF
Interactions of coinage-group cations with the tetraselenotungstate anion: multinuclear NMR spectroscopic results and crystal structures of (.mu.-WSe4)[(PMe2Ph)2Cu]2, (.mu.-WSe4)[(PMePh2)Au]2, and (.mu.3-Cl)(.mu.3-WSe4)[(PPh3)Cu]3
Christopher C. Christuk, Mohammad A. Ansari, and James A. Ibers
pp 4365 - 4369; DOI:
10.1021/ic00047a025
PDF
Synthesis and structure of trinuclear and novel tetranuclear gold(I) complexes derived from 8-aminoquinoline
Hubert Schmidbaur, Andreas Kolb, and Peter Bissinger
pp 4370 - 4375; DOI:
10.1021/ic00047a026
PDF
Synthesis and spectroscopic properties of the encapsulated cobalt(III) complexes derived from the unsymmetrically substituted ligand 5-methyl-5-(4-amino-2-azabutyl)-3,7-dithianonane-1,9-diamine (N4S2)
Therese M. Donlevy, Lawrence R. Gahan, Trevor W. Hambley, and Robert Stranger
pp 4376 - 4382; DOI:
10.1021/ic00047a027
PDF
Factors affecting reaction pathways in nucleophilic substitution reactions on platinum(II) complexes: a comparative kinetic and theoretical study
Raffaello Romeo, Antonio Grassi, and Luigi Monsu Scolaro
pp 4383 - 4390; DOI:
10.1021/ic00047a028
PDF
Metal-phosphine bonding revisited. .sigma.-Basicity, .pi.-acidity, and the role of phosphorus d orbitals in zerovalent metal-phospine complexes
Gianfranco Pacchioni and Paul S. Bagus
pp 4391 - 4398; DOI:
10.1021/ic00047a029
PDF
Effect of the porphyrin macrocycle on the spectroscopic properties and catalytic activity of electroreduced nickel(II) porphyrins
K. M. Kadish, M. M. Franzen, B. C. Han, C. Araullo-McAdams, and D. Sazou
pp 4399 - 4403; DOI:
10.1021/ic00047a030
PDF
Models for peroxidase compound I: generation and spectroscopic characterization of new oxoferryl porphyrin .pi. cation radical species
D. Mandon, R. Weiss, K. Jayaraj, A. Gold, J. Terner, E. Bill, and A. X. Trautwein
pp 4404 - 4409; DOI:
10.1021/ic00047a031
PDF
Linkage isomerism in square-planar complexes of platinum and palladium with histidine and derivatives
Trevor G. Appleton, Ferdinand J. Pesch, Markus Wienken, Stephan Menzer, and Bernhard Lippert
pp 4410 - 4419; DOI:
10.1021/ic00047a032
PDF
Synthesis of difluorophosphoranes from phosphines and mercuric fluoride
Kenneth M. Doxsee, Erin M. Hanawalt, and Timothy J. R. Weakley
pp 4420 - 4421; DOI:
10.1021/ic00047a033
PDF
Optimized synthesis, structure, and solution dynamics of 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis(methylenephosphonic acid) (H8DOTP)
Istvan Lazar, Duane C. Hrncir, Won Dae Kim, Garry E. Kiefer, and A. Dean Sherry
pp 4422 - 4424; DOI:
10.1021/ic00047a034
PDF
Application of photoelectron spectroscopy to molecular properties. 46. Gas-phase structure and stability of alkynylphosphines and allenylphosphines: photoelectronic study
S. Lacombe, W. Dong, G. Pfister-Guillouzo, J. C. Guillemin, and J. M. Denis
pp 4425 - 4427; DOI:
10.1021/ic00047a035
PDF
A copper(I) complex with chelating 1,5-hexadiene
Thomas Nickel, Klaus Richard Poerschke, Richard Goddard, and Carl Krueger
pp 4428 - 4430; DOI:
10.1021/ic00047a036
PDF
Multiple bonds between main-group elements and transition metals. 113. Simple and efficient synthesis of methyltrioxorhenium(VII): a general method
Wolfgang A. Herrmann, Fritz E. Kuehn, Richard W. Fischer, Werner R. Thiel, and Carlos C. Romao
pp 4431 - 4432; DOI:
10.1021/ic00047a037
PDF

Issue 22


Two-dimensional proton NMR studies of the paramagnetic metalloenzyme copper-nickel superoxide dismutase
Ivano Bertini, Claudio Luchinat, Li June Ming, Mario Piccioli, Marco Sola, and Joan Selverstone Valentine
pp 4433 - 4435; DOI:
10.1021/ic00048a001
PDF
A new fluorinated tetraalkoxide ligand derived from the hydration of hexafluoroacetylacetone
Elisabeth Bouwman, John C. Huffman, Emil B. Lobkovsky, George Christou, Hui Lien Tsai, and David N. Hendrickson
pp 4436 - 4438; DOI:
10.1021/ic00048a002
PDF
Intermolecular and intramolecular excited-state electron transfer involving electrode-confined rhenium carbonyl complexes: toward molecule-based systems for light absorption, charge separation, and optical energy conversion
Charles S. Christ, Jie Yu, Xiaohong Zhao, G. Tayhas R. Palmore, and Mark S. Wrighton
pp 4439 - 4440; DOI:
10.1021/ic00048a003
PDF
Solution fluorescence and photoredox reactions of molybdenum(V) oxo complexes
Abdul K. Mohammed and Andrew W. Maverick
pp 4441 - 4443; DOI:
10.1021/ic00048a004
PDF
Structural and mechanistic investigation probing ligand substitution of nonacarbonylhydridohydridoditungsten
Jiann T. Lin, Ping S. Huang, Thamas Y. R. Tsai, Ching Yi Liao, Li Hong Tseng, Yuh S. Wen, and Fong Ku Shi
pp 4444 - 4452; DOI:
10.1021/ic00048a005
PDF
Addition and cycloaddition reactions of the nucleophilic oxo and sulfido complexes [tmtaa]Ti:X (X = O, S; tmtaa = dianion of 7,16-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine)
Chris E. Housmekerides, David L. Ramage, Christine M. Kretz, John T. Shontz, Robert S. Pilato, Gregory L. Geoffroy, Arnold L. Rheingold, and Brian S. Haggerty
pp 4453 - 4468; DOI:
10.1021/ic00048a006
PDF
The tungsten-tungsten triple bond. 19. Preparation and characterization of W26+-containing compounds supported by amide/alkoxide and trifluoromethanesulfonate ligands
M. H. Chisholm, K. S. Kramer, J. D. Martin, J. C. Huffman, E. B. Lobkovsky, and W. E. Streib
pp 4469 - 4474; DOI:
10.1021/ic00048a007
PDF
Structural and reactivity studies of a cyanoacetic acid derivative of tungsten pentacarbonyl. X-ray structure of W(CO)5NCCH2COOH
Donald J. Darensbourg, Earl V. Atnip, and Joseph H. Reibenspies
pp 4475 - 4480; DOI:
10.1021/ic00048a008
PDF
Preparation and properties of molybdenum and tungsten dinitrogen complexes. 38. Hydrido-carbonato, hydrido-carbamato, and carbon dioxide complexes of tungsten derived from the carbonyl-dinitrogen complex trans-[W(CO)(N2)(Ph2PCH2CH2PPh2)2]
Toyohisa Ishida, Tetsuya Hayashi, Yasushi Mizobe, and Masanobu Hidai
pp 4481 - 4485; DOI:
10.1021/ic00048a009
PDF
Reactions of the electronically unsaturated polyhydride tris[.mu.-bis(dimethylphosphino)methane]-.mu.-hydridotetrahydridodirhenium hexafluorophosphate with carbon monoxide and isocyanide ligands. Isolation and structural characterization of complexes of composition [Re2H5-nLn(.mu.-dmpm)3]PF6 (n = 2 or 4; L = CO or RNC)
Karen E. Meyer, Phillip E. Fanwick, and Richard A. Walton
pp 4486 - 4491; DOI:
10.1021/ic00048a010
PDF
Facile and quantitative activation of dihydrogen by the phosphinidene-stabilized ruthenium cluster Ru4(CO)13(.mu.3-PPh): synthesis and spectroscopic and structural characterization of (.mu.-H)2Ru4(CO)12(.mu.3-PPh)
Francoise Van Gastel, John F. Corrigan, Simon Doherty, Nicholas J. Taylor, and Arthur J. Carty
pp 4492 - 4498; DOI:
10.1021/ic00048a011
PDF
Isomerization, photoreaction, and structure studies of osmium complexes containing carboxamido and halide ligands
Kuang Lieh Lu, Huiyue Lo, Ying Chih Lin, and Yu Wang
pp 4499 - 4502; DOI:
10.1021/ic00048a012
PDF
Synthesis and characterization of volatile monomeric copper(II) fluoroalkoxides
Patrick M. Jeffries, Scott R. Wilson, and Gregory S. Girolami
pp 4503 - 4509; DOI:
10.1021/ic00048a013
PDF
Metal-metal cooperation via 1,1'-bis(diphenylphosphino)ferrocene (dppf). 1. Structurally distinctive silver(I) dppf complexes of nitrato and carboxylato ligands in variable coordination modes. Crystal structures of [Ag(NO3)(dppf)]2.cntdot.2CHCl3, [Ag2(HCO2)2(dppf)3].cntdot.2CH2Cl2, [Ag2(CH3CO2)2(dppf)]2, and Ag2(C6H5CO2)2(dppf)
T. S. Andy Hor, Soh Ping Neo, Chee Siong Tan, Thomas C. W. Mak, Kevin W. P. Leung, and Ru Ji Wang
pp 4510 - 4516; DOI:
10.1021/ic00048a014
PDF
Preparation and characterization of (tetrabenzoporphyrinato)cobalt(II) iodide, a ring-oxidized molecular conductor
Kwangkyoung Liou, Timothy P. Newcomb, Michael D. Heagy, Julia A. Thompson, William B. Heuer, Ronald L. Musselman, Claus S. Jacobsen, Brian M. Hoffman, and James A. Ibers
pp 4517 - 4523; DOI:
10.1021/ic00048a015
PDF
Kinetic studies of the aquopentaamminecobalt(III)/- and aquopentaamminechromium(III)/hydrogen chromate complexation reaction
Michael R. Grace and Peter A. Tregloan
pp 4524 - 4529; DOI:
10.1021/ic00048a016
PDF
Spectroscopic evidence for selenium iodides in carbon disulfide solution: Se3I2, Se2I2, and SeI2
Madhuban Gopal and John Milne
pp 4530 - 4533; DOI:
10.1021/ic00048a017
PDF
Exchange processes in diselenium and selenium-sulfur dihalides, Se2X2 and SeSX2 (X = Br, Cl). A selenium-77 2D-EXSY study
John Milne and Antony J. Williams
pp 4534 - 4538; DOI:
10.1021/ic00048a018
PDF
Photooxidation of dichloro- and dibromoaurate(1-) induced by ds excitation
Horst Kunkely and Arnd Vogler
pp 4539 - 4541; DOI:
10.1021/ic00048a019
PDF
A new nickel(II) cyclam (cyclam = 1,4,8,11-tetraazacyclotetradecane) complex covalently attached to tris(1,10-phenanthroline)ruthenium(2+). A new candidate for the catalytic photoreduction of carbon dioxide
Eiichi Kimura, Xianhe Bu, Mitsuhiko Shionoya, Senji Wada, and Shinobu Maruyama
pp 4542 - 4546; DOI:
10.1021/ic00048a020
PDF
Exchange reaction of bridging acetate ligands and reversible electrophilic rhodium-carbon activation in ortho-metalated rhodium(II) compounds with acetic acid. Kinetic study of the exchange reaction of acetates with acetic acid-d4 in the compound Rh2(O2CCH3)3[(C6H4)P(C6H5)2].cntdot.2HO2CCH3
P. Lahuerta and E. Peris
pp 4547 - 4551; DOI:
10.1021/ic00048a021
PDF
Ligand effects on the redox chemistry of (oxo)(phosphine)ruthenium(IV) complexes: oxidation of alcohols
James G. Muller, John Henry Acquaye, and Kenneth J. Takeuchi
pp 4552 - 4557; DOI:
10.1021/ic00048a022
PDF
Effect of alkali-metal cations on the chemistry of aqueous silicate solutions
Stephen D. Kinrade and David L. Pole
pp 4558 - 4563; DOI:
10.1021/ic00048a023
PDF
Low-temperature emission and absorption spectra of trans- and cis-diammine(1,4,8,11-tetraazacyclotetradecane)chromium(III) salts
Alexander D. Kirk and Hans U. Guedel
pp 4564 - 4569; DOI:
10.1021/ic00048a024
PDF
Moessbauer spectroscopy and magnetization studies of .alpha.- and .beta.-ruthenium trichloride
Y. Kobayashi, T. Okada, K. Asai, M. Katada, H. Sano, and F. Ambe
pp 4570 - 4574; DOI:
10.1021/ic00048a025
PDF
Geometry, electronic structure, and coordination ability of (diiminoethane)bis(phosphine)copper(1+) at the lowest energy triplet metal-to-ligand charge-transfer excited state. A theoretical study
Shigeyoshi Sakaki, Hiroki Mizutani, and Yuichi Kase
pp 4575 - 4581; DOI:
10.1021/ic00048a026
PDF
Electrochemistry in liquid sulfur dioxide. 11. Oxidation of tris(2,2'-bipyridine)nickel(2+) and spectroscopy and isolation of products
Jerzy B. Chlistunoff and Allen J. Bard
pp 4582 - 4587; DOI:
10.1021/ic00048a027
PDF
Transition metal chemistry of main group hydrazides. 1. Synthesis and characterization of cyclometallaphosphohydrazides of cobalt(I), copper(I), and palladium(II). X-ray structures of cobalt(I) and palladium(II) representatives
Kattesh V. Katti, Prahlad R. Singh, and Charles L. Barnes
pp 4588 - 4593; DOI:
10.1021/ic00048a028
PDF
General synthesis of iron(III) tetrathiolate complexes. Structural and spectroscopic models for the [Fe(Cys-S)4] center in oxidized rubredoxin
Lynn E. Maelia, Michelle Millar, and Stephen A. Koch
pp 4594 - 4600; DOI:
10.1021/ic00048a029
PDF
Hydrido mercapto and bis(mercapto) derivatives of ruthenium(II) phosphine complexes
Philip G. Jessop, Chung Li Lee, Golnar Rastar, Brian R. James, Colin J. L. Lock, and Romolo Faggiani
pp 4601 - 4605; DOI:
10.1021/ic00048a030
PDF
Synthesis and reactivity of ruthenatetraboranes: molecular structure of [RuH(B3H8)(CO)(PPh3)2]
Nathaniel W. Alcock, Ian D. Burns, Kanwaljit S. Claire, and Anthony F. Hill
pp 4606 - 4610; DOI:
10.1021/ic00048a031
PDF
Synthesis and characterization of bis(2-pyridylmethyl)amine complexes of manganese(II), zinc(II), and cadmium(II)
Joergen Glerup, Patricia A. Goodson, Derek J. Hodgson, Kirsten Michelsen, Karen Margrethe Nielsen, and Hoegni Weihe
pp 4611 - 4616; DOI:
10.1021/ic00048a032
PDF
Lariat-type B12 model complexes. 2. Ligand-responsive NMR trends of pendant methylpyridyl Costa-type organocobalt complexes
Luigi G. Marzilli, Alessandra Gerli, and Antonia M. Calafat
pp 4617 - 4627; DOI:
10.1021/ic00048a033
PDF
Unusual structural features of tetrakis(.mu.-carboxylato)dirhodium(II), an antitumor agent, bound to azathioprine, a biologically active mercaptopurine derivative
H. T. Chifotides, K. R. Dunbar, J. H. Matonic, and N. Katsaros
pp 4628 - 4634; DOI:
10.1021/ic00048a034
PDF
Dinuclear copper(II) and polymeric tetranuclear copper(II) and copper(II)-copper(I) complexes of macrocyclic ligands capable of forming endogenous alkoxide and phenoxide bridges. Structural, magnetic, and electrochemical studies
Santokh S. Tandon, Laurence K. Thompson, John N. Bridson, Vickie McKee, and Alison J. Downard
pp 4635 - 4642; DOI:
10.1021/ic00048a035
PDF
Oxygen and chlorine atom transfer between tungsten, molybdenum, and rhenium complexes. Competition between one- and two-electron pathways
Diana E. Over, Susan C. Critchlow, and James M. Mayer
pp 4643 - 4648; DOI:
10.1021/ic00048a036
PDF
Redox chemistry of superoxide dismutase. Cyclic voltammetry of wild-type enzymes and mutants on functionally relevant residues
H. A. Azab, L. Banci, M. Borsari, C. Luchinat, M. Sola, and M. S. Viezzoli
pp 4649 - 4655; DOI:
10.1021/ic00048a037
PDF
Reactions of unsymmetrically substituted derivatives of cisplatin with short oligodeoxynucleotides containing a -GpG- sequence: H-bonding interactions in pGpG moieties cross-linked by an asymmetric platinum complex enhancing the formation of one geometrical isomer
M. J. Bloemink, R. J. Heetebrij, K. Inagaki, Y. Kidani, and J. Reedijk
pp 4656 - 4661; DOI:
10.1021/ic00048a038
PDF
Catalysis of copper(II)-NaZSM-5 zeolites during benzyl alcohol oxidation
Masakazu Nakao, Satoru Nishiyama, Shigeru Tsuruya, and Mitsuo Masai
pp 4662 - 4668; DOI:
10.1021/ic00048a039
PDF
The aqueous hexacyanoferrate(II/III) self-exchange reaction at high pressures
Hideo Takagi and Thomas W. Swaddle
pp 4669 - 4673; DOI:
10.1021/ic00048a040
PDF
Kinetics of reactions of aqueous iron(III) ions with azide and thiocyanate at high pressures
Michael R. Grace and Thomas W. Swaddle
pp 4674 - 4678; DOI:
10.1021/ic00048a041
PDF
Framework alkali metal zinc orthoborates: AZn4(BO3)3 (A = K, Rb, Cs)
Robert W. Smith, Jeanne L. Luce, and Douglas A. Keszler
pp 4679 - 4682; DOI:
10.1021/ic00048a042
PDF
Preparation, characterization, and oxygen-17 NMR kinetic studies of analogous technetium(V) and rhenium(V) complexes which contain a seven-membered chelate ring. Single-crystal structure analyses of [Ph4P][TcO(DBDS)] and [Ph4As][ReO(DBDS)], where DBDS is N,N'-bis(mercaptoacetyl)butane-1,4-diamine
Baohe Chen, Mary Jane Heeg, and Edward Deutsch
pp 4683 - 4690; DOI:
10.1021/ic00048a043
PDF
Raman evidence for the formation of a monoaquo adduct of iron(II) tetrakis((N-tert-butylcarbamoyl)phenyl)porphyrin. A model for hemoproteins at low pH
Leonin Leondiadis, Michel Momenteau, and Alain Desbois
pp 4691 - 4696; DOI:
10.1021/ic00048a044
PDF
Electrochemistry of planar cobalt(II) and nickel(II) tetraaza[14]annulene complexes
Peter J. Lukes, Alan C. McGregor, Thomas Clifford, and Joe A. Crayston
pp 4697 - 4699; DOI:
10.1021/ic00048a045
PDF
Electrophilic attack on dinuclear iridium complexes by halogens. Structure of [Ir2I2(.mu.-I)(CO)2(.mu.-Ph2PCH2PPh2)2]I.cntdot.2CHCl3
Alessandra Crispini, Giovanni De Munno, Mauro Ghedini, and Francesco Neve
pp 4700 - 4703; DOI:
10.1021/ic00048a046
PDF
X-ray photoelectron spectroscopy of a series of heterometallic gold-platinum phosphine cluster compounds
Yu. M. Shul'ga, A. V. Bulatov, Rachael A. T. Gould, Wayde V. Konze, and Louis H. Pignolet
pp 4704 - 4706; DOI:
10.1021/ic00048a047
PDF
Isolation and x-ray crystal structure of (phenylselenito)triphenyltin: the first example of an organotin ester of phenylseleninic acid
V. Chandrasekhar, M. G. Muralidhara, K. R. Justin Thomas, and Edward R. T. Tiekink
pp 4707 - 4708; DOI:
10.1021/ic00048a048
PDF
Silane alcoholysis by a nickel(II) complex in a N, O, S ligand environment
Daniel E. Barber, Zheng Lu, Thomas Richardson, and Robert H. Crabtree
pp 4709 - 4711; DOI:
10.1021/ic00048a049
PDF
Properties and reactivity of metallocarboxylates. Crystal and molecular structure of the -CO22--bridged "polymer" {[CoIII(en)2(CO2)](ClO4).cntdot.H2O}n
David J. Szalda, Mei H. Chou, Etsuko Fujita, and Carol Creutz
pp 4712 - 4714; DOI:
10.1021/ic00048a050
PDF

Issue 23


Synthesis of [Mo4S6(SH)2(PMe3)6] and [Mo6S10(SH)2(PEt3)6] consisting of fused molybdenum-sulfur Mo3(.mu.3-S) cluster units
Kiyoshi Tsuge, Hideo Imoto, and Taro Saito
pp 4715 - 4716; DOI:
10.1021/ic00049a001
PDF
Origin and relevance of the staggering in one-dimensional molecular metals. A density functional study of metallophthalocyanine model dimers
A. Rosa and E. J. Baerends
pp 4717 - 4726; DOI:
10.1021/ic00049a002
PDF
Preparation and characterization of hydroxysilicoaluminum pillared clays
Dongyuan Zhao, Yashu Yang, and Xiexian Guo
pp 4727 - 4732; DOI:
10.1021/ic00049a003
PDF
Electron-diffraction study of gaseous pentakis(dimethylamido)tantalum(V), Ta(NMe2)5
Kolbjoern Hagen, Catherine J. Holwill, David A. Rice, and Jonathan D. Runnacles
pp 4733 - 4736; DOI:
10.1021/ic00049a004
PDF
Electronic properties of palladium ternary hydrides A2PdH2 (A = lithium, sodium)
R. V. Kasowski, D. Noreus, L. Wang, and M. H. Whangbo
pp 4737 - 4739; DOI:
10.1021/ic00049a005
PDF
Investigations on solid chlorine dioxide: temperature-dependent crystal structure, IR spectrum, and magnetic susceptibility
Anette Rehr and Martin Jansen
pp 4740 - 4742; DOI:
10.1021/ic00049a006
PDF
Hydrothermal synthesis and structural characterization of four layered vanadyl(IV) phosphate hydrates A(VO)2(PO4)2.cntdot.4H2O (A = Co, Ca, Sr, Pb)
H. Y. Kang, W. C. Lee, S. L. Wang, and K. H. Lii
pp 4743 - 4748; DOI:
10.1021/ic00049a007
PDF
Synthesis, crystal structure, electrochemical, and spectroelectrochemical properties of the new manganese(III) complex [MnIII(BBPEN)][PF6] [H2BBPEN = N,N'-bis(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)ethylenediamine]
Ademir Neves, Sueli M. D. Erthal, Ivo Vencato, Augusto S. Ceccato, Yvonne P. Mascarenhas, Otaciro R. Nascimento, Manfredo Horner, and Alzir A. Batista
pp 4749 - 4755; DOI:
10.1021/ic00049a008
PDF
Is the metal-metal bond length in decacarbonylmanganeserhenium anomalous? X-ray crystal structure determination of MnRe(CO)9L (L = tert-BuNC, P(CH2C6H5)3) and MnRe(CO)8(CNBu-tert) (PPh3)
Ann E. Leins, David G. Billing, Demetrius C. Levendis, Johan Du Toit, and Neil J. Coville
pp 4756 - 4761; DOI:
10.1021/ic00049a009
PDF
Crystal structure and high-pressure micro-Raman spectra of tricarbonyl(.eta.5-pentamethylcyclopentadienyl)rhenium(I), (.eta.5-C5Me5)Re(CO)3
Yining Huang, Ian S. Butler, and Denis F. R. Gilson
pp 4762 - 4765; DOI:
10.1021/ic00049a010
PDF
Structure and optical spectroscopy of bis(2-phenylpyridine)(2,2'-bipyridine) rhodium hexafluorophosphate and related complexes
Gabriela Frei, Arne Zilian, Andrea Raselli, Hans U. Guedel, and Hans Beat Buergi
pp 4766 - 4773; DOI:
10.1021/ic00049a011
PDF
A novel mixed-valence selenium(IV)/selenium(VI) oxo compound: crystal structure determination and x-ray absorption near edge structure study of erbium selenite(IV) selenate(VI) hydrate, Er(SeO3)(SeO4)1/2.cntdot.H2O
Russell E. Morris, Angus P. Wilkinson, and Anthony K. Cheetham
pp 4774 - 4777; DOI:
10.1021/ic00049a012
PDF
Rhenium-selenium-chlorine solid phases: cluster excision and core substitution reactions of molecular species
Omar M. Yaghi, Michael J. Scott, and R. H. Holm
pp 4778 - 4784; DOI:
10.1021/ic00049a013
PDF
Heteronuclear trinuclear copper-chromium and copper-cobalt complex ions of the types [CuII{Cr(A)4(OH)2}2]4+ and [CuII{Co(A)4(OH)2}2]4+
Joergen Glerup, Patricia A. Goodson, Derek J. Hodgson, Marc H. Lynn, and Kirsten Michelsen
pp 4785 - 4791; DOI:
10.1021/ic00049a014
PDF
Suppression of cluster unsaturation by formation of extensive but long-range metal-metal bonding: crystal structures of [Ru3H(pyS)(CO)9] and [{Ru3H(pyS)(CO)7}3], where pyS is the pyridine-2-thiolato ligand
Antony J. Deeming, Kenneth I. Hardcastle, and Manzurul Karim
pp 4792 - 4796; DOI:
10.1021/ic00049a015
PDF
Steric effects of the 2-(diphenylphosphino)-6-methoxypyridine short-bite bridging ligand in the synthesis of binuclear complexes. Crystal and molecular structure of [Rh2Cu(CO)2(Ph2PPyOMe)2(.mu.-Cl)2]BF4.cntdot.CH2Cl2
Carmela Grazia Arena, Felice Faraone, Maurizio Lanfranchi, Enrico Rotondo, and Antonio Tiripicchio
pp 4797 - 4802; DOI:
10.1021/ic00049a016
PDF
Synthesis and characterization by FAB mass spectrometry of a series of new polymetallic homo- and heteronuclear complexes of ruthenium(II) and rhodium(III) with the symmetric bridging ligand 1,4,5,8,9,12-hexaazatriphenylene
P. Didier, L. Jacquet, A. Kirsch-De Mesmaeker, R. Hueber, and A. Van Dorsselaer
pp 4803 - 4809; DOI:
10.1021/ic00049a017
PDF
Hydrotris(3-neopentylpyrazol-1-yl)borates: a new type of sterically hindered poly(pyrazolyl)borates
J. C. Calabrese and S. Trofimenko
pp 4810 - 4814; DOI:
10.1021/ic00049a018
PDF
Thermal decomposition of 1:1 R3Al:en adducts (R = Me, Et; en = ethylenediamine): synthesis and structure of a novel intermediate, Al[(HNCH2CH2NH)AlMe2]3
Zhiping Jiang, Leonard V. Interrante, Daekeun Kwon, Fook S. Tham, and Rudolph Kullnig
pp 4815 - 4822; DOI:
10.1021/ic00049a019
PDF
Dynamic behavior and crystal structures of Pd2(.mu.NS,.eta.2-L)2Cl2(PMe3)2 (L = pyrimidine-2-thiolate, 4-methylpyrimidine-2-thiolate, and methylimidazole-2-thiolate): influence of the N-C-S bond angle on the stability of (heterocyclic 2-thiolato)dipalladium complexes
Glenn P. A. Yap and Craig M. Jensen
pp 4823 - 4828; DOI:
10.1021/ic00049a020
PDF
Electronic structure and chemical bonding of a series of rare earth metal clusters R7X12Z
Song Gao, Guangxian Xu, and Lemin Li
pp 4829 - 4833; DOI:
10.1021/ic00049a021
PDF
Ab initio study of superalkalis. First ionization potentials and thermodynamic stability
Eva Rehm, Alexander I. Boldyrev, and Paul v R. Schleyer
pp 4834 - 4842; DOI:
10.1021/ic00049a022
PDF
Redox chemistry of water-soluble iron, manganese, and chromium metalloporphyrins and acid-base behavior of their lyate axial ligands in aqueous solution: influence of electronic effects
Seungwon Jeon and Thomas C. Bruice
pp 4843 - 4848; DOI:
10.1021/ic00049a023
PDF
Ring reduction of [N-methyltetrakis(4-sulfonatophenyl)porphinato]cobalt(II), -nickel(II), and -copper(II) and subsequent methyl group migration. Reversible reaction between methyl radicals and NiIITSPP
D. M. Guldi, P. Neta, P. Hambright, and R. Rahimi
pp 4849 - 4853; DOI:
10.1021/ic00049a024
PDF
Macrocyclic ligands with 18-membered rings containing pyridine or furan groups: preparation, protonation, and complexation by metal ions
George L. Rothermel, Lan Miao, Anna L. Hill, and Susan C. Jackels
pp 4854 - 4859; DOI:
10.1021/ic00049a025
PDF
Sixth-order kinetics in a catalyzed autoxidation of a macrocyclic cobalt(II) complex
Adam Marchaj, Andreja Bakac, and James H. Espenson
pp 4860 - 4863; DOI:
10.1021/ic00049a026
PDF
Electrocatalytic reduction of carbon dioxide based on 2,2'-bipyridyl complexes of osmium
Mitchell R. M. Bruce, Elise Megehee, B. Patrick Sullivan, H. Holden Thorp, Terrence R. O'Toole, Allison Downard, J. Richard Pugh, and Thomas J. Meyer
pp 4864 - 4873; DOI:
10.1021/ic00049a027
PDF
Spectroscopy, photophysical properties, and x-ray crystal structure of platinum(II) complexes of quaterpyridine
Chin Wing Chan, Chi Ming Che, Ming Chu Cheng, and Yu Wang
pp 4874 - 4878; DOI:
10.1021/ic00049a028
PDF
Steric and electronic factors influencing the reactivity of tertiary phosphines toward platinum(II) complexes
Raffaello Romeo, Giuseppe Arena, and Luigi Monsu Scolaro
pp 4879 - 4884; DOI:
10.1021/ic00049a029
PDF
Heats of the reactions of tricarbonyl(naphthalene)chromium, tricarbonyl(cycloheptatriene)chromium, tricarbonyl(cycloheptatriene)tungsten, and tricarbonyltris(ethylcyanide)tungsten with pyridine, phosphines, phosphites, and other ligands. Comparative thermochemical study of L3M(CO)3 complexes (M = Cr, Mo, W)
Shakti L. Mukerjee, Russell F. Lang, Telvin Ju, Gabor Kiss, and Carl D. Hoff
pp 4885 - 4889; DOI:
10.1021/ic00049a030
PDF
Composition and structure of a (benzimidazole)chlorobis(ethylenediamine)cobalt salt
Richard E. Marsh
pp 4890 - 4890; DOI:
10.1021/ic00049a031
PDF
Synthesis, characterization, and reactivity of lead(II) glycolate complexes
Clive D. Chandler, Mark J. Hampden-Smith, and Eileen N. Duesler
pp 4891 - 4893; DOI:
10.1021/ic00049a032
PDF
Intercalation of montmorillonite with individual chromium(III) hydrolytic oligomers
A. Drljaca, J. R. Anderson, L. Spiccia, and T. W. Turney
pp 4894 - 4897; DOI:
10.1021/ic00049a033
PDF
Molecular precursor chemistry for titanium nitride: synthesis and structure of [Ti(NMe2)(N3)(.mu.-NMe2)]3(.mu.3-N3)(.mu.3-NH)
M. E. Gross and T. Siegrist
pp 4898 - 4899; DOI:
10.1021/ic00049a034
PDF
A linear polymeric copper(II) complex bridged simultaneously by azido, nitrato, and betaine ligands. Crystal structure of catena-[Bis(.mu.-(1,1)-azido)bis(.mu.-nitrato-O,O')bis-((.mu.-trimethylammonio)acetato-O,O')dicopper(II)], [Cu2(N3)2(NO3)2(Me3NCH2CO2)2]n
Mok Yin Chow, Zhong Yuan Zhou, and Thomas C. W. Mak
pp 4900 - 4902; DOI:
10.1021/ic00049a035
PDF

Issue 24


An eight-coordinate cage: synthesis and structure of the first macrotricyclic tetraterephthalamide ligand
Jide Xu, T. D. P. Stack, and Kenneth N. Raymond
pp 4903 - 4905; DOI:
10.1021/ic00050a001
PDF
Suppression by vanadium(IV) of chromium(V)-mediated DNA cleavage and chromium(VI/V)-induced mutagenesis. Synthesis and crystal structure of the vanadium(IV) complex (NH4)[V(O){HOC(Et)2COO}{OC(Et)2COO}]
Gregory Barr-David, Trevor W. Hambley, Jennifer A. Irwin, Robert J. Judd, Peter A. Lay, Brooke D. Martin, Richard Bramley, Nicholas E. Dixon, Philip Hendry, and et al.
pp 4906 - 4908; DOI:
10.1021/ic00050a002
PDF
The nature of phosphorus(III) ligands as probed by molybdenum-95 NMR spectroscopy
Elmer C. Alyea and Shuquan Song
pp 4909 - 4910; DOI:
10.1021/ic00050a003
PDF
Boron analogs of phenylalanine, valine, leucine, and isoleucine: syntheses of amine-alkyl[(ethylimino)alkoxymethyl]boranes
Christopher H. Sutton, Mark W. Baize, Wyatt J. Mills, and Lee J. Todd
pp 4911 - 4916; DOI:
10.1021/ic00050a004
PDF
Perfluoro- and polyfluoroazaalkenes as precursors to bis(perfluoroalkyl or polyfluoroalkyl) alkyl (or aryl) tertiary amines
Yihong Chen, Nimesh R. Patel, Robert L. Kirchmeier, and Jeanne M. Shreeve
pp 4917 - 4920; DOI:
10.1021/ic00050a005
PDF
Reactions of nido-6-SB9H11 with imines. Structural characterization of endo-9-((tert-Bu)MeC:NH)-arachno-6-SB9H11
Stefan Kuepper, Patrick J. Carroll, and Larry G. Sneddon
pp 4921 - 4925; DOI:
10.1021/ic00050a006
PDF
A dimolybdosulfenamide: condensations and crystal structures. Sulfur invertomer structural effects
Elaine K. Haub, John F. Richardson, and Mark E. Noble
pp 4926 - 4932; DOI:
10.1021/ic00050a007
PDF
Linear trimeric, dimeric, and monomeric titanium(III) aryloxides
Ravinder Minhas, Robbert Duchateau, Sandro Gambarotta, and Corinne Bensimon
pp 4933 - 4938; DOI:
10.1021/ic00050a008
PDF
Oxovanadium(V) 1,3-propanediolate chloride complexes: tetrameric clusters
Debbie C. Crans, Robert W. Marshman, Miri Shaia Gottlieb, Oren P. Anderson, and Mary M. Miller
pp 4939 - 4949; DOI:
10.1021/ic00050a009
PDF
Effects of solvent, temperature, and pressure on the photophysical and visible-spectroscopic behavior of the trans-diammine(1,4,8,11-tetraazacyclotetradecane)chromium(III) ion
L. Vincze, D. A. Friesen, S. P. Mezyk, and W. L. Waltz
pp 4950 - 4958; DOI:
10.1021/ic00050a010
PDF
Kinetics of acetyl radical formation from methyl radicals and carbon monoxide and crystal structures of two acetylcobalt complexes
Andreja Bakac, James H. Espenson, and Victor G. Young
pp 4959 - 4964; DOI:
10.1021/ic00050a011
PDF
Variable modes of nickel(II) coordination with macrocyclic ligands based on 1,5-bis(2-mercaptoethyl)-1,5-diazacyclooctane (BME-DACO)
Marcetta Y. Darensbourg, Ivan Font, Daniel K. Mills, Magdalena Pala, and Joseph H. Reibenspies
pp 4965 - 4971; DOI:
10.1021/ic00050a012
PDF
Comparative investigation of the spin-crossover compounds Fe(btz)2(NCS)2 and Fe(phen)2(NCS)2 (where btz = 2,2'-bi-4,5-dihydrothiazine and phen = 1,10-phenanthroline). Magnetic properties and thermal dilatation behavior and crystal structure of Fe(btz)2(NCS)2 at 293 and 130 K
Jose Antonio Real, Bernard Gallois, Thierry Granier, Franz Suez-Panama, and Jacqueline Zarembowitch
pp 4972 - 4979; DOI:
10.1021/ic00050a013
PDF
Low-spin tris(quinone oximates) of manganese(II,III). Synthesis, isomerism, and equilibria
Partha Basu and Animesh Chakravorty
pp 4980 - 4986; DOI:
10.1021/ic00050a014
PDF
A manganese(III) complex of 3,5-bis((salicylideneamino)methyl)pyrazole: synthesis, structure, and properties
Kenji Shindo, Yumika Mori, Kenichiro Motoda, Hiroshi Sakiyama, Naohide Matsumoto, and Hisashi Okawa
pp 4987 - 4990; DOI:
10.1021/ic00050a015
PDF
F430 model chemistry. Mechanistic investigation of the reduction, coupling, and dehydrohalogenation of alkyl halides by the nickel(I) octaethylisobacteriochlorin anion
Goutam K. Lahiri, Leonard J. Schussel, and Alan M. Stolzenberg
pp 4991 - 5000; DOI:
10.1021/ic00050a016
PDF
Difference ultraviolet spectroscopic studies on the binding of lanthanides to human serum transferrin
Wesley R. Harris and Yong Chen
pp 5001 - 5006; DOI:
10.1021/ic00050a017
PDF
Electrochemical investigations of poplar, spinach, cucumber, and parsley plastocyanins at conventional and microsized carbon electrodes
Felix N. Buechi, Alan M. Bond, Rachel Codd, Laila N. Huq, and Hans C. Freeman
pp 5007 - 5014; DOI:
10.1021/ic00050a018
PDF
Electronic spectra and electronic structures of [Zr6Cl12Z]Cl6n- (Z = Be, B, Fe) clusters
Marcus R. Bond and Timothy Hughbanks
pp 5015 - 5021; DOI:
10.1021/ic00050a019
PDF
Communication between metal centers in tungsten(0)-tungsten(II) complexes bridged by 1,4-diisocyanobenzene: is the ligand .pi. system involved?
Desiree S. Grubisha, Jeffrey S. Rommel, Thomas M. Lane, Wilfred T. Tysoe, and Dennis W. Bennett
pp 5022 - 5027; DOI:
10.1021/ic00050a020
PDF
Valence localization in iron complexes with o-quinone-derived ligands studied by high magnetic field Moessbauer spectroscopy
Michelle J. Cohn, Chuan Liang Xie, Jean Pierre M. Tuchagues, Cortlandt G. Pierpont, and David N. Hendrickson
pp 5028 - 5033; DOI:
10.1021/ic00050a021
PDF
Electronic spectra of pyrazolyl-bridged binuclear iridium(I) complexes
Janet L. Marshall, Michael D. Hopkins, Vincent M. Miskowski, and Harry B. Gray
pp 5034 - 5040; DOI:
10.1021/ic00050a022
PDF
The dixenon(1+) cation: formation in the condensed phases and characterization by ESR, UV-visible, and Raman spectroscopy
Dean R. Brown, Martin J. Clegg, Anthony J. Downs, Richard C. Fowler, Alan R. Minihan, James R. Norris, and Lawrence Stein
pp 5041 - 5052; DOI:
10.1021/ic00050a023
PDF
Synthesis and structure of a trinickeliron cluster featuring single and double thiolato bridges
Gerard J. Colpas, Roberta O. Day, and Michael J. Maroney
pp 5053 - 5055; DOI:
10.1021/ic00050a024
PDF
The oxidation reaction in x-irradiated bis(ethylenediamine)platinum(II) bis(hydrogen squarate): a single-crystal EPR study of a platinum(III) complex
Michel Geoffroy, Gerald Bernardinelli, Paule Castan, Henry Chermette, Diane Deguenon, Safouh Nour, Jacques Weber, and Michel Wermeille
pp 5056 - 5060; DOI:
10.1021/ic00050a025
PDF
The ion-pair mechanism in square planar substitution. Displacement of dimethyl sulfoxide from chloro(dimethyl sulfoxide)(N,N,N'N'-tetramethyldiaminoethane)platinum(II) salts by halide ions in dichloromethane solution
Giuseppe Alibrandi, Raffaelo Romeo, Luigi Monsu Scolaro, and Martin L. Tobe
pp 5061 - 5066; DOI:
10.1021/ic00050a026
PDF
Complexation of monovalent metal ions by 4,7,13,16-tetraoxa-1,10-diazabicyclo[8.8.8]hexacosane in a range of solvents. A potentiometric titration and nuclear magnetic resonance study
Stephen F. Lincoln and Ashley K. W. Stephens
pp 5067 - 5071; DOI:
10.1021/ic00050a027
PDF
Vanadium(V) complexes of 1,5,10-tris(2,3-dihydroxybenzoyl)-1,5,10-triazadecane and its analogs
Alison Butler, Roger De la Rosa, Qizhi Zhou, Amrit Jhanji, and Carl J. Carrano
pp 5072 - 5077; DOI:
10.1021/ic00050a028
PDF
Electrocatalysis of the reduction of molecular oxygen to water by tetraruthenated cobalt meso-tetrakis(4-pyridyl)porphyrin adsorbed on graphite electrodes
Chunnian Shi and Fred C. Anson
pp 5078 - 5083; DOI:
10.1021/ic00050a029
PDF
Electrochemistry and spectroelectrochemistry (EPR, UV-visible-near-IR) of platinum(II) 2,2'-bipyridine and ring-metalated bipyridine complexes: PtII(L-) and PtI(L-) but not PtI(L)
Paul S. Braterman, Jae Inh Song, Franz M. Wimmer, Smita Wimmer, Wolfgang Kaim, Axel Klein, and R. D. Peacock
pp 5084 - 5088; DOI:
10.1021/ic00050a030
PDF
Kinetic and equilibrium studies on porphyrins, chlorins, and isobacteriochlorins: basicities, zinc incorporation, and acid-catalyzed solvolysis reactions in aqueous and nonaqueous solutions
T. P. G. Sutter and P. Hambright
pp 5089 - 5093; DOI:
10.1021/ic00050a031
PDF
Structures of charge-perturbed or sterically overcrowded molecules. 16. The cesium tetracyanoethylenide radical salt
H. Bock and K. Ruppert
pp 5094 - 5099; DOI:
10.1021/ic00050a032
PDF
Synthesis, reactivity, and dynamic behavior of a boron-containing silsesquioxane
Frank J. Feher, Theodore A. Budzichowski, and Joseph W. Ziller
pp 5100 - 5105; DOI:
10.1021/ic00050a033
PDF
Reduction of aldehydes and ketones by transition metal hydrides. 3. Reduction of .beta.-diketones by trans,trans-dicarbonylhydridonitrosylbis(trimethylphosphine)tungsten with formation of tungsten(0) .beta.-diketonates
Adolphus A. H. Van der Zeijden, Dario Veghini, and Heinz Berke
pp 5106 - 5116; DOI:
10.1021/ic00050a034
PDF
Synthesis and spectroscopic properties of the complexes [M2(DIEN)2(NIPHOS)2][SbF6]2 (M = Ir, DIEN = 1,5-cyclooctadiene (COD); M = Rh, DIEN = norbornadiene (NBD); NIPHOS = 2-(2'-pyridyl)-4,5-dimethylphosphinine). X-ray crystal structure of [Ir2(COD)2(NIPHOS)2][SbF6]2
Bruno Schmid, Luigi M. Venanzi, Tobias Gerfin, Volker Gramlich, and Francois Mathey
pp 5117 - 5122; DOI:
10.1021/ic00050a035
PDF
Clusters derived from the hydroboration of decacarbonyldi-.mu.-hydridotriosmium and their derivatives
Deng Yang Jan, David P. Workman, Leh Yeh Hsu, Jeanette A. Krause, and Sheldon G. Shore
pp 5123 - 5131; DOI:
10.1021/ic00050a036
PDF
Magnetic properties of a dodecanuclear polyoxovanadate with exchange and electron delocalization effects
Anne Laure Barra, Dante Gatteschi, B. S. Tsukerblatt, Joachim Doering, Achim Mueller, and Louis Claude Brunel
pp 5132 - 5134; DOI:
10.1021/ic00050a037
PDF
Reduction potential of the nitrate radical in aqueous solution
Pei Yun Jiang, Yosuke Katsumura, Kenkichi Ishigure, and Yoichi Yoshida
pp 5135 - 5136; DOI:
10.1021/ic00050a038
PDF
Synthesis and crystal structure of a binuclear ruthenium compound containing [Ru2(.mu.-S5)(.mu.-S2CNMe2)(S2CNMe2)(CO)2(PPh3)2] and [Ru2(.mu.-S6)(.mu.-S2CNMe2)(S2CNMe2)(CO)2(PPh3)2]: the first ruthenium compounds with bridging S5 and S6 ligands
Hiroyuki Uemura, Masaki Kawano, Takehide Watanabe, Takaya Matsumoto, and Kazuko Matsumoto
pp 5137 - 5139; DOI:
10.1021/ic00050a039
PDF
Kinetics and mechanism of the ferrate oxidation of sulfite and selenite in aqueous media
Michael D. Johnson and Jonathan Bernard
pp 5140 - 5142; DOI:
10.1021/ic00050a040
PDF
Resonance Raman spectroscopic studies of trans-dioxorhenium(V) tetrapyridyl species
Christopher S. Johnson, Carolyn Mottley, Joseph T. Hupp, and Gerald D. Danzer
pp 5143 - 5145; DOI:
10.1021/ic00050a041
PDF
Synthesis, characterization, and crystal structure of bis(triphenylphosphine)iminium carbidoheneicosacarbonyl(triphenylphosphite)heptarhenate(1-). Illustration of a polar intermediate stage in cluster decapping
Scott W. Simerly, Scott R. Wilson, and John R. Shapley
pp 5146 - 5149; DOI:
10.1021/ic00050a042
PDF
Structure of bis[(tricarbonyl)-.mu.-hydridobis(trimethylphosphine)rhenium]decacarbonyltriosmium: change in the site of hydride coordination in a metal cluster on carbonyl substitution by trimethyl phosphine
Weibin Wang, Raymond J. Batchelor, Harry B. Davis, Frederick W. B. Einstein, and Roland K. Pomeroy
pp 5150 - 5153; DOI:
10.1021/ic00050a043
PDF
Homonuclear and heteronuclear metal complexes with a cyclic tetracopper(II) unit. Syntheses, crystal structures, and magnetic properties of [CuII4(dmap)3(OH)(O2CCH3)2(HO2CCH3)(H2O)][PF6]2, [CuII4(dmap)2(O2CCH3)4][PF6]2, [CuII4(dmap)2(O2CCH3)2(OH)2][HgII(O2CCH3)Cl2]2[HgIICl2], and [CuII4(dmap)2(O2CCH3)3(OH)2(H2O)][PF6] (dmap = 1,3-bis(dimethylamino)-2-propanolato). [Erratum to document cited in CA116(26):267843w]
Suning Wang, Steven J. Trepanier, Jian Chuan Zheng, Zhen Pang, and Michael J. Wagner
pp 5154 - 5154; DOI:
10.1021/ic00050a044
PDF
The first discrete structure for the heptaiodide ion. [Erratum to document cited in CA117(4):39137j]
Rinaldo Poli, John C. Gordon, Raj K. Khanna, and Phillip E. Fanwick
pp 5154 - 5154; DOI:
10.1021/ic00050a045
PDF

Issue 25


Exchange couplings in Lewis acid adducts of substituted niobocene trihydrides
Antonio Antinolo, Fernando Carrillo, Mariano Fajardo, Juan Fernandez-Baeza, Antonio Otero, and Bruno Chaudret
pp 5156 - 5157; DOI:
10.1021/ic00051a001
PDF
Synthesis, properties, and crystal structure of a novel .mu.-hydrazine-bridged mixed-valence ruthenium(II,III) complex stabilized by hydrazine hydrogen bonds, [RuCl(TMP)2]2(.mu.-Cl)(.mu.-N2H4)(.mu.-S2) (TMP = trimethyl phosphite)
Masaki Kawano, Chikara Hoshino, and Kazuko Matsumoto
pp 5158 - 5159; DOI:
10.1021/ic00051a002
PDF
[M(SR)3L2] complexes of ruthenium(IV,III) and osmium(IV): structural integrity of the trigonal [M(SR)3]+,0 cores
Soami P. Satsangee, John H. Hain, Pamela T. Cooper, and Stephen A. Koch
pp 5160 - 5161; DOI:
10.1021/ic00051a003
PDF
Reassignment of the valence photoelectron spectra of nickel diallyl complex Ni(.eta.3-C3H5)2 using variable energy photoelectron spectroscopy
Xiaorong Li, G. M. Bancroft, R. J. Puddephatt, Y. F. Hu, Z. Liu, and K. H. Tan
pp 5162 - 5163; DOI:
10.1021/ic00051a004
PDF
Conformation changes of dimeric zinc(II) porphyrins induced by binding of bidentate ligands
Yoshio Uemori, Akiko Nakatsubo, Hiroyasu Imai, Shigeo Nakagawa, and Eishin Kyuno
pp 5164 - 5171; DOI:
10.1021/ic00051a005
PDF
Cathodic reduction of oxygen and hydrogen peroxide at cobalt and iron crowned phthalocyanines adsorbed on highly oriented pyrolytic graphite electrodes
Nagao Kobayashi, Pavel Janda, and A. B. P. Lever
pp 5172 - 5177; DOI:
10.1021/ic00051a006
PDF
Mononuclear and binuclear chromium(III) picolinate complexes
Diane M. Stearns and William H. Armstrong
pp 5178 - 5184; DOI:
10.1021/ic00051a007
PDF
Tetranuclear manganese(III)-oxo-carboxylate complexes possessing terminal phenoxide or alkoxide ligands
Elisabeth Bouwman, Milissa A. Bolcar, Eduardo Libby, John C. Huffman, Kirsten Folting, and George Christou
pp 5185 - 5192; DOI:
10.1021/ic00051a008
PDF
Synthesis and characterization of seven-coordinate tantalum(I) and niobium(I) complexes with cis carbonyl and alkyl isocyanide ligands
Edmund M. Carnahan, R. Lynn Rardin, Simon G. Bott, and Stephen J. Lippard
pp 5193 - 5201; DOI:
10.1021/ic00051a009
PDF
Organotransition-metal metallacarboranes. 30. Tetradecker metallacarborane sandwiches: synthesis via double-decker stacking and structural characterization of Co-Co-Co, cobalt-nickel-cobalt, and cobalt-ruthenium-cobalt complexes
Kent W. Piepgrass, Xiangsheng Meng, Markus Hoelscher, Michal Sabat, and Russell N. Grimes
pp 5202 - 5210; DOI:
10.1021/ic00051a010
PDF
Ferrocenium hexafluorophosphate: molecular dynamics in the solid state
Robert J. Webb, Michael D. Lowery, Yutaka Shiomi, Michio Sorai, Richard J. Wittebort, and David N. Hendrickson
pp 5211 - 5219; DOI:
10.1021/ic00051a011
PDF
Dialkoxyosmium(IV) porphyrins. Crystal and molecular structures of diethoxy-, diphenoxy-, and bis(2-propanolato)(meso-tetraphenylporphyrinato)osmium(IV)
Chi Ming Che, Jie Sheng Huang, Zao Ying Li, Chung Kwong Poon, Wai Fong Tong, Ting Fong Lai, Ming Chu Cheng, Chih Chieh Wang, and Yu Wang
pp 5220 - 5225; DOI:
10.1021/ic00051a012
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Heterodinuclear bis(diphenylphosphino)methane-bridged molybdenum (d6)-gold (d10) complexes: metal-metal interactions and ligand oxidation
Alan L. Balch, Bruce C. Noll, Marilyn M. Olmstead, and Dawn V. Toronto
pp 5226 - 5230; DOI:
10.1021/ic00051a013
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Paramagnetic .sigma.-bonded phenylnickel(II) macrocyclic systems. Nuclear magnetic resonance identification of (.sigma.-phenyl)nickel(II) 5,20-diphenyl-10,15-bis(p-tolyl)-21-thiaporphyrin and (.sigma.-phenyl)nickel(II) N-methyltetraphenylporphyrin
Piotr J. Chmielewski and Lechoslaw Latos-Grazynski
pp 5231 - 5235; DOI:
10.1021/ic00051a014
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Photolysis of argon matrixes containing tribromoboron and dihydrogen: synthesis of hydroboranes via dibromoboron
Antoni Moroz and Ray L. Sweany
pp 5236 - 5242; DOI:
10.1021/ic00051a015
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Luminescence and intramolecular energy-transfer processes in isomeric cyano-bridged rhenium(I)-rhenium(I) and rhenium(I)-ruthenium(II)-rhenium(I) polypyridyl complexes
K. Kalyanasundaram, M. Graetzel, and M. K. Nazeeruddin
pp 5243 - 5253; DOI:
10.1021/ic00051a016
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Ab initio calculation of the magnetic exchange interactions in (.mu.-oxo)diiron(III) systems using a broken symmetry wave function
J. R. Hart, A. K. Rappe, S. M. Gorun, and T. H. Upton
pp 5254 - 5259; DOI:
10.1021/ic00051a017
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Electronic coupling in cyano-bridged ruthenium polypyridine complexes and role of electronic effects on cyanide stretching frequencies
Carlo Alberto Bignozzi, Roberto Argazzi, Jon R. Schoonover, Keith C. Gordon, R. Brian Dyer, and Franco Scandola
pp 5260 - 5267; DOI:
10.1021/ic00051a018
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Kinetics and mechanism of acceleration of copper(II) incorporation into a porphyrin by reducing agents
Masaaki Tabata and Mie Babasaki
pp 5268 - 5271; DOI:
10.1021/ic00051a019
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Preparation and NMR characterization of .eta.1-N-bonded platinum(II) and palladium(II) adducts of eight-membered heterocyclic thiazenes
Tristram Chivers and Robert W. Hilts
pp 5272 - 5279; DOI:
10.1021/ic00051a020
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Aqueous uranium complexes. 2. Raman spectroscopic study of the complex formation of the dioxouranium(VI) ion with a variety of inorganic and organic ligands
Chinh Nguyen Trung, G. M. Begun, and Donald A. Palmer
pp 5280 - 5287; DOI:
10.1021/ic00051a021
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Equilibria and dynamics of thallium-EDTA (Tl(edta)X2-) complexes (X = halide, pseudohalide) studied by multinuclear NMR
Johan Blixt, Julius Glaser, Piroska Solymosi, and Imre Toth
pp 5288 - 5297; DOI:
10.1021/ic00051a022
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Complexes containing heteronuclear quadruple bonds. Preparation and characterization of quadruply bonded .alpha.-MoWCl4(L-L)2 (L-L = dppe, dmpe) and .beta.-MoWCl4(L-L)2 (L-L = dppm, dmpm, dppe)
F. A. Cotton and Chris A. James
pp 5298 - 5307; DOI:
10.1021/ic00051a023
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Heterobimetallic edge-sharing bioctahedral complexes. Synthesis, characterization, and singlet-triplet separations as determined by phosphorus-31 nuclear magnetic resonance
F. A. Cotton, Judith L. Eglin, Chris A. James, and Rudy L. Luck
pp 5308 - 5315; DOI:
10.1021/ic00051a024
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Synthesis, structure, spectroscopic properties, and hydrolytic chemistry of organophosphonoyl polyoxotungstates of formula [C6H5P(O)]2Xn+W11O39(8-n)- (Xn+ = P5+, Si4+)
Gyu Shik Kim, Karl S. Hagen, and Craig L. Hill
pp 5316 - 5324; DOI:
10.1021/ic00051a025
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Synthesis, spectroscopic characterization, and electrochemical properties of bis[1,2-bis(5-chlorosalicylideneamino)ethanato(.mu.-oxo)manganese(IV)]
Gregory C. Dailey, Colin P. Horwitz, and Carol A. Lisek
pp 5325 - 5330; DOI:
10.1021/ic00051a026
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Synthesis, reactions, and phosphorus-31 NMR analysis of (diphosphine)platinum dithiolates
A. K. Fazlur-Rahman and J. G. Verkade
pp 5331 - 5335; DOI:
10.1021/ic00051a027
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Orthometalation reactions of binuclear dirhodium(II) compounds: thermodynamic studies
Pascual Lahuerta, Jorge Paya, and Antonio Bianchi
pp 5336 - 5338; DOI:
10.1021/ic00051a028
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Synthesis and characterization of the heterometallic complexes (PPh4)2[Mn(MS4)2] (M = Mo, W). X-ray crystal structure of the tungsten derivative
Alessandro Bencini, Franco Cecconi, Carlo A. Ghilardi, Stefano Midollini, Francesco Nuzzi, and Annabella Orlandini
pp 5339 - 5342; DOI:
10.1021/ic00051a029
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Editorial - Page Limit for Communications

pp 5155 - 5155; DOI:
10.1021/ic00051a600
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Issue 26


A distorted mercury [Hg(SR)4]2- complex with alkanethiolate ligands: the fictile coordination sphere of monomeric [Hg(SR)x] complexes
Nandakumar Govindaswamy, Jayson Moy, Michelle Millar, and Stephen A. Koch
pp 5343 - 5344; DOI:
10.1021/ic00052a001
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Electrochemical oxidation of bis(cyclopentadienyl)titanium dichloride
J. E. Anderson and S. M. Sawtelle
pp 5345 - 5346; DOI:
10.1021/ic00052a002
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Facile amino to pyridyl isomerization: pentaammineruthenium(II) walks the nicotinamide and isonicotinamide rings
Mei H. Chou, Bruce S. Brunschwig, Carol Creutz, Norman Sutin, Andrew Yeh, Rong Chin Chang, and Chin Tung Lin
pp 5347 - 5348; DOI:
10.1021/ic00052a003
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ROESY: a technique for establishing the existence of chemical exchange in paramagnetic model hemes with short T1 and T2 relaxation times
Ursula Simonis, Jerry L. Dallas, and F. Ann Walker
pp 5349 - 5350; DOI:
10.1021/ic00052a004
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Crown thioether chemistry. The first homoleptic thioether complex of technetium and its potential application in tumor imaging
David J. White, Heinz Josef Kuppers, Alison J. Edwards, David J. Watkin, and Stephen R. Cooper
pp 5351 - 5352; DOI:
10.1021/ic00052a005
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Is chromium hexafluoride octahedral? Theory confirms "yes!"
Kristine Pierloot and Bjoern O. Roos
pp 5353 - 5354; DOI:
10.1021/ic00052a006
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On the structure and existence of chromium hexafluoride
Arndt Neuhaus, Gernot Frenking, Christian Huber, and Juergen Gauss
pp 5355 - 5356; DOI:
10.1021/ic00052a007
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Vibrational and electronic spectra of molecular chromium tetrafluoride, CrF4, and chromium pentafluoride, CrF5. Comments on the existence of chromium hexafluoride, CrF6
J. Jacobs, H. S. P. Mueller, H. Willner, E. Jacob, and H. Buerger
pp 5357 - 5363; DOI:
10.1021/ic00052a008
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"Ab initio" calculations on a novel mode for storing and releasing electrons via carbon-carbon bond formation and cleavage
R. Cambi, R. Nottoli, M. Rosi, A. Sgamellotti, and C. Floriani
pp 5364 - 5367; DOI:
10.1021/ic00052a009
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Far-infrared spectroscopy of quadruply bonded M2X4L4 complexes
Michael D. Hopkins, Vincent M. Miskowski, Patrick M. Killough, Alfred P. Sattelberger, William H. Woodruff, and Harry B. Gray
pp 5368 - 5374; DOI:
10.1021/ic00052a010
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Excited-state deactivation mechanisms of the M2(dba)3 complexes (M = palladium, platinum; dba = dibenzylideneacetone)
Stephan M. Hubig, Marc Drouin, Andre Michel, and Pierre D. Harvey
pp 5375 - 5380; DOI:
10.1021/ic00052a011
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Comparative study of crystal structures and thermal magnetic properties of a yttrium-copper Y2Cu8 and a neodymium-copper Nd2Cu8 complex
Suning Wang, Zhen Pang, and Michael J. Wagner
pp 5381 - 5388; DOI:
10.1021/ic00052a012
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Structural variants of tetranuclear L4Cu4X4. Influence of L on the coordination mode of copper(I)
Mikael Haakansson, Susan Jagner, Eric Clot, and Odile Eisenstein
pp 5389 - 5394; DOI:
10.1021/ic00052a013
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Tetrahedral-atom zincophosphate structures. Zinc diethyl phosphate, [Zn(O2P(OC2H5)2)2]x, a one-dimensional inorganic "polymer"
William T. A. Harrison, Tina M. Nenoff, Thurman E. Gier, and Galen D. Stucky
pp 5395 - 5399; DOI:
10.1021/ic00052a014
PDF
Polydentate ligand chemistry of Group 13 metals: effects of the size and donor selectivity of metal ions on the structures and properties of aluminum, gallium, and indium complexes with potentially heptadentate (N4O3) amine phenol ligands
Shuang Liu, Steven J. Rettig, and Chris Orvig
pp 5400 - 5407; DOI:
10.1021/ic00052a015
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Coordination chemistry of 2-(2'-hydroxyphenyl)-2-oxazolines with aluminum, gallium, and indium: first tris(ligand)metal(III) complexes of this naturally occurring binding group
H. R. Hoveyda, Veranja Karunaratne, Steven J. Rettig, and Chris Orvig
pp 5408 - 5416; DOI:
10.1021/ic00052a016
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Products from reactions of manganese oxo complex [Mn2O2(O2CCH3)(tpen)]2+ in acidic and neutral aqueous media: [Mn2(.mu.-O)2(.mu.-O2CCH3)(tpen)]3+ and [{Mn3(.mu.-O)4(OH)(tpen)}2(.mu.-tpen)]6+
Samudranil Pal and William H. Armstrong
pp 5417 - 5423; DOI:
10.1021/ic00052a017
PDF
Structural and magnetic characterization of trinuclear, mixed-valence manganese acetates
Dimitris P. Kessissoglou, Martin L. Kirk, Myoung Soo Lah, Xinhua Li, Catherine Raptopoulou, William E. Hatfield, and Vincent L. Pecoraro
pp 5424 - 5432; DOI:
10.1021/ic00052a018
PDF
Catalytic antibodies. Circular dichroism and UV-vis studies of antibody-metalloporphyrin interactions
E. Keinan, E. Benory, S. C. Sinha, A. Sinha-Bagchi, D. Eren, Z. Eshhar, and B. S. Green
pp 5433 - 5438; DOI:
10.1021/ic00052a019
PDF
Electron transfer. 115. Reduction of cobalt-bound superoxide with ascorbate
S. K. Saha, M. C. Ghosh, and E. S. Gould
pp 5439 - 5443; DOI:
10.1021/ic00052a020
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Square planar platinum(II) complexes: synthesis, IR spectroscopy, and hydration equilibria of PtIIL(CN)2 (L = 4,4'-di-tert-butyl-2,2'-bipyridine)
Kuo Chen Shih and R. H. Herber
pp 5444 - 5449; DOI:
10.1021/ic00052a021
PDF
Cytochrome c oxidase models: a dinuclear iron(III) porphyrin-copper(II) complex with a sulfur bridge
Barbara R. Serr, Christine E. L. Headford, Oren P. Anderson, C. Michael Elliott, Kevork Spartalian, Vladimir E. Fainzilberg, William E. Hatfield, Brian R. Rohrs, Sandra S. Eaton, and Gareth R. Eaton
pp 5450 - 5465; DOI:
10.1021/ic00052a022
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Non-metal redox kinetics: reactions of iodine and triiodide with thiosulfate via I2S2O32- and IS2O3- intermediates
William M. Scheper and Dale W. Margerum
pp 5466 - 5473; DOI:
10.1021/ic00052a023
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Kinetic generation of cis-cyclopentadienyl(dicarbonyl)rhenium dihydride from the reaction of (C5H5)Re(CO)2(.mu.-H)Pt(H)(PPh3)2 with diphenylacetylene
Charles P. Casey, Robin S. Tanke, Paulette N. Hazin, Carl R. Kemnitz, and Robert J. McMahon
pp 5474 - 5479; DOI:
10.1021/ic00052a024
PDF
Feasibility of a limiting D mechanism for complex formation and ligand substitution reactions of pentacyanoferrate(II)
G. Stochel, J. Chatlas, P. Martinez, and R. Van Eldik
pp 5480 - 5483; DOI:
10.1021/ic00052a025
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A hydrogen atom in an organoplatinum-amine system. 2. The first isolated arylplatinum(IV) hydrides: synthetic and theoretical study (SCF and CAS-SCF calculations) on model complexes with a N-M(IV)-H/M(II)-.cntdot..cntdot..cntdot.H-N+ unit (M = Pd, Pt)
Ingrid C. M. Wehman-Ooyevaar, David M. Grove, Peter De Vaal, Alain Dedieu, and Gerard Van Koten
pp 5484 - 5493; DOI:
10.1021/ic00052a026
PDF
Pentacoordinated molecules. 94. Seven-membered rings in pentaoxyphosphoranes containing trifluoroethoxy groups
T. K. Prakasha, Sarah D. Burton, Roberta O. Day, and Robert R. Holmes
pp 5494 - 5499; DOI:
10.1021/ic00052a027
PDF
Synthesis, structure, and reactivity of heterometallic polyhydride complexes of rhenium with yttrium and lutetium
Daniel Alvarez, Kenneth G. Caulton, William J. Evans, and Joseph W. Ziller
pp 5500 - 5508; DOI:
10.1021/ic00052a028
PDF
Molecular dihydrogen and hydrido derivatives of ruthenium(II) complexes containing chelating ferrocenyl-based tertiary phosphine amine ligands and/or monodentate tertiary phosphine ligands
Cashman R. S. M. Hampton, Ian R. Butler, William R. Cullen, Brian R. James, Jean Pierre Charland, and J. Simpson
pp 5509 - 5520; DOI:
10.1021/ic00052a029
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Microstructures in thin polymeric films. Photochemically produced molecular voids
Sharon Gould, Kimberley H. Gray, Richard W. Linton, and Thomas J. Meyer
pp 5521 - 5525; DOI:
10.1021/ic00052a030
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Circular dichroism, luminescence, and electronic absorption of copper binding sites in metallothionein and its chemically synthesized .alpha. and .beta. domains
Yue Jin Li and Ulrich Weser
pp 5526 - 5533; DOI:
10.1021/ic00052a031
PDF
Molecular recognition by protonated O-BISDIEN and its metal complexes
Ramunas J. Motekaitis and Arthur E. Martell
pp 5534 - 5542; DOI:
10.1021/ic00052a032
PDF
Synthesis, spectroscopy, and structural studies of tetrakis(O-alkyl dithiocarbonato)germanium. Crystal structures of Ge[S2COR]4, where R = Me, Et, and iso-Pr
John E. Drake, Anil G. Mislankar, and Jincai Yang
pp 5543 - 5548; DOI:
10.1021/ic00052a033
PDF
Chemical oxidation of the ligand in nickel(II) cyclam: formation of a novel dinuclear complex and of a related cation containing a ligand radical ion
A. McAuley and C. Xu
pp 5549 - 5554; DOI:
10.1021/ic00052a034
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NMR study of the kinetics of ligand-exchange reactions of ethylenediamine with tetrakis(ethylenediamine)lanthanide(III) complexes
John H. Forsberg, Theodore J. Dolter, Ann M. Carter, Deepak Singh, Steven A. Aubuchon, Aaron T. Timperman, and Ali Ziaee
pp 5555 - 5560; DOI:
10.1021/ic00052a035
PDF
Synthesis and structural characterization of new copper complexes and the copper-barium-alkoxide complex BaCu4(OC(R)C(H)C(R)O)4(OR')2(HOR')4 (R = C(CH3)3, R' = CH2CH2OCH3)
Wolfgang Bidell, Valery Shklover, and Heinz Berke
pp 5561 - 5571; DOI:
10.1021/ic00052a036
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Structural relationships between mono- and dimeric bis(alkoxides) and bis(aryloxides) of calcium and barium. X-ray crystal structures of M(OC6H2-tert-Bu2-2,6-Me-4)2(THF)3.(THF) (M = calcium, barium) and [Ca(.mu.-OR)(OR)(THF)]2.2(toluene) [R = C(C6H5)2CH2C6H4Cl-4]
Kris F. Tesh, Timothy P. Hanusa, John C. Huffman, and Carolyn J. Huffman
pp 5572 - 5579; DOI:
10.1021/ic00052a037
PDF
Reactivity of MH(.eta.2-H2BH2)(CO)(PiPr3)2 (M = osmium, ruthenium) toward electrophiles: synthesis of new hydridocarbonylosmium(II) and -ruthenium(II) complexes containing triisopropylphosphine as ligand
Miguel A. Esteruelas, Maria P. Garcia, Ana M. Lopez, Luis A. Oro, Natividad Ruiz, Christoph Schluenken, Cristina Valero, and Helmut Werner
pp 5580 - 5587; DOI:
10.1021/ic00052a038
PDF
Ambivalent metal ion binding properties of cytidine in aqueous solution
Yoshiaki Kinjo, Liangnian Ji, Nicolas A. Corfu, and Helmut Sigel
pp 5588 - 5596; DOI:
10.1021/ic00052a039
PDF
pH Dependence of relaxivities and hydration numbers of gadolinium(III) complexes of macrocyclic amino carboxylates
Xun Zhang, C. Allen Chang, Harry G. Brittain, J. Mark Garrison, Joshua Telser, and Michael F. Tweedle
pp 5597 - 5600; DOI:
10.1021/ic00052a040
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